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1.
Chemosphere ; 362: 142620, 2024 Jun 14.
Artigo em Inglês | MEDLINE | ID: mdl-38880265

RESUMO

Water pollution, stemming from various contaminants including organic and pharmaceutical pollutants, poses a significant global challenge. Amidst the array of methods available for pollutant mitigation, the three-dimensional electrochemical approach emerges as a standout solution due to its environmental compatibility, cost-effectiveness, and rapid efficiency. This study delves into the efficacy of three-dimensional electrochemical processes in purging organic and pharmaceutical pollutants from aqueous media. Existing research indicates that the three-dimensional electrochemical process, particularly when employing particle electrodes, exhibits notable success in degrading organic and pharmaceutical pollutants. This achievement is largely attributed to the ample specific surface area of particle electrodes and the shortened mass transfer distance, which collectively enhance efficiency in comparison to traditional two-dimensional electrochemical methods. Moreover, this approach is lauded for its environmental friendliness and cost-effectiveness. However, it is imperative to note that the efficacy of the process is subject to various factors including temperature, pH levels, and current intensity. While the addition of oxidants can augment process efficiency, it also carries the risk of generating intermediate compounds that impede the reaction. In conclusion, the three-dimensional electrochemical method proves to be a viable and practical approach, provided that process conditions are meticulously considered and adhered to. Offering advantages from both environmental and economic perspectives, this method presents a promising alternative to conventional water and wastewater treatment techniques.

2.
Heliyon ; 10(2): e24179, 2024 Jan 30.
Artigo em Inglês | MEDLINE | ID: mdl-38293470

RESUMO

Antibiotic contamination of water sources, particularly tetracycline (TC) contamination, has emerged as one of the global issues that needs action. In this research, ZnCoFe2O4@Chitosan (Ch) as a magnetic nanohybrid adsorbent was synthesized using the microwave-assisted co-precipitation method, and their efficiency for the TC adsorption process was investigated. FESEM (Field Emission Scanning Electron Microscope), EDX (Energy Dispersive X-ray), Mapping and line Scan, XRD (X-Ray Diffraction), FTIR (Fourier Transform Infrared Spectrometer), VSM (Vibrating Sample Magnetometer), Thermogravimetric analysis (TGA) and BET (Brunauer Emmett Teller) techniques were used to check and verify its physical and chemical properties. The removal of TC via the adsorption process from synthetic and real wastewater samples was investigated. The factors determining the TC adsorption process, comprising tetracycline concentration (5-30 mg/L), adsorbent dosage (0.7-2 g/L), contact time (2-45 min), and pH (3-11), were evaluated. The removal effectiveness for the synthetic sample and the real wastewater sample was 93 % and 80 %, respectively, under the ideal TC adsorption process parameters of pH 3, adsorbent dosage 1 g/L, TC initial concentration 5 mg/L, and contact time 30 min. According to kinetic and equilibrium studies, the adsorption of TC by ZnCoFe2O4@Ch follows pseudo-second-order kinetics and the Freundlich isotherm. Additionally, it was determined through the analysis of thermodynamic data that the process of exothermic adsorption is spontaneous and is followed by a decrease in disorder (ΔH = -15.16 kJ/mol, ΔS = -28.69 kJ/mol, and ΔG = -6.62 kJ/mol). After five cycles of recovery and regeneration, the ZnCoFe2O4@Ch magnetic nanocomposite was able to remove 65 % of the TC pollutant and had good chemical stability. The results showed that the magnetic nano-adsorbent ZnCoFe2O4@Ch is a novel magnetic nano-adsorbent with high adsorption capacity that can be utilized to eliminate pharmaceutical contaminants from aqueous solutions.

