Ixora coccinea L. - A reliable source of nanocellulose for bio-adsorbent applications.

Nanocellulose, a subset of nanomaterials made from cellulose, one of the world's most plentiful natural resources, has the potential to offer environmentally friendly, renewable, and sustainable building blocks with enhanced properties for a variety of applications in the nanotechnology field. This article describes the impact of glutaraldehyde (GA) on glycerol plasticized nanocellulose derived from I. coccinea L. plant root. Using a variety of characterization techniques, including Fourier Transform Infrared Spectroscopy (FTIR), X-ray Powder Diffraction (XRD), Scanning Electron Microscopy (SEM), AFM, tensile and Brunauer-Emmett-Teller (BET) analysis, the effect of GA on glycerol plasticized nano-cellulose was investigated. The tensile modulus of the GA-crosslinked, 2 % glycerol-plasticized nanocellulose scaffolds is higher (88.82 MPa) than that of the regular nanocellulose scaffolds (78.8 MPa). The scaffold Young's modulus has been increased to 86.3 MPa. The results of the BET study proved that the surface area of the GA crosslinked nano-cellulose scaffold improved to129.703 m2/g. The larger surface area in turn results in a greater number of contact sites between consecutive fibers. This enhances the utility of the scaffold as a bio-adsorbent for waste water treatment. The absorbance of textile black dye and methylene blue dye in sunlight using nanocellulose composites as photocatalyst revealed a significant decrease in dye concentration after each hour, demonstrating the composites' bio-adsorbent property. The non-toxic nature, inertness, increased crystallinity index values, and good mechanical qualities are other characteristics of the GA-treated nanocellulose encourages its uses as product packaging, bioengineering materials, tissue engineering, and insulation coatings.

Waste-Derived Fuels and Renewable Chemicals for Bioeconomy Promotion: A Sustainable Approach.

Bio-based fuels and chemicals through the biorefinery approach has gained significant interest as an alternative platform for the petroleum-derived processes as these biobased processes are noticed to have positive environmental and societal impacts. Decades of research was involved in understanding the diversity of microorganisms in different habitats that could synthesize various secondary metabolites that have functional potential as fuels, chemicals, nutraceuticals, food ingredients, and many more. Later, due to the substrate-related process economics, the diverse low-value, high-carbon feedstocks like lignocellulosic biomass, industrial byproducts, and waste streams were investigated to have greater potential. Among them, municipal solid wastes can be used as the source of substrates for the production of commercially viable gaseous and liquid fuels, as well as short-chain fattyacids and carboxylic acids. In this work, technologies and processes demanding the production of value-added products were explained in detail to understand and inculcate the value of municipal solid wastes and the economy, and it can provide to the biorefinery aspect.

Bioremediation of Endocrine Disrupting Chemicals- Advancements and Challenges.

Endocrine Disrupting Chemicals (EDCs), major group of recalcitrant compounds, poses a serious threat to the health and future of millions of human beings, and other flora and fauna for years to come. A close analysis of various xenobiotics undermines the fact that EDC is structurally diverse chemical compounds generated as a part of anthropogenic advancements as well as part of their degradation. Regardless of such structural diversity, EDC is common in their ultimate drastic effect of impeding the proper functioning of the endocrinal system, basic physiologic systems, resulting in deregulated growth, malformations, and cancerous outcomes in animals as well as humans. The current review outlines an overview of various EDCs, their toxic effects on the ecosystem and its inhabitants. Conventional remediation methods such as physico-chemical methods and enzymatic approaches have been put into action as some form of mitigation measures. However, the last decade has seen the hunt for newer technologies and methodologies at an accelerated pace. Genetically engineered microbial degradation, gene editing strategies, metabolic and protein engineering, and in-silico predictive approaches - modern day's additions to our armamentarium in combating the EDCs are addressed. These additions have greater acceptance socially with lesser dissonance owing to reduced toxic by-products, lower health trepidations, better degradation, and ultimately the prevention of bioaccumulation. The positive impact of such new approaches on controlling the menace of EDCs has been outlaid. This review will shed light on sources of EDCs, their impact, significance, and the different remediation and bioremediation approaches, with a special emphasis on the recent trends and perspectives in using sustainable approaches for bioremediation of EDCs. Strict regulations to prevent the release of estrogenic chemicals to the ecosystem, adoption of combinatorial methods to remove EDC and prevalent use of bioremediation techniques should be followed in all future endeavors to combat EDC pollution. Moreover, the proper development, growth and functioning of future living forms relies on their non-exposure to EDCs, thus remediation of such chemicals present even in nano-concentrations should be addressed gravely.

