RESUMO
As an important part of the membrane field, hollow fiber membranes (HFM) have been widely concerned by scholars. HFM fouling in the industrial application results in a reduction in its lifespan and an increase in cost. In recent years, various explorations on the HFM fouling control strategies have been carried out. In the current work, we critically review the influence of flow field characteristics in HFM-based bioreactor on membrane fouling control. The flow field characteristics mainly refer to the spatial and temporal variation of the related physical parameters. In the HFM field, the physical parameter mainly refers to the variation characteristics of the shear force, flow velocity and turbulence caused by hydraulics. The factors affecting the flow field characteristics will be discussed from three levels: the micro-flow field near the interface of membrane (micro-interface), the flow field around the membrane module and the reactor design related to flow field, which involves surface morphology, crossflow, aeration, fiber packing density, membrane vibration, structural design and other related parameters. The study of flow field characteristics and influencing factors in the HFM separation process will help to improve the performance of HFM in full-scale water treatment plants.
RESUMO
As a factor affecting the efficiency of hollow fiber membrane filtration, air resistance is gradually being discovered. To obtain a better air resistance control strategy, in the study, two representative strategies have been proposed, namely, membrane vibration and inner surface modification, which was achieved by aeration combined with looseness-induced membrane vibration and dopamine (PDA) hydrophilic modification of the inner surface, respectively. The performance of two strategies was based on Fiber Bragg Grating (FBG) sensing technology and ultrasonic phased array (UPA) technology to achieve real-time monitoring. Mathematical model result shows that in hollow fiber membrane modules, the initial appearance of air resistance causes a rapid reduction in filtration efficiency, while this effect diminishes as the air resistance increases. Besides, experimental results show that aeration combined with fiber looseness helps to inhibit air aggregation and accelerate air escape, while inner surface modification enhances the hydrophilicity of inner surface, weakens the air adhesion and increases the drag force of fluid on air bubbles. In the corresponding optimized state, both strategies perform well in optimizing the air resistance control, and the improvement in flux enhancement ability for the two strategies is 26.92 and 34.10%, respectively.
Assuntos
Filtração , Vibração , Ultrassom , Membranas ArtificiaisRESUMO
In water treatment with membrane filtration process, a lot of factors such as process design, operation, and fouling affect membrane flux. But it is often neglected the flux decline which attribute to air resistance. In this study, it has been observed that air resistance caused by air trapped initially at startup as well as the release of air from the permeating liquid has an adverse effect on the membrane filtration and backwash process in water treatment. In the study, a new in-situ monitoring method, ultrasonic phased array (UPA), was used to investigate the distribution of released air in the hollow fiber membrane module. The operation parameters such as backwash interval, duration and strength were investigated. A strategy was also proposed to mitigate the adverse effects of air resistance. The results showed that UPA can successfully monitor the distribution of released air, which has a good positive correlation with air sound pressure reflection R¯air. The released air is mainly distributed far away from the outlet, while as the backwash interval and strength increase, the range of released air distribution gradually expands. We also found the optimal operating parameters for the minimum released air volume that the backwash interval is 90 min and the backwash duration is 60 s. Besides, the air resistance has a good positive correlation with released air. Moreover, the released air migration results show that air dispersion and redissolution are beneficial to reduce the air resistance in the backwash process. In summary, the optimal operation can mitigate the air resistance in the variable membrane filtration mode in water treatment.
Assuntos
Filtração , Purificação da Água , Membranas Artificiais , Tecnologia , Ultrassom , Purificação da Água/métodosRESUMO
The polymer coagulant aid can effectively enhance the coagulation-ultrafiltration (C-UF) process for the purification of drinking water. However, when coagulant aid entered the filtration, it may also cause serious membrane fouling as polymer. In-situ Raman spectroscopy and electrochemical impedance spectroscopy(EIS) were applied to monitor the effects of coagulant aids on the membrane. The causes of fouling were assisted discussed through stage cleaning of the membrane. The equivalent circuit fitting was performed on the EIS data and the Raman spectral data were statistically analyzed after peak fitting. EIS and the cluster analysis of Raman spectroscopy provided an earlier feedback on membrane fouling layers compared to flux. The cause of membrane fouling was explained via variation of characteristic functional groups obtained by Raman spectroscopy. When the molecular weight of the coagulant aid was 160 times,80 times and 16 times larger than the MWCO of the UF membrane, the equivalent circuit obtained by fitting the EIS of the UF system satisfied Rs + c(QpRp), Rs(QcRc)(QpRp) and Rs(Qt(Rc(QpRp))) respectively. Partial correlation analysis showed that the corresponding factors causing irreversible fouling of membrane were humic acid(HA), HA and coagulant aids, coagulant aids. Combined with the mean roughness (Ra) of membrane, the coagulant aid performed differently in the cleaning of contaminated membrane and also affected the cleaning of HA.
