RESUMO
The monolayer graphene-noble metallic nanostructure hybrid system with excellent optical characteristic, which is deserved pay attentions in the study of surface-enhanced Raman scattering spectroscopy. In this work, a hybrid sandwich structure is designed to transfer single-layer graphene to the surface of discs substrate covered by silver film and assembly of the dense Au nanoparticles (AuNPs). Blu-ray disc has a cycle density of approximately 5.7 times that of DVD-R due to the different storage capacities of these optical discs. In the research, enhancement effects have been explored for two different periodic grating structures. Compared to spectra of Si/G structure, Graphene Raman spectra from Blu-grating/AuNPs/G structure and Blu-grating/G/AuNPs enhancement multiples at the 2D peak position possesses different Raman responses of 1.09 and 2.51 times, respectively. The sandwich hybrid structure of Ag grating/graphene/AuNPs obtains a Raman enhancement factor (EF) of 6.2×108 for Rhodamine 6G and surface-enhanced Raman Scattering(SERS) detection limit of 0.1 nM. These findings can be attributed to the electric field enhancement of the hybrid structure and the chemical enhancement of graphene. This study provides a new approach for SERS detection and offers a new technique for designing SERS sensors with grapheme-plasmon hybrid structures.
