RESUMO
Manufacturing high-performance activated carbon (AC) materials from abundant biomass at low temperature and short activation time is targeted by the green and sustainable chemical industry. Here, a 1980 m2/g of carbon nanospheres-anchored porous carbon material (PHAC) derived from waste sawdust was prepared by a method of H3PO4 hydrothermal combined with fast activation at 450 °C within 2.8 min. It is found that H3PO4 hydrothermal pretreatment could promote the dehydration of carbohydrates to form more unstable C = O structures, which were decomposed in the subsequent fast activation to form pore structures. In addition, this process is also conducive to the formation of carbon nanospheres, increasing the degree of graphitization and producing more graphite defects. The prepared PHAC showed good adsorption performance for different types of pollutants. This work provides a new insight for the preparation of high performance biomass based carbon materials under mild conditions.
