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J Nanosci Nanotechnol ; 21(12): 6016-6023, 2021 12 01.
Artigo em Inglês | MEDLINE | ID: mdl-34229799

RESUMO

Manganese dioxide (α-MnO2) and graphene oxide (GO nanocomposites were prepared and successfully characterized using Fourier-transform infrared (FT-IR), field emission scanning-electron microscopy (FE-SEM), and energy-dispersive X-ray spectroscopy (EDX) mapping methods and Xray diffraction (XRD) analyses. This reagent is an efficient catalyst for the aerobic oxidation of trimethylsilyl (TMS), tetrahedropyranyl (THP), and methoxymethyl ethers (MOM) to their corresponding carbonyl compounds in the presence of K2CO3. All reactions were performed in n-hexane under mild and completely heterogeneous reaction conditions. Our novel method has the advantages of excellent yields, short reaction times, availability and reusability of the catalyst and simple and easy work-up procedure compared to the conventional methods reported in the literature.


Assuntos
Nanocompostos , Óxidos , Éteres , Grafite , Compostos de Manganês , Estresse Oxidativo , Espectroscopia de Infravermelho com Transformada de Fourier
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