Effects and applications of surfactants on the release, removal, fate, and transport of microplastics in aquatic ecosystem: a review.

Microplastics (MPs) and surfactants (STs) are emerging pollutants in the environment. While many studies have focused on the interactions of STs with MPs, there has not been a comprehensive review focusing on the effect of STs on MPs in aquatic ecosystems. This review summarizes methods for removal of MPs from wastewater (e.g., filtration, flotation, coagulation/flocculation, adsorption, and oxidation-reduction) and the interactions and effects of STs with MPs (adsorption, co-adsorption, desorption, and toxicity). STs can modify MPs surface properties and influence their removal using different wastewater treatments, as well as the adsorption-desorption of both organic and inorganic chemicals. The concentration of STs is a crucial factor that impacts the removal or adsorption of pollutants onto MPs. At low concentrations, STs tend to facilitate MPs removal by flotation and enhance the adsorption of pollutants onto MPs. High ST concentrations, mainly above the critical micelle concentrations, cause MPs to become dispersed and difficult to remove from water while also reducing the adsorption of pollutants by MPs. Excess STs form emulsions with the pollutants, leading to electrostatic repulsion between MPs/STs and the pollutant/STs. As for the toxicity of MPs, the addition of STs to MPs shows complicated results, with some cases showing an increase in toxicity, some showing a decrease, and some showing no effect.

Degradation rates of phorbol esters in Jatropha curcas L. oil and pressed seeds under different storage conditions.

BACKGROUND: Phorbol esters (PEs), found in Jatropha curcas crude oil (JCO) and J. curcas pressed seeds (JPS), are known as bioactive compounds in agricultural and pharmaceutical applications. The degradation rates of PEs in JCO and JPS under various conditions is important for the utilisation of PEs. Thus the objective of this study was to determine the PE degradation rates in JCO and JPS under different storage conditions. RESULTS: PE degradation rates were found to be first-order reactions. The slowest degradation rate was at 0.9 × 10-3 d-1 for both JCO and JPS unexposed to light at 4 °C. Light intensity (1097 lx and 4690 lx, representing diffused sunlight and fluorescent lighting, respectively) and temperature (25 to 35 °C) were the significant degradation factors. Light exposure led to 280% to 380% higher degradation rates in JCO than in JPS due to light penetration through the transparent oil. Dried and sterilised JPS showed an 80% to 90% lower PE degradation rate than untreated JPS under all storage conditions since biodegradation was assembly limited. CONCLUSION: The PEs were unstable under the studied conditions, especially when exposed to light and room temperature. To protect against PE degradation, a material should be stored in a light-protected container and below 4 °C. © 2016 Society of Chemical Industry.