Recent Progress in Screening of Mycotoxins in Foods and Other Commodities Using MXenes-Based Nanomaterials.

Mycotoxin pollution in agricultural food products endangers animal and human health during the supply chains, therefore the development of accurate and rapid techniques for the determination of mycotoxins is of great importance for food safety guarantee. MXenes-based nanoprobes have attracted enormous attention as a complementary analysis and promising alternative strategies to conventional diagnostic methods, because of their fascinating features, like high electrical conductivity, various surface functional groups, high surface area, superb thermal resistance, good hydrophilicity, and environmentally-friendlier characteristics. In this study, we outline the state-of-the-art research on MXenes-based probes in detecting various mycotoxins like aflatoxin, ochratoxin, deoxynivalenol, zearalenone, and other toxins as a most commonly founded mycotoxin in the agri-food supply chain. First, we present the diverse synthesis approaches and exceptional characteristics of MXenes. Afterward, based on the detecting mechanism, we divide the biosensing utilizations of MXenes into two subcategories: electrochemical, and optical biosensors. Then their performance in effective sensing of mycotoxins is comprehensively deliberated. Finally, present challenges and prospective opportunities for MXenes are debated.

Tailoring metal-oxide interfaces of inverse catalysts of TiO2/nanoporous-Au under hydrogen oxidation.

Engineering metal-oxide interfaces in TiO2/nanoporous (np) Au inverse catalysts results in enhancement of H2 oxidation activity. While the intrinsic activity of the novel np-Au prepared from a Au-Si alloy is low, the activity increased as the weight fraction of the TTIP (amount of TiO2) was increased to 0.5 weight%. We correlate the change in activity with the active sites at the perimeter interface between the TiO2 and np-Au.

Intrinsic relation between catalytic activity of CO oxidation on Ru nanoparticles and Ru oxides uncovered with ambient pressure XPS.

Recent progress in colloidal synthesis of nanoparticles with well-controlled size, shape, and composition, together with development of in situ surface science characterization tools, such as ambient pressure X-ray photoelectron spectroscopy (APXPS), has generated new opportunities to unravel the surface structure of working catalysts. We report an APXPS study of Ru nanoparticles to investigate catalytically active species on Ru nanoparticles under oxidizing, reducing, and CO oxidation reaction conditions. The 2.8 and 6 nm Ru nanoparticle model catalysts were synthesized in the presence of poly(vinyl pyrrolidone) polymer capping agent and deposited onto a flat Si support as two-dimensional arrays using the Langmuir-Blodgett deposition technique. Mild oxidative and reductive characteristics indicate the formation of surface oxide on the Ru nanoparticles, the thickness of which is found to be dependent on nanoparticle size. The larger 6 nm Ru nanoparticles were oxidized to a smaller extent than the smaller Ru 2.8 nm nanoparticles within the temperature range of 50-200 °C under reaction conditions, which appears to be correlated with the higher catalytic activity of the bigger nanoparticles. We found that the smaller Ru nanoparticles form bulk RuO(2) on their surfaces, causing the lower catalytic activity. As the size of the nanoparticle increases, the core-shell type RuO(2) becomes stable. Such in situ observations of Ru nanoparticles are useful in identifying the active state of the catalysts during use and, hence, may allow for rational catalyst designs for practical applications.

Ultrathin titania coating for high-temperature stable SiO2/Pt nanocatalysts.

The facile synthesis of silica supported platinum nanoparticles with ultrathin titania coating to enhance metal-support interactions suitable for high temperature reactions is reported, as thermal and structure stability of metal nanoparticles is important for catalytic reactions.