3.
Int J Environ Health Res ; 34(4): 2031-2051, 2024 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-37158808

RESUMO

Reactive-oxygen-species are produced more often in the body when bisphenol A (BPA), an endocrine-disrupting-substance, is present. In this investigation, bio-sorbents from an aqueous solution adapted from Aloe-vera were used to survey BPA removal. Aloe-vera leaf wastes were used to create activated carbon, which was then analyzed using Fourier transform infrared (FTIR), Field emission scanning electron microscopy (FESEM), X-ray diffraction (XRD), Thermogravimetric analysis (TGA), Zeta potential, and Brunauer-Emmett-Teller (BET) techniques. It was revealed that the adsorption process adheres to the Freundlich isotherm model with R2>0.96 and the pseudo-second-order kinetic model with R2>0.99 under ideal conditions (pH = 3, contact time = 45 min, concentration of BPA = 20 mg.L-1, and concentration of the adsorbent = 2 g.L-1). After five-cycle, the efficacy of removal was greater than 70%. The removal of phenolic-chemicals from industrial-effluent can be accomplished with the assistance of this adsorbent in a cost-effective and effective-approach.


Assuntos
Aloe , Compostos Benzidrílicos , Fenóis , Poluentes Químicos da Água , Adsorção , Termodinâmica , Folhas de Planta/química , Poluentes Químicos da Água/análise
4.
Environ Sci Pollut Res Int ; 30(51): 111076-111091, 2023 Nov.
Artigo em Inglês | MEDLINE | ID: mdl-37798522

RESUMO

Although the fundamental reasons for cognitive function disorders have been well documented, little is known about the impact of environmental exposures, such as pesticides, on children's cognitive function development. This study investigated the effect of exposure to organophosphate pesticides on children's cognitive function. In order to determine various factors of exposure, hair samples were collected from 114 elementary school children who lived in Boyer-Ahmad County in the province of Kohgiluyeh and Boyer-Ahmad, Iran. A detailed questionnaire was utilized to gather demographic information and exposure profile. Pesticides were detected in hair samples using a gas chromatography-mass spectrometer (GC-MS); also, cognitive function was assessed using the trail-making test (TMT), which was divided into two parts: TMT-part A and TMT-part B. Participants in the study were 10.12 ± 1.440 years old on average. Children in rural areas had higher mean total pesticide concentrations (13.612 ± 22.01 ng/g) than those who lived in the urban areas (1.801 ± 1.32). The results revealed that boys (46.44 s and 92.37 s) completed the TMT-part A and part B tests in less time than girls (54.95 s and 109.82 s), respectively, and showed better performance (2.14) on the cognitive function exam than girls (2.07). Diazinon and TMT-part B were positively correlated (p < 0.05). With the increase in pesticides, there was no discernible difference in cognitive function. Pesticide use throughout a child's development may affect certain cognitive function indicators. In order to assess causal relationships, group studies and case studies are required because the current research was cross-sectional in nature.


Assuntos
Inseticidas , Praguicidas , Masculino , Feminino , Humanos , Criança , Estudos Transversais , Agricultura , Praguicidas/análise , Exposição Ambiental/análise , Compostos Organofosforados , Diazinon , Cognição
5.
Environ Monit Assess ; 195(11): 1272, 2023 Oct 05.
Artigo em Inglês | MEDLINE | ID: mdl-37794217

RESUMO

Emissions of greenhouse gases from industrial facilities, such as refineries, are one of the most significant environmental problems in many countries. This study aimed to assess the present status of emission sources near a gas refinery region, and the contribution of sources to air pollution was estimated by monitoring CO for a year at a fixed station. This descriptive-analytical study was conducted between January and December 2020. A simulation of CO gas distribution and pollutant concentration prediction was carried out. The results show that the maximum concentration of CO in the 1-h period was 2260 µg/m3, which corresponds to the peak concentration in spring, and in the 8-h period, it was 573 µg/m3, which corresponds to the peak concentration in winter. The studied area's maximum pollutant concentration was also compared to national and international standards for clean air. In all four seasons, the maximum simulated CO concentrations were lower than the Iranian and EPA standards for clean air. Maximum concentrations have occurred in the southern slopes of the study area's heights, and, due to the appropriate wind speed, maximum concentrations in the northeastern mountain peaks occurred at a more considerable distance due to the high altitude of the mountains and the lack of suitable conditions for pollutant escape. Furthermore, because of the height of smokestacks and flares from the ground and the effect of wind on the release height, the concentration of pollutants at the foot of the stacks is low and decreases gradually over a certain distance. Finally, the distribution and deposition of pollutants in the pathway of the smoke were influenced by the type of topography.


