Swimming ability of Schizothoracinae fishes in Yarlung Zangbo River of China.

The Yarlung Zangbo River is a river with abundant hydropower resources but fragile biodiversity in China. As an important benchmark for both research and ecological management, there is still a lack of knowledge about the swimming ability of fishes in the Yarlung Zangbo River. The induced flow velocity (Uind), critical swimming speed (Ucrit), and burst swimming speed (Uburst) of five Schizothoracinae species were tested in this study. Relative swimming ability related to body length and body shape was calculated. The results indicated that the average absolute swimming speeds (Uind-a, Ucrit-a, and Uburst-a) of all the experimental fish were 10.20 ± 0.01, 57.58 ± 3.28, and 69.54 ± 2.94 cm/s, respectively, and the corresponding relative Uind, Ucrit, and Uburst related to body length (Uind-l, Ucrit-l, Uburst-l) were 1.15 ± 0.07, 5.04 ± 0.26, and 7.23 ± 0.28 BL/s, respectively. Moreover, relative Uind, Ucrit, and Uburst related to body shape (Uind-s, Ucrit-s, and Uburst-s) were 0.80 ± 0.13, 2.49 ± 0.51, and 4.32 ± 0.57 cm-2/s, respectively. No significantly differences in relative swimming speeds existed among five species. Only Oxygymnocypris stewartii was significantly weaker in Uburst-s than Schizothorax o'connori. The body shape showed a stronger relationship with swimming speed than the body length did. Schizothoracinae fish in the Yarlung Zangbo River basin are less sensitive to the water flow and performed weaker Ucrit and Uburst compared to those in the Yangtze River basin, indicating that Schizothoracinae fish in the Yarlung Zangbo River may be more susceptible to threats from environmental changes. The paper enriched the research on the swimming ability of Schizothoracinae fishes and provided efficient data for the fish conservation in the Yarlung Zangbo River.

Conflict between urbanization and water environmental protection: Lessons from the Xiangjiang River Basin in China.

China, the largest developing country, has experienced rapid urbanization since its reform and opening-up. However, the increasing pollution load from urban areas has deteriorated urban river water quality, contradicting the concept of sustainable and green development promoted by the Chinese government. This situation elucidates governmental shortcomings in systematic environmental protection. Our study revealed that the current wastewater treatment plant (WWTP) discharge standards in urban areas are insufficient for attaining the desired urban river water quality and thus intensify the conflict between urbanization and water environmental protection. As urbanization continues, the urban population will grow, further exacerbating pollution and conflict. Our focus was the Xiangjiang River basin in Zunyi, a typical urbanized city in China. Using a validated one-dimensional mathematical model, we compared the water quality in the Xiangjiang River between current and upgraded WWTP discharge standards. The results showed that the water quality in the Xiangjiang River falls short of the standards, with more than 60 % of the river exceeding limits. However, upgrading WWTP discharge standards significantly reduces the proportion of river sections exceeding limits, with only 0.4 % exceeding standards during specific periods. This enhancement greatly improved the Xiangjiang River's water quality, aided in restoring the entire water environment in the basin, and supported water environmental protection goals. Our research findings offer crucial support for local governments in shaping comprehensive water environmental protection policies and insights for addressing similar environmental challenges caused by rapid urbanization in other developing regions.

Study of the characteristics of pollutants in rural domestic sewage and the optimal sewage treatment process: a Chengdu Plain case study.

Domestic sewage is an important source of surface water pollution in the rural areas of developing countries, especially in the rural areas of China. In recent years, with the strategy of rural revitalization, China has paid increasing attention to the treatment of rural domestic sewage. Therefore, 16 villages in the Chengdu Plain were selected for the study, and seven indicators were analyzed and evaluated, including pH, five-day biochemical oxygen demand (BOD5), chemical oxygen demand (COD), ammonia nitrogen (NH3-N), total phosphorus (TP), suspended solids (SS) and total nitrogen (TN), in the water samples at the inlet and outlet of the wastewater treatment plant. The concentration of each pollutant in the rural scattered domestic sewage of the Chengdu Plain in Southwest China was obtained, and the concentration of each pollutant in domestic sewage was higher than that in summer. In addition, the preferred process for removing each pollutant was obtained by studying the effects of the treatment process, season and hydraulic retention time on the removal efficiency of each pollutant. The research results provide valuable references for the planning and process selection of rural domestic sewage treatment.

