1.
Acta Crystallogr Sect E Struct Rep Online
; 70(Pt 9): m330-1, 2014 Sep 01.
Artigo
em Inglês
| MEDLINE
| ID: mdl-25309185
RESUMO
In the mononuclear copper(II) title complex, [Cu(C11H16N3O)(H2O)]Br, the Cu(II) atom is coordinated by one O and three N atoms of the Schiff base ligand that forms together with one water mol-ecule a slightly distorted [CuN3O2] square-pyramidal polyhedron. The deviation of the Cu(II) atom from the mean equatorial plane is 0.182â (2)â Å. The equatorial plane is nearly coplanar to the aromatic ring of the ligand [angle between planes = 10.4â (1)°], and the water molecule is situated in the apical site. All coordinating atoms (except the imine nitro-gen) and the bromide ion contribute to the formation of the N-Hâ¯Br, O-Hâ¯Br and O-Hâ¯O hydrogen bonds, which link mol-ecules into chains along [01-1].