[Environmental characterization of the National Contaminated Sites in SENTIERI project]. / Caratterizzazione ambientale dei Siti di Interesse Nazionale per le bonifiche (SIN) nel progetto SENTIERI.

The concept of "polluted site" was firstly introduced in Italy with the definition of "environmental high risk areas" (Rule 349/86). Later, the decree 471/99 stated that a site is considered polluted if the concentration of even just one index pollutant in anyone of the matrices (soil or subsoil, surface or ground waters) exceeds the allowable threshold limit concentration. The boundaries of Italian polluted sites (IPS) were defined (Decree 152/06) on the basis of health, environmental and social criteria. SENTIERI Project includes 44 out of the 57 sites comprised in the "National environmental remediation program"; they correspond to the largest national industrial agglomerates. For each site, characterization data were collected, classified and arranged in tables. A great part of collected data came also from the environmental remediation programmes planned for the sites. These plans show that characterization and risk assessment activities were mainly undertaken for private industrial areas, as they were considered source of pollution. On the other hand, municipal and/or green and agricultural areas included in IPSs were poorly studied. Therefore, it is difficult to assess the exposure of the populations living inside and/or near the IPSs. The most probable population exposure come from the contamination of ground waters utilized for irrigation, or industrial emissions. For a description of SENTIERI, refer to the 2010 Supplement of Epidemiology & Prevention devoted to SENTIERI Project.

Dark nematicons.

We experimentally demonstrate and model dark spatial solitons in azo-doped liquid crystals, in the presence of saturation and nonlocality of the effective nonlinearity due to changes in molecular order. The guiding properties of dark solitons are probed with a weak input of different wavelength.

Nematicon all-optical control in liquid crystal light valves.

We discuss the interactions between self-guided light beams and light-induced perturbations in a liquid crystal light valve. The model and data are in perfect agreement.

Spatial solitons in liquid-crystal light valves.

Liquid-crystal light valves can control the orientation of a nematic layer under the independent or combined action of applied voltage and impinging light intensity; hence, they offer a unique environment for the propagation of spatial optical solitons or nematicons. We demonstrate nematicon excitation, propagation, and steering in photoconductive light valves.

An in vitro investigation of the reductive metabolism of chloroform.

In hypoxic (1% pO2) and anoxic (0% pO2) incubations of CHCl3 with rat liver microsomes from PB-induced animals, no evidence of formation of monochloromethyl carbene could be found. Dichloromethane was detected as a volatile metabolite of CHCl3 in incubations with rat liver microsomes from PB-induced animals, under different oxygenation conditions (from 0% to 20% pO2). With uninduced microsomes, significant levels of dichloromethane were formed only in hypoxic (1% pO2) or anoxic incubations. The amount of dichloromethane measured was 2-6 times lower than the levels of adducts to the fatty acyl chains (FC) of microsomal phospholipid. The very low rate of dichloromethane formation suggests that the assay of expired dichloromethane is not suitable to detect the reductive metabolism of CHCl3 in vivo.