Synthesis of bifunctional NiFe layered double hydroxides (LDH)/Mo-doped g-C3N4 electrocatalyst for efficient methanol oxidation and seawater splitting.

To boost the oxygen evolution reaction (OER) and methanol oxidation reaction (MOR) of pristine NiFe-layered double hydroxides (LDH), the NiFe-LDH/Mo-doped graphitic carbon nitride (NiFe-LDH/MoCN) heterojunction was synthesized herein through hydrothermal method. The establishment of built-in electric field in NiFe-LDH/MoCN heterojunction enhanced the electrochemical oxidation activities towards both seawater splitting and methanol oxidation, via the improving electrocatalyst surface wettability and conductivity. Almost 10-fold enhancement of turnover frequency (TOF) and electrochemical active surface area (ECSA) than pure NiFe-LDH implied more active sites to participate in catalytic reactions via Mo doping and the formation of heterostructure. Moreover, the local charge redistribution demonstrated in the NiFe-LDH/MoCN interface region may favor the adsorption of methanol and OH- in the seawater. The present work may expound the strong coupling interaction and the establishment of built-in electric field in the interface between NiFe-LDH and semiconductor to enhance both methanol oxidation and seawater oxidation for NiFe-LDH.

The characterization of a novel magnetic biochar derived from sulfate-reducing sludge and its application for aqueous Cr(â ¥) removal through synergistic effects of adsorption and chemical reduction.

Removal of heavy metals from the aqueous environment via physiochemical adsorption always remains a great challenge owing to the slow kinetics and low removal capacity for the conventional adsorbent. In this study, the sulfate-reducing bacteria (SRB)-rich anaerobic sludge was pyrolyzed for the preparation of magnetic biochar, i.e. SBC-20-500 (SBC: sulfate-reducing sludge-based biochar; 20 denotes the biochar dosage, namely 8 g dried sludge in 400 mL iron solution which is equal to 20 g/L; 500 represents the pyrolysis temperature, i.e. at 500 °C) with tunable pore structure and surface properties towards efficient removal of chromium (Cr (Ⅵ)). The characterization revealed that magnetic biochar SBC-20-500 exhibited higher surface area and larger pore volume compared to non-magnetic SBC-500. Batch experiments on Cr (Ⅵ) removal were performed under different biochar dosages, pH values, initial Cr (Ⅵ) concentrations and temperatures. The results illustrated that magnetic biochar demonstrated much larger Cr (Ⅵ) adsorption capacity with qe of 5.3585 mg/g as compared to non-modified one (qe = 0.7206 mg/g). The maximum Cr (Ⅵ) removal efficiency of SBC-20-500 reached approximately 93.7% within 24 h under the conditions of pH = 3.0, biochar dosage = 0.8 g and initial Cr (Ⅵ) concentration = 50 mg/L. The kinetic and isotherm fitting results suggested that the pseudo-second-order kinetic and Langmuir isotherm model were more suitable for describing the adsorption behavior of Cr (Ⅵ) by SBC-20-500. The XPS and FTIR results confirmed that chemical reduction of Cr (Ⅵ) to Cr (Ⅲ) also played a role in Cr (Ⅵ) removal in the presence of SBC-20-500. Moreover, the Cr (Ⅵ) removal capacity could still achieve 3.50 mg/g even after five adsorption-desorption cycles, indicating the satisfactory reusability of the as-prepared biochar. The results of this study may provide a win-win approach for simultaneous resource recovery from the wasted sulfate-reducing sludge (SRS) and highly-efficient remediation of Cr (Ⅵ)-contaminated environment.

Impacts of water temperature on phosphorus release of sediments under flowing overlying water.

