Neem extract-blended nanocellulose derived from jackfruit peel for antibacterial packagings.

The use of jackfruit peel as a source for natural and fully biodegradable "nanocellulose" (NC) for the production of bioplastics with Azadirachta indica (A. indica) extracts and polyethylene glycol (PEG) for the antibacterial properties is investigated. The characterization of the biocomposite using FT-IR and WXRD was reported. The physicochemical properties including thickness, moisture content, water holding capacity, swelling, porosity, and biodegradability in soil were investigated. The incorporation of A. indica extract revealed an increased shelf life due to the strong antibacterial activity, and these biocomposites were degraded in soil within 60 days after the end use without any harm to the environment. Jackfruit-derived nanocellulose film blended with A. indica extract exhibited strong antibacterial activity against gram-positive and gram-negative food spoilage bacteria. Disc diffusion assay, live/dead assay, and CFU analysis confirmed the antibacterial property of the synthesized film. Moreover, the films clearly prevented the biofilm formation in bacteria. Thus, the developed bioplastics can be utilized as appropriate substitutes to food packaging materials and also for biomedical applications such as wound dressings.

Enhancement of mechanical and thermal properties of Ixora coccinea L. plant root derived nanocellulose using polyethylene glycol-glutaraldehyde system.

Nanocellulose fibers are widely acknowledged as a more sustainable alternative to polyimide and polyethylene terephthalate-based plastic films derived from petrochemicals. Cellulose is also utilised in packaging, tissue engineering, electronic, optical, and sensor applications, pharmaceutical applications, cosmetic applications, insulation, water filtration, and hygiene applications, as well as vascular grafts. In the present study to improve the tensile and thermal properties of cellulose nanofibers, polyethylene glycol (PEG 600) with varying concentrations was produced by solvent casting and chemically crosslinked with glutaraldehyde (GA). The effects of various PEG 600 concentrations on nanofibers and the morphology of the resulting nanofibers were investigated. The effects of GA on PEG-nanocellulose morphology, average diameter, tensile strength, elongation, and thermal characteristics were investigated. Strong (GA)-based acetal linkages are used to substitute secondary hydrogen bonds in nanocellulose films. The 1% PEG 600 plasticized nanocellulose scaffolds cross-linked with GA showed a higher tensile modulus (93 MPa) than its GA untreated nanocellulose scaffolds (69 MPa). The Young's modulus of the scaffold is increased up to 83.62 MPa. The crystallinity index values of GA-treated scaffolds were increased, and the mechanical characteristics were greatly improved, according to Fourier transform infrared (FTIR) and XRD analysis on the films. The thermogravimetric analysis (TG/DTG/DSC) of the GA treated plasticized nanocellulose scaffold showed maximum decomposition temperature (Tmax) at 360.01 °C.

Microbial valorization of lignin: Prospects and challenges.

Lignin is the world's second most prevalent biomaterial, but its effective value-added product valorization methods are still being developed. The most common preparation processes for converting lignin to platform chemicals and biofuels are fragmentation and depolymerization. Due to its structural diversity, fragmentation generally produces a variety of products, necessitating tedious separation and purifying methods to isolate the desired products. Bacterial-based techniques are commonly utilized for lignin fragmentation due to their high metabolitic activity. Recent advancements in lignin valorization utilizing bacteria, such as lignin decomposing microbes and major pathways involved that can breakdown lignin into various valuable products namely lipids, furfural, vanillin, polyhydroxybutyrate, poly lactic acid blends were discussed in this review. This review also covers the genetic and fermentation methodologies to enhance lignin decomposition, challenges and future trends of microbe based lignin valorization.

Nanocellulose as green material for remediation of hazardous heavy metal contaminants.

Heavy metal pollution generated by urban and industrial activities has become a major global concern due to its high toxicity, minimal biodegradability, and persistence in the food chain. These are the severe pollutants that have the potential to harm humans and the environment as a whole. Mercury, chromium, copper, zinc, cadmium, lead, and nickel are the most often discharged hazardous heavy metals. Nanocellulose, reminiscent of many other sustainable nanostructured materials, is gaining popularity for application in bioremediation technologies owing to its many unique features and potentials. The adsorption of heavy metals from wastewaters is greatly improved when cellulose dimension is reduced to nanometric levels. For instance, the adsorption efficiency of Cr3+ and Cr6+ is found to be 42.02% and 5.79% respectively using microcellulose, while nanocellulose adsorbed 62.40% of Cr3+ ions and 5.98% of Cr6+ ions from contaminated water. These nanomaterials are promising in terms of their ease and low cost of regeneration. This review addresses the relevance of nanocellulose as biosorbent, scaffold, and membrane in various heavy metal bioremediation, as well as provides insights into the challenges, future prospects, and updates. The methods of designing better nanocellulose biosorbents to improve adsorption efficiency according to contaminant types are focused.

Lignocellulose in future biorefineries: Strategies for cost-effective production of biomaterials and bioenergy.

