RESUMO
The effect of MoS2 nanosheet (NS) decoration on the gas-sensing properties of SnO2 nanofibers (NFs) was investigated. The decorated sensors were fabricated by facile on-chip electrospinning technique and subsequently dropping MoS2 NSs-dispersed solution. The MoS2 NS decoration resulted in enhanced the response and reduced the operating temperature of SnO2 NFs towards SO2 gas. The SnO2 NF sensor decorated with the optimum density of MoS2 NSs exhibited about 10-fold enhancement in gas response to 10 ppm SO2 at 150 °C as compared with the bare SnO2 NF sensor. Furthermore, the decorated sensors exhibited an extremely low detection limit and good selectivity for SO2 gas against other interfering gases, such as CO, NH3, and H2. The enhanced SO2 gas-sensing performance of MoS2 NSs-decorated SnO2 NFs was attributed to the chemical sensitization of MoS2 NSs and charge transfer through heterojunctions between the NSs and SnO2 nanograins. The classification of toxic gases such as CO, H2, and NH3 by the MoS2 NSs-decorated SnO2 NF sensors can achieve high accuracy with linear discriminant analysis (LDA). Our results suggest that the one-dimensional nanostructures of semiconductor metal oxides decorated with two-dimensional transition metal dichalcogenides are attractive candidates for the detection of hazardous gases.
RESUMO
The selective detection and classification of NH3 and H2S gases with H2S gas interference based on conventional SnO2 thin film sensors is still the main problem. In this work, three layers of SnO2/Pt/WO3 nanofilms with different WO3 thicknesses (50, 80, 140, and 260 nm) were fabricated using the sputtering technique. The WO3 top layer were used as a gas filter to further improve the selectivity of sensors. The effect of WO3 thickness on the (NH3, H2, and H2S) gas-sensing properties of the sensors was investigated. At the optimal WO3 thickness of 140 nm, the gas responses of SnO2/Pt/WO3 sensors toward NH3 and H2 gases were slightly lower than those of Pt/SnO2 sensor film, and the gas response of SnO2/Pt/WO3 sensor films to H2S gas was almost negligible. The calcification of NH3 and H2 gases was effectively conducted by machine learning algorithms. These evidences manifested that SnO2/Pt/WO3 sensor films are suitable for the actual NH3 detection of NH3 and H2S gases.
RESUMO
In the current work, we report the on-chip fabrication of a low-temperature H2S sensor based on p-type Co3O4 nanofibers (NFs) using the electrospinning method. The FESEM images show the typical spider-net like morphologies of synthesized Co3O4 NFs with an average diameter of 90 nm formed on the comb-like electrodes. The EDX data indicate the presence of Co and O elements in the NFs. The XRD analysis results confirm the formation of single-phase cubic spinel nanocrystalline structures (Fd3 m) for the synthesized Co3O4 NFs. The Raman results are in agreement with the XRD data through the presence of five typical vibration modes of the nanocrystalline Co3O4. The gas sensing properties of the fabricated Co3O4 NF sensors are tested to 1 ppm H2S within a temperature range of 150 °C to 450 °C. The results indicate a highest sensor response to 1 ppm H2S with the gas response of aproximately 2.1 times and the gas response/recovery times of 75 s/258 s at a low temperature of 250 °C. The fabricated sensor also demonstrates good selectivity and a low detection limit of 18 ppb. The overall results suggest a simple and effective fabrication process for the p-type Co3O4 NF sensor for practical applications in detecting H2S gas at low temperature.
