RESUMO
Amorphous nanomaterials have aroused extensive interest due to their unique properties. Their performance is highly related with their distinct atomic arrangements, which have no long-range order but possess short- to medium-range order. Herein, an overview of state-of-the-art synthesis methods of amorphous nanomaterials, structural characteristics and their electrochemical properties is presented. Advanced characterization methods for analyzing and proving the local order of amorphous structures, such as X-ray absorption fine structure spectroscopy, atomic electron tomography and nanobeam electron diffraction, are introduced. Various synthesis strategies for amorphous nanomaterials are covered, especially the salt-assisted metal organic decomposition method to prepare ultrathin amorphous nanosheets. Furthermore, the design and structure-activity relationship of amorphous nanomaterials towards electrochemical applications, including electrocatalysts and battery anode/cathode materials, is discussed.