River sediment typically acts a 'sink' or 'source' of phosphorus for the overlying water owing to the adsorption of phosphorous by the sediment or release of phosphorous to the water, respectively. In this study, a method is proposed for the determination of the equilibrium concentration of the total phosphorus (ECTP) and total phosphorus release rate (Rr). Phosphorus release experiments were conducted on natural river sediments in flowing water with a low velocity under different water temperatures. An empirical equation was established for the correlation between ECTP and Rr at an arbitrary temperature and at 20 °C. The results indicate that an increase in the water temperature significantly enhances the phosphorus release. In comparison with total phosphorus, dissolved phosphorus and particulate phosphorus in the overlying water do not change with the water temperature. Thus, the results of this study aid in understanding the contaminant exchange between sediments and water in flowing rivers.

Contribution of heavy metal in driving microbial distribution in a eutrophic river.

Urban rivers represent an important source of freshwater. Accelerated urban development has resulted in imbalances in the water ecological environment and even eutrophication. Moreover, both natural and anthropogenic sources result in frequent heavy metal pollution in urban rivers. However, the combined impact of eutrophication and heavy metal pollution on the diversity and structure of the river microbial communities has not been adequately addressed. The microbial community distribution and predicted functions were examined in six water and sediment samples from the Laojingshui (LJS) River using metagenomic sequencing. The results showed that there were distinct differences in the microbial composition along the river. Redundancy analysis (RDA) revealed that the redox potential (Eh) was the most influential factor, explaining 76.5% of the variation (p = 0.002), and the heavy metals Zn and Cu explained 4.5 and 3.9%, respectively (p < 0.05). The results revealed that high nitrogen and phosphorus concentrations may have affected the proliferation of opportunistic plant species, such as Eichhornia crassipes, but Eh and heavy metals may have had greater impacts than N and P on the microorganisms in the water and sediment. The sensitivities of Deltaproteobacteria, Acidobacteria, Gemmatimonadetes and Nitrospira were most significant under Zn and Cu contamination when accompanied by eutrophic conditions. The expression ratio of the CYS (Cystain) gene might explain why the spatial distribution of each metal differed. This study suggests that heavy metals in eutrophication water continue to be the main factors determining the composition of microbial community, so the treatment of eutrophic water still needs to attach great importance to the complex pollution of heavy metals.

Experimental Research on the Degradation Coefficient of Ammonia Nitrogen Under Different Hydrodynamic Conditions.

Degradation coefficients for pollutants in water are important parameters that are significantly influenced by environmental conditions. In controlled experiments, the processes and trends of ammonia nitrogen (NH3-N) degradation in raw waters were studied under different flow conditions using a laboratory annular flume. Analysis of the observed change in NH3-N concentration with time under various flow conditions allowed calculation of a degradation efficiency (concentration change amount/initial concentration) which for NH3-N increased as the flow velocity increased. According to a first-order kinetic equation to fit the experimental data, the range of variation of the degradation coefficient of NH3-N at different flowrates was between 0.047 per day (0.01 m/s) and 0.203 per day (0.30 m/s). Dimensional analysis was used to analyze the relationship between the degradation coefficient and flow velocity (v), water depth (H), Froude number (Fr), and Reynolds number (Re), which was verified through field data collected in the Chishui River.

Experimental Investigation on the Relationship Between COD Degradation and Hydrodynamic Conditions in Urban Rivers.

Due to extensive pollution and the relatively weak flow replacement in urban rivers, determining how to fully utilize the self-purification abilities of water bodies for water quality protection has been a complex and popular topic of research and social concern. Organic pollution is an important type of urban river pollution, and COD (chemical oxygen demand) is one of the key pollution factors. Currently, there is a lack of research on the relationship between COD degradation and the flow characteristics of urban rivers. In this paper, COD degradation experiments were conducted in an annular flume with Jinjiang River water at controlled flow velocities and the COD degradation coefficients under different hydraulic conditions were analyzed. A good correlation was observed between the degradation coefficient and hydraulic conditions. According to dimensional analysis, the relationship between the COD degradation coefficient and hydraulic conditions such as the flow velocity, water depth, Reynolds number (Re), and Froude number (Fr) was established as K COD = 86400 u h F r 0.8415 R e - 1.2719 + 0.258 . The COD degradation coefficients of the Chishui River in Guizhou Province ranged from 0.175-0.373 1/d based on this formula, and the field-measured values varied from 0.234-0.463 1/d. The error in the formula ranged from 5.4-25.3%. This study provides a scientific basis for the prediction of the COD degradation coefficients of urban rivers.

