RESUMO
The high temperature oxidation of the Pt(111) surface with molecular oxygen has been studied using scanning tunnelling microscopy and low energy electron diffraction (LEED). Results indicate a self-limited growth of well-ordered PtO2 nanoclusters which have an O-Pt-O trilayer structure. Each nanocluster has a triangular shape and nucleates at the Pt(111) surface step edge due to the mobility of Pt atoms. The triangular PtO2 nanoislands on the upper and lower Pt(111) terraces represent two mirror domains with the mirror plane perpendicular to the substrate and aligned along the [Formula: see text] direction of the latter. LEED data obtained from the nanostructured PtO2/Pt(111) surface show a characteristic (2 x 2) pattern. Different oxidation conditions lead to the formation of chemisorbed oxygen on the Pt(111) surface alongside PtO2 nanoclusters. Oxygen adsorbs on the surface forming a variety of structures which result in (3 x 3), (5 x 5) and (7 x 7) LEED patterns.
RESUMO
We report on the formation of equilateral triangular clusters hollow inside with 5-6 atoms per side, self-assembled on Ni adislands grown on Rh(111). The observation of standing wave patterns on the Ni adislands and the Rh(111) indicates that the self-assembly is mediated by Friedel oscillations. In this context, we propose a model based on the energy of interaction between adsorbates, which explains the formation of the clusters as a result of the assembly of rows of 5-6 adatoms.
RESUMO
We report on scanning tunneling microscopy studies of the Cu(014)-O surface using MnNi tips. Remarkably, the results show a regular apparent doubling of surface atomic rows in the {110} direction. A qualitative explanation of this feature based on tight binding and density functional theory calculations of the electronic structure of the tip is presented. Double imaging of the same atom by different legs of dyz orbital could be the reason for the observed doubling. The orientation of the orbital is determined by the O-Mn crystal field.