Assuntos
Poluentes Atmosféricos , Poluição do Ar , Poluentes Atmosféricos/análise , Material Particulado/análise , Irã (Geográfico) , Monitoramento Ambiental/métodos , Poluição do Ar/análise , Oriente Médio
6.
Heliyon ; 9(6): e17518, 2023 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-37408889

RESUMO

This study aims to evaluate the effect of fermented synbiotic soy milk containing Lactobacillus acidophilus, Bifidobacterium lactis, and inulin on a series of hematological and oxidative stress parameters, as well as serum lead levels in rats. In this study, 56 male Sprague-Dawley rats were randomly assigned to assess probiotics (L. acidophilus or B. lactis), probiotics with prebiotics (i.e., inulin), and the corresponding controls. Several hematologic parameters (red blood cell (RBC)), hematocrit (HCT) and hemoglobin (Hgb)), serum lead levels, superoxide dismutase (SOD) activity, and malondialdehyde (MDA) presence was measured to evaluate changes on day 42. Although a significant difference was observed in serum lead levels, there were no significant changes in hematological and oxidative stress parameters between the study groups. In conclusion, this study demonstrates that administering synbiotic fermented soy milk containing the probiotic Lactobacillus acidophilus and the prebiotic inulin may significantly improve serum lead levels in rats.

7.
Heliyon ; 9(5): e15678, 2023 May.
Artigo em Inglês | MEDLINE | ID: mdl-37305470

RESUMO

Nowadays, the presence of humic acid (HA) in water sources is highly regarded due to the production of extremely harmful byproducts such as trihalomethanes. In this study, the effectiveness of an Ag3PO4/TiO2 catalyst produced by in situ precipitation as a heterogeneous catalyst for the degradation of humic acid in the existence of visible and solar light was evaluated. The Ag3PO4/TiO2 catalyst's structure was characterized using X-ray powder diffraction (XRD), scanning electron microscopy (SEM), and energy dispersive spectroscopy (EDS), after which the catalyst dosage, HA concentration, and pH parameters were adjusted. After a 20-min reaction, the highest HA degradation of 88.2% and 85.9% in presence of solar light and visible light were attained at the ideal operating conditions of 0.2 g/L catalyst, 5 mg/L HA, and pH 3, respectively. It was discovered that, based on kinetic models, the degradation of HA matched both Langmuir-Hinshelwood and pseudo-first-order kinetics at concentrations of 5 to 30 mg/L (R2 > 0.8). The Langmuir-Hinshelwood model had surface reaction rate constants (Kc) of 0.729 mg/L.min and adsorption equilibrium constants (KL-H) of 0.036 L/mg. Eventually, a real-water investigation into the process' effectiveness revealed that, under ideal circumstances, the catalyst had a reasonable HA removal efficiency of 56%.