Nanocellulose in tissue engineering and bioremediation: mechanism of action.

Nanocellulose are nano-sized components which are biodegradable, biocompatible and renewable. It offers mechanical strength and chemical stability in plants and bacteria. The environmental contamination is reduced by employing various bioremediation techniques which usesmicroorganisms like algae, bacteria and fungi as bio-adsorbents. The bio adsorbent property of nanocellulose contribute more for the bioremediation methods and the detailed study of its mechanism and application is essential which is discussed here. The mechanism happening between the contaminant and nanocellulose adsorbent should be explored in detail in order to develop effective new bioremediation strategies. Nanocellulose structural functionalization helps to modify the nanocellulose structure based on which it can be utilized for specific functions. Exploring the mechanisms that contribute to the implementation of nanocellulose in tissue engineering helps for further developments and advancement in the biomedical application of nanocellulose. Not much studies are available that elucidate and study the basic steps involved in the biomedical and environmental usage of nanocellulose. This review has focussed on the basic mechanisms involved in the use of nanocellulose in tissue engineering and bioremediation processes.

Bacterial nanocellulose: engineering, production, and applications.

Bacterial nanocellulose (BNC) has been emerging as a biomaterial of considerable significance in a number of industrial sectors because of its remarkable physico-chemical and biological characteristics. High capital expenses, manufacturing costs, and a paucity of some well-scalable methods, all of which lead to low BNC output in commercial scale, are major barriers that must be addressed. Advances in production methods, including bioreactor technologies, static intermittent, and semi-continuous fed batch technologies, and innovative outlay substrates, may be able to overcome the challenges to BNC production at the industrial scale. The novelty of this review is that it highlights genetic modification possibilities in BNC production to overcome existing impediments and open up viable routes for large-scale production, suitable for real-world applications. This review focuses on various production routes of BNC, its properties, and applications, especially the major advancement in food, personal care, biomedical and electronic industries.

Potential of nanocellulose for wastewater treatment.

Wastewater management has significant interest worldwide to establish viable treatment techniques to ensure the availability of clean water. The specialities of nanocellulose for this particular application is due to their high aspect ratio and accessibility of plenty of -OH groups for binding with dyes, heavy metals and other pollutants. This review aggregates the application of nanocellulose for wastewater treatment particularly as adsorbents of dyes and heavy metals, and also as membranes for filtering various other contaminants including microbes. The membrane technologies are proven to be effective relating to their durability and separation effectiveness. The commercial scale application of nanocellulose based materials in water treatment processes depend on various factors like routes of synthesis, surface modifications, hydrophilic/hydrophobic, porosity, durability etc. The recent developments on production of novel adsorbents or membranes encourage the implementation of nanocellulose based cleaner technologies for wastewater treatment.

Advanced biomaterials for sustainable applications in the food industry: Updates and challenges.

Maintaining the safety and quality of food are major concerns while developing biomaterial based food packaging. It offers a longer shelf-life as well as protection and quality control to the food based on international standards. Nano-biotechnology contributes to a far extent to make advanced packaging by developing multifunctional biomaterials for potential applications providing smarter materials to consumers. Applications of nano-biocomposites may thus help to deliver enhanced barrier, mechanical strength, antimicrobial and antioxidant properties to novel food packaging materials. Starch derived bioplastics, polylactic acid and polyhydroxybutyrate are examples of active bioplastics currently in the food packaging sector. This review discusses the various types of biomaterials that could be used to improve future smarter food packaging, as well as biomaterials' potential applications as food stabilizers, pathogen control agents, sensors, and edible packaging materials. The regulatory concerns related to the use of biomaterials in food packaging and commercially available biomaterials in different fields are also discussed. Development of novel biomaterials for different food packaging applications can therefore guarantee active food packaging in future.