[Spatiotemporal Succession Characteristics of Algal Functional Groups and Its Impact Factors for a Typical Channel-Type Reservoir in a Southwest Mountainous Area].

In order to explore the spatial and temporal variations of algal functional groups in the Zipingpu reservoir, a typical channel-type reservoir in the southwest mountainous area of China, water samples were collected from eight sections of the Zipingpu reservoir from April 2016 to March 2017.A total of 21 algal functional groups were identified as B, C, D, F, G, H1, J, L0, LM, MP, N, P, S2, T, W1, W2, X1, X2, X3, Y, and Z. Based on the analysis of the dominant degree (y > 0.02), the algal functional groups were dominated by W2, Y, L0, W1, MP, and B. The C-R-S strategy of algal growth in the Zipingpu reservoir showed that R-type was a more dominant type than the S- and C-type for the majority of the time. Peridinium (group L0, type S) was the significant algae in the Zipingpu reservoir algal bloom event in June 2016.Redundancy analysis (RDA) was used to explore the relationship between algal functional groups and environmental factors. The results showed that algal density, chlorophyll a, water temperature, and biochemical oxygen demand were the major factors influencing the spatiotemporal succession of algal functional groups across the eight sampling sections, with water temperature having the highest influence.

Degradation of pentachlorophenol by pure and mixed cultures in two different soils.

GOAL, SCOPE AND BACKGROUND: Pentachlorophenol (PCP) is the second highest volume pesticide used in the United States. It is a mutagenic compound whose exposure poses significant health effects, One of the most desirable, environmentally friendly treatment methods is bioremediation. For soil-based contamination, the effectiveness of bioremediation will also be affected by the presence of an active indigenous population, sorption of the contaminant onto the soil, and environmental parameters. METHODS: Two pure strains and their mixed culture were used to evaluate PCP biodegradation in two different field soils, Columbia (CO) and New Mexico (NM). Biostimulation of the indigenous microbes was evaluated by adding nutrients. The efficiency of adding bacteria strains (bioaugmentation) for degrading PCP was determined with Arthrobacter sp., Flavobacterium sp. and a 50:50 mixture of the two bacteria strains. RESULTS: In CO soil, only 24%, 12% and 25% of the initial PCP concentration were degraded by Flavobacterium sp., Arthrobacter sp. and mixed culture, respectively. Arthrobacter sp. was used in NM soil with two initial concentrations and achieved degradation efficiencies of 57% and 61% for 361 and 95 mg kg- concentrations, respectively. Discussion. Analysis via statistical methods showed that the bacteria had different efficiencies on PCP degradation in each soil. 2 CONCLUSIONS: All bacteria catalyzed a higher PCP degradation when present in NM soil. Second, Flavobacterium sp. degraded more PCP than Arthrobacter sp. in CO soil. The mixed culture achieved the highest degradation efficiency regardless of the initial concentration or soil origin. RECOMMENDATIONS AND PERSPECTIVES: The effect of the soil properties, such as the soil organic matter (SOM) on PCP biodegradation should be investigated. Future work can also investigate the effect of aging time on biodegradation.

Sorption-desorption behavior of PCP on soil organic matter and clay minerals.

Pentachlorophenol (PCP) contamination is a severe environmental problem due to its widespread occurrence, toxicity and recalcitrance. In order to gain a better understanding of the fate of PCP in soils, the role of the soil organic matter (SOM) and clay minerals in the PCP sorption-desorption was studied on two bulk field soils, two subsoils (i.e., SOM or clay-removed soil) and two artificial soils. The two field soils used were a silty loam from New Mexico (NM) containing 10% clay and a sandy-clay-loam from Colombia (CO) South America comprised of 18% clay minerals. The bulk CO soil containing kaolinite sorbed significantly less PCP than the NM soil. All soils depicted an apparent hysteresis during sorption. The CO bulk and subsoils desorbed 14-20% and 15-26% of the sorbed PCP respectively whereas the NM bulk and subsoils desorbed only 4-12% and 5-16%, respectively. Experiments conducted with pure clay and artificial soils indicated that the expandable clay minerals were key sorbent material. Additional studies to investigate the interaction between SOM and clay minerals are needed to fully understand sorptive phenomena.