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1.
Steroids ; 51(3-4): 363-84, 1988.
Artigo em Inglês | MEDLINE | ID: mdl-3217960

RESUMO

Complete analysis of the proton nuclear magnetic resonance spectrum of desoxycorticosterone (DOC) has been made using selective double irradiation, two-dimensional experiments, relaxation rate, and nuclear Overhauser effect measurements in order to specify the structure and conformation of products encountered during the preparation of the specific antigen DOC-bovine serum albumin (BSA). It has been shown that DOC has the normal P conformation with ring A half-chair, and ring B chair. This confirms results previously obtained by circular dichroism measurements.


Assuntos
Desoxicorticosterona/análise , Espectroscopia de Ressonância Magnética , Conformação Molecular
2.
Steroids ; 51(3-4): 349-61, 1988.
Artigo em Inglês | MEDLINE | ID: mdl-3217959

RESUMO

Deoxycorticosterone (DOC) derivative compounds (DOC, DOC 21-acetate, and 7-mercaptopropionic DOC) have been prepared and purified by high pressure liquid chromatography. Synthesis products have been identified, and three chromophores have been displayed by their n----II and II----II dichroic transitions. A normal half-chair conformation is favored in ring A.


Assuntos
Desoxicorticosterona/análogos & derivados , Desoxicorticosterona/análise , Dicroísmo Circular , Desoxicorticosterona/síntese química , Hidrólise , Conformação Molecular
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