Recent Progress in Metal Nanowires for Flexible Energy Storage Devices.

With the rapid evolution of wearable electronics, the demand for flexible energy storage devices is gradually increasing. At present, the commonly used energy storage devices in life are based on rigid frames, which may lead to failure or explosion when mechanical deformation occurs. The main reason for this phenomenon is the insufficient elastic limit of the metal foil current collector with a simple plane structure inside the electrodes. Obviously, the design and introduction of innovative structural materials in current collectors is the key point to solving this problem. Several recent studies have shown that metal nanowires can be used as novel current collector materials to fabricate flexible energy storage devices. Herein, we review the applications of metal nanowires in the field of flexible energy storage devices by selecting the three most representative metals (Au, Ag, and Cu). By the analysis of the various typical literature, the advantages and disadvantages of these three metal nanowires (Au, Ag, and Cu) are discussed respectively. Finally, we look forward to the development direction of one-dimensional (1D) metal nanowires in flexible energy storage devices and show the personal opinions with a reference value, hoping to provide the experience and ideas for related research in the future.

Efficient and reusable ordered mesoporous WO x /SnO2 catalyst for oxidative desulfurization of dibenzothiophene.

The oxidative desulfurization (ODS) of organic sulfur compounds over tungsten oxide supported on highly ordered mesoporous SnO2 (WO x /meso-SnO2) was investigated. A series of WO x /meso-SnO2 with WO x contents from 10 wt% to 30 wt%, were prepared by conventional wet impregnation. The physico-chemical properties of the WO x /meso-SnO2 catalysts were characterized by X-ray diffraction (XRD), N2 adsorption-desorption isotherms, electron microscopy, Fourier transform infrared spectroscopy (FT-IR), Raman spectroscopy, and the temperature-programmed reduction of hydrogen (H2-TPR). The characterization results indicated that these catalysts possessed mesoporous structures with uniform pores, high specific surface areas, and well-dispersed polyoxotungstate species on the surface of meso-SnO2 support. The ODS performances were evaluated in a biphasic system (model oil/acetonitrile, S initial = 2000 ppm), using H2O2 as an oxidant, and acetonitrile as an extractant. Dibenzothiophene (DBT) in the model oil was removed completely within 60 min at 50 °C using 20 wt% WO x /meso-SnO2 catalyst. Additionally, the effect of reaction temperature, H2O2/DBT molar ratio, amount of catalyst and different sulfur-containing substrates on the catalytic performances were also investigated in detail. More importantly, the 20 wt% WO x /meso-SnO2 catalyst exhibited 100% surfur-removal efficiency without any regeneration process, even after six times recycling.