1.
Acta Crystallogr E Crystallogr Commun
; 73(Pt 1): 41-44, 2017 Jan 01.
Artigo
em Inglês
| MEDLINE
| ID: mdl-28083132
RESUMO
The mononuclear mixed-ligand title complex, [CuCl(C7H7N3O2S)(C18H15P)2], displays a distorted tetra-hedral coordination sphere around the CuI atom, with two P atoms from two tri-phenyl-phosphane mol-ecules, one terminal S atom from a 1-(4-nitro-phen-yl)thio-urea mol-ecule and a chloride ion as ligands. An intra-molecular N-Hâ¯Cl hydrogen bond stabilizes the mol-ecular conformation [graph-set motif R22(6)]. In the crystal, further N-Hâ¯Cl hydrogen bonds connect individual mol-ecules into zigzag chains parallel to [001]. The chains are linked by weak C-Hâ¯O hydrogen-bonding inter-actions into a three-dimensional network.