8.
Sci Rep ; 13(1): 9053, 2023 06 03.
Artigo em Inglês | MEDLINE | ID: mdl-37270572

RESUMO

Serious health issues can result from exposure to the nitrogenous pollutant like 2,4,6-trinitrotoluene (TNT), which is emitted into the environment by the munitions and military industries, as well as from TNT-contaminated wastewater. The TNT removal by extended aeration activated sludge (EAAS) was optimized in the current study using artificial neural network modeling. In order to achieve the best removal efficiency, 500 mg/L of chemical oxygen demand (COD), 4 and 6 h of hydraulic retention time (HRT), and 1-30 mg/L of TNT were used in this study. The kinetics of TNT removal by the EAAS system were described by the calculation of the kinetic coefficients K, Ks, Kd, max, MLSS, MLVSS, F/M, and SVI. Adaptive neuro fuzzy inference system (ANFIS) and genetic algorithms (GA) were used to optimize the data obtained through TNT elimination. ANFIS approach was used to analyze and interpret the given data, and its accuracy was around 97.93%. The most effective removal efficiency was determined using the GA method. Under ideal circumstances (10 mg/L TNT concentration and 6 h), the TNT removal effectiveness of the EAAS system was 84.25%. Our findings demonstrated that the artificial neural network system (ANFIS)-based EAAS optimization could enhance the effectiveness of TNT removal. Additionally, it can be claimed that the enhanced EAAS system has the ability to extract wastewaters with larger concentrations of TNT as compared to earlier experiments.


Assuntos
Esgotos , Trinitrotolueno , Redes Neurais de Computação , Análise da Demanda Biológica de Oxigênio
9.
Heliyon ; 9(4): e14870, 2023 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-37025894

RESUMO

Prevention and control of foodborne pathogens are of vital public health importance, and poultry meat is recognized as a major source of Salmonella infection in humans. Therefore, it is necessary to reduce the presence of salmonella in poultry meat. This article provided a systematic review and modeling to assess the effect of various factors on bacteriophages' function on Salmonella spp. Reduction in poultry meat. Twenty-two studies were included based on the inclusion and exclusion criteria mentioned in the methodology. The results showed that each unit increase in bacterial dose, phage dose, and temperature increases the Salmonella reduction by about 7%, 20%, and 1%, respectively. In addition, wild-type phages were more efficient than commercial-type phages, and this result was statistically significant (ß = 1.124; p-value <0.001). This multivariate analysis is a helpful tool to predict the role of various factors in the role of phage in reducing Salmonella in poultry meat.

10.
Heliyon ; 9(3): e14246, 2023 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-36938422

RESUMO

Arsenic is a priority contaminant that enters drinking water through both natural and man-made processes, posing a risk to human health and leading to the development of a variety of illnesses. Since millions of people are exposed to drinking water with a concentration of this pollution that is higher than allowed levels, its removal has become a crucial issue, and this removal is accomplished using a variety of techniques. In this study, the removal of arsenic using two membrane processes-nanofiltration (NF) and reverse osmosis (RO) has been specially investigated in light of the outstanding removal efficiency of arsenic through membrane processes. Arsenic in drinking water must be removed using the right techniques to comply with world health organization (WHO) guidelines. According to the findings of several studies, NF membranes can remove significant amounts of heavy metals, such as arsenic, at low pressures while still producing high-quality water, which lowers operating costs. RO membranes are regarded as yet another efficient membrane technology for eliminating both types of arsenic throughout a wide pH and pressure range. Although the likelihood of membrane clogging can be considered as a restriction in these processes, given the possibility of its modification through the use of proper pre-treatment and also taking into consideration benefits such as the lack of need for chemicals, the absence of sludge production, removal effectiveness up to the WHO standard limit, and the removal of a wide variety of contaminants, they are preferred compared to other techniques in as much as they have the potential to become the most effective method of removal.

