Preparation and Investigation of High Surface Area Aerogels from Crosslinked Polypropylenes.

Polypropylene-based aerogels with high surface area have been developed for the first time. By chemical crosslinking of polypropylene with oligomeric capped-end amino compounds, followed by dissolution, thermally induced phase separation, and the supercritical CO2 drying process or freeze-drying method, the aerogels exhibit high specific surface areas up to 200 m2/g. Moreover, the silica-cage multi-amino compound was utilized in a similar vein for forming hybrid polypropylene aerogels. According to the SEM, the developed polypropylene-based aerogels exhibit highly porous morphology with micro-nanoscale structural features that can be controlled by processing conditions. Our simple and inexpensive synthetic strategy results in a low-cost, chemically resistant, and highly porous material that can be tailored according to end-use applications.

Brake Fluid Condition Monitoring by a Fiber Optic Sensor Using Silica Nanomaterials as Sensing Components.

In the automotive industry, there has been considerable focus on developing various sensors for engine oil monitoring. However, when it comes to monitoring the condition of brake fluid, which is crucial for ensuring safety, there has been a lack of a secure online method for this monitoring. This study addresses this gap by developing a hybrid silica nanofiber mat, or an aerogel integrated with an optical fiber sensor, to monitor brake fluid condition. The incorporation of silica nanofibers in this hybrid enhances the sensitivity of the optical fiber glass surface by at least 3.75 times. Furthermore, creating an air gap between the glass surface of the optical fiber and the nanofibers boosts sensitivity by at least 5 times, achieving a better correlation coefficient (R2 = 0.98). In the case of silica aerogel, the sensitivity is enhanced by 10 times, but this enhancement relies on the presence of the established air gap. The air gap was adjusted to range from 0.5 mm to 1 mm, without any significant change in the measurement within this range. The response time of the developed sensor is a minimum of 15 min. The sensing material is irreversible and has a diameter of 2.5 mm, making it easily replaceable. Overall, the sensor demonstrates strong repeatability, with approximately 90% consistency, and maintains uncertainty levels below 5% across specific ranges: from 3% to 6% for silica aerogel and from 5% to 6% for silica nanofibers in the presence of an air gap. These findings hold promise for integrating such an optical fiber sensor into a car's electronic system, enabling the direct online monitoring of brake fluid quality. Additionally, the study elucidates the effect of water absorption on the refractive index of brake fluid, as well as on the silica nanomaterials.

Flexible Hybrid and Single-Component Aerogels: Synthesis, Characterization, and Applications.

The inherent disadvantages of traditional nonflexible aerogels, such as high fragility and moisture sensitivity, severely restrict their applications. To address these issues, different techniques have been used to incorporate the flexibility in aerogel materials; hence, the term "flexible aerogels" was introduced. In the case of introducing flexibility, the organic part is induced with the inorganic part (flexible hybrid aerogels). Additionally, some more modern research is also available in the fabrication of hybrid flexible aerogels (based on organic-organic), the combination of two organic polymers. Moreover, a new type (single-component flexible aerogels) are quite a new category composed of only single materials; this category is very limited, charming to make the flexible aerogels pure from single polymers. The present review is composed of modern techniques and studies available to fabricate hybrid and single-component flexible aerogels. Their synthesis, factors affecting their parameters, and limitations associated with them are explained deeply. Moreover, a comparative analysis of drying methods and their effectiveness in the development of structures are described in detail. The further sections explain their properties and characterization methods. Eventually, their applications in a variety of multifunctional fields are covered. This article will support to introduce the roadmap pointing to a future direction in the production of the single-component flexible aerogel materials and their applications.

Hybrid and Single-Component Flexible Aerogels for Biomedical Applications: A Review.

The inherent disadvantages of traditional non-flexible aerogels, such as high fragility and moisture sensitivity, severely restrict their applications. To address these issues and make the aerogels efficient, especially for advanced medical applications, different techniques have been used to incorporate flexibility in aerogel materials. In recent years, a great boom in flexible aerogels has been observed, which has enabled them to be used in high-tech biomedical applications. The current study comprises a comprehensive review of the preparation techniques of pure polymeric-based hybrid and single-component aerogels and their use in biomedical applications. The biomedical applications of these hybrid aerogels will also be reviewed and discussed, where the flexible polymeric components in the aerogels provide the main contribution. The combination of highly controlled porosity, large internal surfaces, flexibility, and the ability to conform into 3D interconnected structures support versatile properties, which are required for numerous potential medical applications such as tissue engineering; drug delivery reservoir systems; biomedical implants like heart stents, pacemakers, and artificial heart valves; disease diagnosis; and the development of antibacterial materials. The present review also explores the different mechanical, chemical, and physical properties in numerical values, which are most wanted for the fabrication of different materials used in the biomedical fields.

Aerogels for Biomedical, Energy and Sensing Applications.

The term aerogel is used for unique solid-state structures composed of three-dimensional (3D) interconnected networks filled with a huge amount of air. These air-filled pores enhance the physicochemical properties and the structural characteristics in macroscale as well as integrate typical characteristics of aerogels, e.g., low density, high porosity and some specific properties of their constituents. These characteristics equip aerogels for highly sensitive and highly selective sensing and energy materials, e.g., biosensors, gas sensors, pressure and strain sensors, supercapacitors, catalysts and ion batteries, etc. In recent years, considerable research efforts are devoted towards the applications of aerogels and promising results have been achieved and reported. In this thematic issue, ground-breaking and recent advances in the field of biomedical, energy and sensing are presented and discussed in detail. In addition, some other perspectives and recent challenges for the synthesis of high performance and low-cost aerogels and their applications are also summarized.

Hybrid and Synthetic FRP Composites under Different Strain Rates: A Review.

As a high-demand material, polymer matrix composites are being used in many advanced industrial applications. Due to ecological issues in the past decade, some attention has been paid to the use of natural fibers. However, using only natural fibers is not desirable for advanced applications. Therefore, hybridization of natural and synthetic fibers appears to be a good solution for the next generation of polymeric composite structures. Composite structures are normally made for various harsh operational conditions, and studies on loading rate and strain-dependency are essential in the design stage of the structures. This review aimed to highlight the different materials' content of hybrid composites in the literature, while addressing the different methods of material characterization for various ranges of strain rates. In addition, this work covers the testing methods, possible failure, and damage mechanisms of hybrid and synthetic FRP composites. Some studies about different numerical models and analytical methods that are applicable for composite structures under different strain rates are described.