Remarkable Improvement in Hydrogen Sensing Characteristics with Pt/TiO2 Interface Control.

Owing to their excellent hydrogen surface susceptibility, TiO2 thin films have been proven worthy of sensing hydrogen. However, these sensors work best at temperatures of 150-400 °C, with poor selectivity and a low response at room temperature. In this context, the novelty of this paper includes an investigation of the critical role of electrode fabrication that is found to significantly define the surface as well as the performance of a sensor. Sensors prepared with optimized conditions showed the best sensor response (SR) of ∼1.58 × 107 toward 10 000 ppm H2 with excellent linearity (R-square ∼ 0.98 for 300-10 000 ppm) at room temperature (∼20 °C). In addition, the said sensor showed a response time of ∼125 s with full baseline recovery and a selectivity factors (SF) of ∼1754, 2456, and 4723 to 1000 ppm of interfering reducing gases CH4, CO, and NH3, respectively, at 100 °C. At room temperature, the selectivity factor (for 300 ppm H2) of the sensor is ∼3.41 to 90% RH and ∼37.35 to 250 ppm oxygen, 200 ppm CO, and 1600 ppm CO2. Last but not least, our X-ray diffraction, X-ray photoelectron spectroscopy, and electrical transport characteristics enabled us to explain the high sensing mechanism on the basis of the estimated grain size, the quantitative atomic composition, the barrier at the Pt/TiO2 interface, and the thermal activation energy (also known as the intergranular barrier height) of the thin films.

Directly created electrostatic micro-domains on hydroxyapatite: probing with a Kelvin Force probe and a protein.

Micro-domains of modified surface potential (SP) were created on hydroxyapatite films by direct patterning by mid-energy focused electron beam, typically available as a microprobe of Scanning Electron Microscopes. The SP distribution of these patterns has been studied on sub-micrometer scale by the Kelvin Probe Force Microscopy method as well as lysozyme adsorption. Since the lysozyme is positively charged at physiological pH, it allows us to track positively and negatively charged areas of the SP patterns. Distribution of the adsorbed proteins over the domains was in good agreement with the observed SP patterns.

Charge specific protein placement at submicrometer and nanometer scale by direct modification of surface potential by electron beam.

The understanding and the precise control of protein adsorption is extremely important for the development and optimization of biomaterials. The challenge resides in controlling the different surface properties, such as surface chemistry, roughness, wettability, or surface charge, independently, as modification of one property generally affects the other. We demonstrate the creation of electrically modified patterns on hydroxyapatite by using scanning electron beam to tailor the spatial regulation of protein adsorption via electrostatic interactions without affecting other surface properties of the material. We show that domains, presenting modulated surface potential, can be created to precisely promote or reduce protein adsorption.

In situ photoexcitation of silver-doped titania nanopowders for activity against bacteria and yeasts.

Photocatalytic and in situ microbial activity of the amorphous and annealed states of Ag-doped and un-doped titania were examined. Studies on their structure, morphology, composition, and the photo-absorption characteristics of these materials were performed. These results were correlated with the photocatalytic and microbial activity against methicillin resistant Staphylococcus aureus K324 (MRSA), methicillin susceptible S. aureus ATCC 25923 (MSSA), Escherichia coli PA 170, and yeasts Candida albicans ATCC 90028. The annealed powders containing anatase form of titania exhibited relatively higher photocatalytic activity,corresponding to activity against MRSA,when exposed to UV-A radiation. In comparison, amorphous powders exhibited low photoactivity and showed poor antibacterial performance against MRSA under UV-A exposure. Doping of amorphous titania with Ag resulted in an anti-MRSA effect without exposure to UV radiation. In the Ag-doped crystalline anatase samples, the size of Ag primary nanocrystallites increased, which led to the decrease in the surface concentration of Ag and detriment anti-MRSA activity.