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1.
Talanta ; 150: 367-74, 2016 Apr 01.
Artigo em Inglês | MEDLINE | ID: mdl-26838420

RESUMO

The growing global demand for specialty coffee increases the need for improved coffee quality assessment methods. Green bean coffee quality analysis is usually carried out by physical (e.g. black beans, immature beans) and cup quality (e.g. acidity, flavour) evaluation. However, these evaluation methods are subjective, costly, time consuming, require sample preparation and may end up in poor grading systems. This calls for the development of a rapid, low-cost, reliable and reproducible analytical method to evaluate coffee quality attributes and eventually chemical compounds of interest (e.g. chlorogenic acid) in coffee beans. The aim of this study was to develop a model able to predict coffee cup quality based on NIR spectra of green coffee beans. NIR spectra of 86 samples of green Arabica beans of varying quality were analysed. Partial least squares (PLS) regression method was used to develop a model correlating spectral data to cupping score data (cup quality). The selected PLS model had a good predictive power for total specialty cup quality and its individual quality attributes (overall cup preference, acidity, body and aftertaste) showing a high correlation coefficient with r-values of 90, 90,78, 72 and 72, respectively, between measured and predicted cupping scores for 20 out of 86 samples. The corresponding root mean square error of prediction (RMSEP) was 1.04, 0.22, 0.27, 0.24 and 0.27 for total specialty cup quality, overall cup preference, acidity, body and aftertaste, respectively. The results obtained suggest that NIR spectra of green coffee beans are a promising tool for fast and accurate prediction of coffee quality and for classifying green coffee beans into different specialty grades. However, the model should be further tested for coffee samples from different regions in Ethiopia and test if one generic or region-specific model should be developed.


Assuntos
Coffea/química , Café/química , Qualidade dos Alimentos , Espectroscopia de Luz Próxima ao Infravermelho/métodos , Análise dos Mínimos Quadrados
2.
Environ Pollut ; 199: 209-18, 2015 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-25681816

RESUMO

We propose three estimation strategies (local, remote and mixed) for ultrafine particles (UFP) at three sites in an urban air pollution monitoring network. Estimates are obtained through Gaussian process regression based on concentrations of gaseous pollutants (NOx, O3, CO) and UFP. As local strategy, we use local measurements of gaseous pollutants (local covariates) to estimate UFP at the same site. As remote strategy, we use measurements of gaseous pollutants and UFP from two independent sites (remote covariates) to estimate UFP at a third site. As mixed strategy, we use local and remote covariates to estimate UFP. The results suggest: UFP can be estimated with good accuracy based on NOx measurements at the same location; it is possible to estimate UFP at one location based on measurements of NOx or UFP at two remote locations; the addition of remote UFP to local NOx, O3 or CO measurements improves models' performance.


Assuntos
Poluentes Atmosféricos/análise , Poluição do Ar/estatística & dados numéricos , Monitoramento Ambiental/métodos , Material Particulado/análise , Poluição do Ar/análise , Substâncias Perigosas , Modelos Teóricos , Análise de Regressão , Silicones
3.
J Acoust Soc Am ; 134(1): 852-61, 2013 Jul.
Artigo em Inglês | MEDLINE | ID: mdl-23862891

RESUMO

Urban soundscape design involves creating outdoor spaces that are pleasing to the ear. One way to achieve this goal is to add or accentuate sounds that are considered to be desired by most users of the space, such that the desired sounds mask undesired sounds, or at least distract attention away from undesired sounds. In view of removing the need for a listening panel to assess the effectiveness of such soundscape measures, the interest for new models and techniques is growing. In this paper, a model of auditory attention to environmental sound is presented, which balances computational complexity and biological plausibility. Once the model is trained for a particular location, it classifies the sounds that are present in the soundscape and simulates how a typical listener would switch attention over time between different sounds. The model provides an acoustic summary, giving the soundscape designer a quick overview of the typical sounds at a particular location, and allows assessment of the perceptual effect of introducing additional sounds.


Assuntos
Atenção , Percepção Auditiva , Planejamento de Cidades , Redes Neurais de Computação , Ruído , Mascaramento Perceptivo , População Urbana , Humanos , Pesquisa
4.
J Environ Monit ; 13(10): 2710-9, 2011 Oct.
Artigo em Inglês | MEDLINE | ID: mdl-21879096

RESUMO

Requirements for static (prediction of L(den) and diurnal averaged noise pattern) and dynamic (prediction of 15 min and 60 min evolution of L(Aeq) and statistical levels L(A90,)L(A50) and L(A10)) noise level monitoring are investigated in this paper. Noise levels are measured for 72 consecutive days at 5 neighboring streets in an inner-city noise measurement network in Gent, Flanders, Belgium. We present a method to make predictions based on a fixed monitoring station, combined with short-term sampling at temporary stations. It is shown that relying on a fixed station improves the estimation of L(den) at other locations, and allows for the reduction of the number of samples needed and their duration; L(den) is estimated with an error that does not exceed 1.5 dB(A) to 3.4 dB(A) according to the location, for 90% of the 3 × 15 min samples. Also the diurnal averaged noise pattern can be estimated with a good accuracy in this way. It was shown that there is an optimal location for the fixed station which can be found by short-term measurements only. Short-term level predictions were shown to be more difficult; 7 day samples were needed to build models able to estimate the evolution of L(Aeq,60min) with a RMSE ranging between 1.4 dB(A) and 3.7 dB(A). These higher values can be explained by the very pronounced short-term variations appearing in typical streets, which are not correlated between locations. On the other hand, moderately accurate predictions can be achieved, even based on short-term sampling (a 3 × 15 minute sampling duration seems to be sufficient for many of the accuracy goals set related to static and dynamic monitoring). Finally, the method proposed also allows for the prediction of the evolution of statistical indicators.


Assuntos
Cidades/estatística & dados numéricos , Monitoramento Ambiental/métodos , Ruído dos Transportes/estatística & dados numéricos , Bélgica , Equipamentos e Provisões Elétricas , Monitoramento Ambiental/instrumentação
5.
Comb Chem High Throughput Screen ; 11(9): 745-55, 2008 Nov.
Artigo em Inglês | MEDLINE | ID: mdl-18991577

RESUMO

We discuss various ways in which to construct and process partial order relations or partially ordered sets (posets) in the context of ranking objects on the basis of multiple criteria. Oftentimes, it is undesirable or even impossible to devise a weighting scheme to compute a final score on the basis of the criteria. An alternative is then to restrict oneself to the information contained in the partial ordering of all objects implied by the criteria. We will consider some ways in which one can exploit partial order relations to determine a ranking of a collection of objects. More exactly, we will examine how to combine information coming from two sources, both for the case in which the sources are considered to be equally important, as well as for the case in which one source of information should take priority. We illustrate the concepts on pollution data coming from 59 regions in Baden-Württemberg.


Assuntos
Poluentes do Solo/análise , Cádmio/análise , Técnicas de Química Combinatória , Alemanha , Chumbo/análise
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