Lignocellulosic biomass has been emerging as a biorefinery precursor for variety of biofuels, platform chemicals and biomaterials because of its specific surface morphology, exceptional physical, chemical and biological characteristics. The selection of proper raw materials, integration of nano biotechnological aspects, and designing of viable processes are important to attain a cost-effective route for the development of valuable end products. Lignocellulose-based materials can prove to be outstanding in terms of techno-economic viability, as well as being environmentally friendly and reducing effluent load. This review should facilitate the identification of better lignocellulosic sources, advanced pretreatments, and production of value-added products in order to boost the future industries in a cleaner and safer way.

Bacterial nanocellulose: engineering, production, and applications.

Bacterial nanocellulose (BNC) has been emerging as a biomaterial of considerable significance in a number of industrial sectors because of its remarkable physico-chemical and biological characteristics. High capital expenses, manufacturing costs, and a paucity of some well-scalable methods, all of which lead to low BNC output in commercial scale, are major barriers that must be addressed. Advances in production methods, including bioreactor technologies, static intermittent, and semi-continuous fed batch technologies, and innovative outlay substrates, may be able to overcome the challenges to BNC production at the industrial scale. The novelty of this review is that it highlights genetic modification possibilities in BNC production to overcome existing impediments and open up viable routes for large-scale production, suitable for real-world applications. This review focuses on various production routes of BNC, its properties, and applications, especially the major advancement in food, personal care, biomedical and electronic industries.

Nanobiocatalysts: Advancements and applications in enzyme technology.

Nanobiocatalysts are one of the most promising biomaterials produced by synergistically integrating advanced biotechnology and nanotechnology. These have a lot of potential to improve enzyme stability, function, efficiencyand engineering performance in bioprocessing. Functional nanostructures have been used to create nanobiocatalystsbecause of their specific physicochemical characteristics and supramolecular nature. This review covers a wide range of nanobiocatalysts including polymeric, metallic, silica and carbon nanocarriers as well as their recent developments in controlling enzyme activity. The enormous potential of nanobiocatalysts in bioprocessing in designing effective laboratory trials forapplications in various fields such as food, pharmaceuticals, biofuel, and bioremediation is also discussed extensively.

Potential of nanocellulose for wastewater treatment.

Wastewater management has significant interest worldwide to establish viable treatment techniques to ensure the availability of clean water. The specialities of nanocellulose for this particular application is due to their high aspect ratio and accessibility of plenty of -OH groups for binding with dyes, heavy metals and other pollutants. This review aggregates the application of nanocellulose for wastewater treatment particularly as adsorbents of dyes and heavy metals, and also as membranes for filtering various other contaminants including microbes. The membrane technologies are proven to be effective relating to their durability and separation effectiveness. The commercial scale application of nanocellulose based materials in water treatment processes depend on various factors like routes of synthesis, surface modifications, hydrophilic/hydrophobic, porosity, durability etc. The recent developments on production of novel adsorbents or membranes encourage the implementation of nanocellulose based cleaner technologies for wastewater treatment.

Advanced biomaterials for sustainable applications in the food industry: Updates and challenges.

Maintaining the safety and quality of food are major concerns while developing biomaterial based food packaging. It offers a longer shelf-life as well as protection and quality control to the food based on international standards. Nano-biotechnology contributes to a far extent to make advanced packaging by developing multifunctional biomaterials for potential applications providing smarter materials to consumers. Applications of nano-biocomposites may thus help to deliver enhanced barrier, mechanical strength, antimicrobial and antioxidant properties to novel food packaging materials. Starch derived bioplastics, polylactic acid and polyhydroxybutyrate are examples of active bioplastics currently in the food packaging sector. This review discusses the various types of biomaterials that could be used to improve future smarter food packaging, as well as biomaterials' potential applications as food stabilizers, pathogen control agents, sensors, and edible packaging materials. The regulatory concerns related to the use of biomaterials in food packaging and commercially available biomaterials in different fields are also discussed. Development of novel biomaterials for different food packaging applications can therefore guarantee active food packaging in future.

Development of an eco-friendly biodegradable plastic from jack fruit peel cellulose with different plasticizers and Boswellia serrata as filler.

Pure nanocellulose was extracted from agricultural waste material namely jackfruit (Artocarpus heterophyllus) peel through acid hydrolysis. The extraction method utilizes soapnut solution as an eco-friendly bleaching agent in order to avoid environment polluting chlorinated chemicals. Various thin films were prepared by solvent casting nanocellulose and different plasticizers namely glycerol, polyethylene glycol, polyvinyl alcohol, triethyl citrate along with novel filler, Boswellia serrata commonly known as frankincense. Thin films were characterized by FT-IR, XRD and the surface modifications were investigated using FESEM. The physical, mechanical, thermal properties and biodegradability of the film were also reported. The surface morphology was improved by different plasticizers and a self-assembly was obtained due to more stable hydrogen bonding between the nanocellulose, plasticizers and filler during the film formation. Thermal investigations of plasticizers/Boswellia serrata incorporated thin films revealed an increase in glass transition temperature of nanocellulose. Results indicate that these films are biodegradable and compostable in nature and could be used as substitute for petroleum derived plastics.