Oscillative Trapping of a Droplet in a Converging Channel Induced by Elastic Instability.

Permanent trapping of an oscillating, nonwetting droplet is observed in a converging-diverging microchannel when aqueous, viscoelastic fluids are injected. Classical theories based on the balance between capillary and viscous forces suggest that the droplet size should decrease with increasing flow rates of a displacing Newtonian fluid, and the droplet should be completely displaced at high injection rates. However, droplets in viscoelastic fluids cannot be removed by increasing flow rates due to the oscillation. The oscillation amplitude linearly increases with the Deborah number (De), which further inhibits the droplet's passing through the constriction, "permanently." Our microfluidic experiments show that the onset of oscillation is determined by a critical De, which is near 1. We derive a linear relationship for the trapped droplet length with Ec^{1/3}, where Ec is the elastocapillary number, by introducing the elastic force into the force balance in addition to the capillary and viscous forces.

A highly selective and sensitive 1,8-naphthalimide-based fluorescent sensor for Zn2+ imaging in living cells.

A new 4-amino-1,8-naphthalimide-based fluorescent sensor, with iminoacetic acid and iminoethoxyacetic acid as receptor, was developed. It was applied successfully to detect Zn2+ in aqueous solution and living cells. Under physiological pH conditions, it demonstrates high selectivity and sensitivity for sensing Zn2+ with about 7-fold enhancement in aqueous solution, with a characteristic emission band of 4-amino-1,8-naphthalimide with a green color centered at 550 nm.

A 2.5-D glass micromodel for investigation of multi-phase flow in porous media.

We developed a novel method for fabrication of glass micromodels with varying depth (2.5-D) with no additional complexity over the 2-D micromodels' fabrication. Compared to a 2-D micromodel, the 2.5-D micromodel can better represent the 3-D features of multi-phase flow in real porous media, as demonstrated in this paper with three different examples. Physically realistic capillary snap-off and the formation of isolated residual oil droplets were realized, which is not possible in 2-D micromodels. Droplet size variation during an emulsion flooding was investigated on the 2.5-D micromodel, showing that the droplet size decreases sharply at the inlet, with little change in size downstream of the micromodel. Displacement of light oil with ultra-low interfacial tension (IFT) surfactant was conducted in the 2.5-D micromodel, where we were able to visualize the generation and flowing of a microemulsion phase, which agrees with, and explains observations in experiments of more complex porous media.