11.
Heliyon ; 9(2): e13621, 2023 Feb.
Artigo em Inglês | MEDLINE | ID: mdl-36846698

RESUMO

Background: Biomonitoring is a well-established method for assessing people's exposure to contaminants in the environment. Many non-communicable diseases can be prevented or aggravated by physiologically monitoring heavy metals in biological matrices such as urine, evaluating their association with non-communicable diseases, and attempting to limit exposure to them. The focus of this research was to determine the association between potentially toxic elements (PTE) such as arsenic (As), lead (Pb), chromium (Cr), and zinc (Zn) urine concentrations and anthropometric indices and demographic data in children and adolescents aged 6-18 years in Kerman, Iran. Methods: 106 children and adolescents aged 6-18 years in Kerman were randomly selected. A questionnaire was used to acquire demographic information from the participants' parents. Height, weight, and waist circumference (WC) were all assessed, as well as body mass index (BMI) and BMI Z-score. Induced Coupled Plasma Mass Spectrometry (ICP/MS) was used to quantify As, Pb, Cr, and Zn concentrations in participants' urine. Results: The geometric mean concentrations were As (38.72 ± 39.30), Pb (19.58 ± 22.91), Cr (1.06 ± 0.28), and Zn (344.72 ± 288.16) µg/creatinine. Boys aged 12-18 years old had higher mean concentration of As than boys aged 6-11 years old (p = 0.019) according to two measurement standards, µg/L, and µg/creatinine, whereas girls had no significant difference. In general, there was a strong association between parental education and metal concentrations of As, Pb, and Cr. As, Pb, and Zn (µg/creatinine) had a significant positive association with BMI z-score and BMI. As, Pb, and Zn metals were shown to have a substantial positive association (p < 0.001). There was no evidence of an association between the metals evaluated and WC. Conclusions: The findings of this study generally showed that there was a significant association between demographic characteristics and exposure to these metals in children and adolescents, indicating that these people were exposed to these metals, which can harm their health. As a result, the pathways of exposure to metals must be limited.

12.
Artigo em Inglês | MEDLINE | ID: mdl-35897481

RESUMO

While a large body of literature has shown the health problems of illicit drug use, research is needed on how substance abuse impacts DNA damage and contaminants in blood, especially given Pb-contaminated opium. This pilot study aimed to evaluate the levels of lead (Pb), 8-hydroxy di-guanine (8-oxo-Gua), and malondialdehyde (MDA) in the blood serum of opium addicts and non-addict people. The current study is a case-control study with a cross-sectional design. A sample of 50 opium-addicted and non-addict adults were chosen for this study using convenience and random sampling methods. Participants were divided into two groups: addicts and non-addicts. The atomic absorption spectroscopy method was used to measure the quantity of Pb, and the Enzyme-Linked Immunosorbent Assay (ELISA) method was used to measure the amount of 8-oxo-Gua and MDA. The data were analyzed using an independent t-test. The results show that the amount of Pb in the blood serum of addicted women and men was higher than levels in non-addict men and women, for the study participants (p-value = 0.001). Blood levels were not significantly different between addicts and non-addicts for men or women for 8-oxo-Gua (p-value = 0.647 for women and p-value = 0.785 for men) and MDA (p-value = 0.867 for women and p-value = 0.995 for men). In general, addicts' blood Pb levels were found to be substantially higher than those of normal non-addict persons in this pilot study. As a result, testing for blood Pb levels in addicts may be informative in instances when symptoms are inconclusive.


Assuntos
Drogas Ilícitas , Transtornos Relacionados ao Uso de Substâncias , Adulto , Estudos de Casos e Controles , Estudos Transversais , Feminino , Guanina/análogos & derivados , Humanos , Chumbo , Masculino , Malondialdeído , Ópio , Projetos Piloto , Soro
13.
J Environ Public Health ; 2022: 2939022, 2022.
Artigo em Inglês | MEDLINE | ID: mdl-35096073

