RESUMO
In the title compound, C15H22N2O·H2O, the dihedral angle between the planes of the piperidine and benzene rings is 31.63â (1)°. The piperidine ring adopts a chair conformation. The water solvent mol-ecule is involved in inter-species O-Hâ¯O, O-Hâ¯N, N-Hâ¯O and weak C-Hâ¯O hydrogen-bonding inter-actions, giving rise to chains extending along [010].
RESUMO
In the title compound, C20H22ClNO, the piperidine ring has a twist-boat conformation. There is an intra-molecular C-Hâ¯π inter-action involving the two phenyl rings which are inclined to one another by 84.91â (7)°. In the crystal, mol-ecules are linked via C-Hâ¯O hydrogen bonds, forming helical chains along [010]. The chains are linked by C-Hâ¯π inter-actions, forming sheets parallel to (100).
RESUMO
In the title compound, C14H19ClN2O2·H2O, the piperdine ring adopts a chair conformation. The dihedral angle between the mean plane of the piperidine ring and that of the phenyl ring is 41.64â (1)°. In the crystal, mol-ecules are linked by O-Hâ¯N, N-Hâ¯O and C-Hâ¯O hydrogen bonds involving the water mol-ecule, forming double-stranded chains propagating along [010].
RESUMO
In the title compound, C20H20Cl2N2O2·H2O, the piperidine ring adopts a chair conformation with the two substituent benzene rings inclined to one another [dihedral angle 84.63â (9)°]. In the crystal, the components are linked by Ow-Hâ¯O, N-Hâ¯Ow (w = water) and C-Hâ¯O hydrogen bonds, generating a sheet structure lying parallel to (101).
RESUMO
In the title compound, C22H27N2O2, the piperidine ring adopts a half-chair conformation with the benzene rings inclined in a trans orientation with respect to the piperidine ring [dihedral angle between the benzene rings = 89.1â (1)°]. In the crystal, a three-centre asymmetric N-Hâ¯O/C-Hâ¯O hydrogen-bonding inter-action leads to the formation of chains extending along the a-axis direction.
RESUMO
In the title moleclue, C16H14O4, the dihedral angle between the benzene rings is 16.1â (3)°. The meth-oxy group is essentially coplanar with the benzene ring to which it is attached, with a C-O-C C torsion angle of 5.5â (9)°. In the crystal, mol-ecules are linked by O-Hâ¯O and bifurcated O-Hâ¯(O,O) hydrogen bonds, forming a three-dimensional network. The structure was refined as a two-component inversion twin.
RESUMO
In the title compound, C23H18O4, the meth-oxy-benzene ring and attached C=C grouping are disordered over two sets of sites in a 0.823â (5):0.177â (5) ratio. The dihedral angles between the central benzene ring and the pendant phenyl and meth-oxy-benzene ring (major orientation) are 51.21â (1) and 51.6â (1)°, respectively. In the crystal, inversion dimers linked by pairs of C-Hâ¯O hydrogen bonds generate R 2 (2)(28) loops.
RESUMO
In the title compound, C20H22N2O2, the piperidine ring adopts a chair conformation. The phenyl rings are inclined to one another by 80.1â (1)° and make dihedral angles of 46.1â (1) and 40.2â (1)° with the mean plane of the piperidine ring. In the crystal, pairs of N-Hâ¯O hydrogen bonds link the mol-ecules into inversion dimers. C-Hâ¯O inter-actions further link the mol-ecules, forming a three-dimensional supramolecular network.
RESUMO
In the title compound, C16H14O4, there is an intra-molecular O-Hâ¯O hydrogen bond. The benzene rings are inclined to one another by 13.89â (9)°. The prop-2-en-1-one group is twisted slightly, the O=C-Car-Car (ar = aromatic) and C=C-C=O torsion angles being -10.4â (3) and -7.4â (3)°, respectively. In the crystal, mol-ecules are linked by O-Hâ¯O hydrogen bonds, forming chains along [100]. These chains are further linked by O-Hâ¯O hydrogen bonds, forming corrugated sheets lying parallel to (010). There are C-Hâ¯π inter-actions present within the sheets.
RESUMO
In the title compound, C16H14O4, the benzene rings are inclined to one another by 4.91â (7)°. The conformation about the C=O and C=C bonds is trans and cis, respectively. In the crystal, mol-ecules are linked by O-Hâ¯O hydrogen bonds, forming inversion dimers with an R 2 (2)(14) ring motif. The dimers are linked via O-Hâ¯O and C-Hâ¯O hydrogen bonds, forming undulating two-dimensional networks lying parallel to (10-1). These networks are linked by further C-Hâ¯O hydrogen bonds, forming a three-dimensional structure.
RESUMO
In the title compound, C19H23N, the piperidine ring has a chair conformation. The phenyl rings are inclined to one another by 52.76â (16)°. One of the methyl substituents on the piperidine ring is axial while the other is equatorial, like the phenyl rings. In the crystal, mol-ecules are linked via C-Hâ¯π inter-actions, forming zigzag chains along [001].
RESUMO
In the title compound, C13H18N2O4, the dihedral angle between the benzene and pyrrolidine (all atoms) rings is 70.6â (1)°. The pyrrolidine ring adopts a half-chair conformation. In the crystal, mol-ecules form chains along the c-axis direction linked by O-Hâ¯N hydrogen bonds, which are then connected by C-Hâ¯O inter-actions, forming a sheet parallel to the bc plane.
RESUMO
In the title compound, C21H24ClNO, the piperidine ring adopts a chair conformation. The two phenyl rings are inclined to one another by 20.7â (1)°, and are inclined to the mean plane of the four planar atoms of the piperidine ring by 87.64â (10) and 70.8â (1)°. The mol-ecular structure features short intra-molecular C-Hâ¯Cl and C-Hâ¯O contacts. In the crystal, there are no significant inter-molecular inter-actions present.