RESUMO

Exposure to Endocrine-Disrupting Chemicals (EDCs) at an early age can lead to chronic diseases. 2,4-Dichlorophenol (2,4-DCP) and Triclocarban (TCC) are among EDCs that disrupt the endocrine system and alter the body's metabolism. In the present study, the hypothesis that exposure to 2,4-DCP and TCC affects obesity and predictors of cardiovascular diseases was investigated. Fasting Blood Sugar (FBS), Total Cholesterol (TC), Triglyceride (TG), Low-Density Lipoprotein (LDL), High-Density Lipoprotein (HDL (tests were performed on 79 children and adolescents. Also, blood pressure, Body Mass Index (BMI), and BMI z-score were measured to examine the hypothesis. Urinary concentrations of TCC and 2,4-DCP were measured by Gas Chromatography-Mass Spectrometry (GC/MS). Mean concentrations of TCC and 2,4-DCP (µg/L) were higher in obese individuals (5.50 ± 2.35, 0.29 ± 0.13, respectively). After adjusting for possible confounding factors, the results showed an increase in TCC concentration among girls and a decrease in 2,4-DCP among boys with increasing age. The 2,4-DCP concentration among girls increased by 0.007 and 0.01 units with a one-unit increase in Diastolic Blood Pressure (DBP) and FBS, respectively. There was a significant relationship between TCC and TG (Odds Ratio (OR) = 1.02, p-value = 0.007), LDL (OR = 1.05, p-value = 0.003), and HDL (OR = 0.88, p-value = 0.002). There was also a significant relationship between 2,4-DCP and TG (OR = 1.02, p-value = 0.002), LDL (OR = 1.12, p-value = 0.007), and HDL (OR = 0.92, p-value = 0.02). Exposure to TCC and 2,4-DCP can increase some heart risk factors and increase the risk of cardiovascular diseases and obesity. However, to confirm the results of the present study, it is necessary to conduct further studies, such as cohort and case-control studies, with a larger sample size to examine the causal relationships.


Assuntos
Doenças Cardiovasculares , Adolescente , Índice de Massa Corporal , Carbanilidas , Doenças Cardiovasculares/induzido quimicamente , Doenças Cardiovasculares/epidemiologia , Criança , Clorofenóis , Feminino , Humanos , Irã (Geográfico)/epidemiologia , Masculino , Obesidade , Fatores de Risco , Triglicerídeos
14.
Chemosphere ; 294: 133664, 2022 May.
Artigo em Inglês | MEDLINE | ID: mdl-35066075

RESUMO

BACKGROUND: Although the basic causes of obesity and cardiovascular illness have been extensively researched, little is known about the influence of environmental variables such as heavy metals on obesity development and cardiovascular disease in children and adolescents. The assumption that arsenic (As), lead (Pb), chromium (Cr), and zinc (Zn) exposure impact obesity and predictors of cardiovascular disease was explored in this study. METHOD: A questionnaire was used to gather demographic information as well as certain determinants of exposure to As, Pb, Cr, and Zn from 106 children and adolescents aged 6 to 18. Physical tests (height, weight, waist circumference (WC), BMI, BMI Z-score, Systolic blood pressure (SBP), Diastolic blood pressure (DBP)), blood samples for clinical trials (Fasting Blood Sugar (FBS), Total Cholesterol (TC), Triglyceride (TG), Low-Density Lipoprotein (LDL), High-Density Lipoprotein (HDL) (, and urine samples for urinary creatinine measurement and measures of As, Pb, Cr, and Zn in urine were obtained using the Inductively coupled plasma mass spectrometry (ICP/MS). RESULTS: The average age of the participants in the research was 11.42 ± 3.68. The majority of the participants in the research were boys (56 people). As, Pb, and Zn mean concentrations (µg/L) were greater in obese adults (42.60 ± 22.59, 20.63 ± 14.64, 326 ± 164.82), respectively. After adjusting for possible confounding factors, the data revealed that adolescents aged 12-18 years had higher levels of As and Pb (8.69 and 5.02 µg/L) than children aged 6 to 11. As and Zn metals had significant association with FBS and lipid profile (TC, TG, LDL, HDL), lead had significant correlations with lipid profile, while Cr had significant correlations with WC, SBP, FBS, LDL, TC. CONCLUSION: Childhood and adolescent exposure to As, Pb, Cr, and Zn can impact obesity and cardiovascular disease markers. The current research was a cross-sectional study, which necessitates group studies and case studies to evaluate causal relationships.


Assuntos
Arsênio , Doenças Cardiovasculares , Metais Pesados , Obesidade Infantil , Adolescente , Adulto , Índice de Massa Corporal , Doenças Cardiovasculares/epidemiologia , Doenças Cardiovasculares/etiologia , Criança , Cromo , Estudos Transversais , Humanos , Chumbo , Masculino , Obesidade Infantil/complicações , Fatores de Risco , Zinco
15.
Environ Sci Pollut Res Int ; 29(20): 30754-30763, 2022 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-34993832

RESUMO

Endocrine-disrupting chemicals (EDCs) can be a major risk factor for noncommunicable illnesses, especially when children are exposed to them. The purpose of this study was to assess the urine concentrations of triclosan (TCS), methyl triclosan (MTCS), triclocarban (TCC), and 2,4-dichlorophenol (2,4-DCP) and its association with anthropometric and demographic parameters in children and adolescents aged 6-18 living in Kerman, Iran, in 2020. A GC/MS instrument was used to measure the concentrations of the analytes. TCS, MTCS, TCC, and 2,4-DCP geometric mean concentrations (µg/L) were 4.32 ± 2.08, 1.73 ± 0.88, 4.66 ± 10.25, and 0.19 ± 0.14, respectively. TCS, MTCS, TCC, and 2,4-DCP were shown to have a positive and significant association with BMI z-score and BMI (p-value < 0.01). TCS and MTCS have a positive, strong, and substantial association (p-value < 0.01, r = 0.74). There was no significant association between the waist circumference (WC) and the analytes studied. In addition, there was a close association between analyte concentration and demographic parameters (smoking, education, income, etc.) overall. In Kerman, Iran, the current study was the first to look into the association between TCS, MTCS, TCC, and 2,4-DCP analytes and anthropometric and demographic data. The levels of urinary TCS, MTCS, TCC, 2,4-DCP, and anthropometric parameters in children and adolescents are shown to have a significant association in this study. However, because the current study is cross-sectional and it is uncertain if a single experiment accurately reflects long-term exposure to these analytes, more research is needed to determine the impact of these analyses on the health of children and adolescents.


Assuntos
Carbanilidas , Triclosan , Adolescente , Carbanilidas/análise , Criança , Clorofenóis , Estudos Transversais , Demografia , Humanos , Irã (Geográfico) , Fenóis/análise , Triclosan/análogos & derivados , Triclosan/análise
16.
Chemosphere ; 286(Pt 3): 131872, 2022 Jan.
Artigo em Inglês | MEDLINE | ID: mdl-34411932

RESUMO

In this study, the degradation of Metronidazole (MNZ) using CuCoFe2O4@MC/AC catalyst synthesized by microwave-assisted method, as an efficient activator for persulfate (PS) in the presence of ultrasonic (US: 60 kHz) was investigated. X-ray powder diffraction (XRD), Field emission scanning electron microscope (FESEM), Energy dispersive spectroscopy (EDS)-Mapping and Line scan, Fourier transform infrared spectroscopy (FTIR), Vibrating-sample magnetometer (VSM), and Thermal gravimetric analysis (TGA) were conducted to characterize the structure of CuCoFe2O4@MC/AC catalyst and then the catalyst dose, PS dose, MNZ concentration, and pH parameters were optimized. The maximum MNZ degradation of 93.78 % was achieved after 15 min reaction at the optimized operation conditions: 0.4 g L-1 of catalyst, 6 mM of PS, 5 mg L-1 of MNZ, and pH of 3. The removal efficiency of Total Organic Carbon (TOC) was 87.5 % under optimal conditions. According to kinetic equations, it was found that the MNZ degradation followed both kinetics (pseudo-first-order and Langmuir-Hinshelwood) based on the coefficient of determination (R2) of 0.949, 0.9716, 0.9073, 0.9721, and 0.9662 at concentrations of 5, 10, 15, 20, and 30, respectively. The surface reaction rate constant (Kc) and the adsorption equilibrium constant (KL-H) of the Langmuir-Hinshelwood model were 0.81 (mg L-1 min-1) and 2.184 (L mg-1), respectively. The free radical scavenging experiments were conducted to illustration the proposed mechanism, which shown that the SO4-• was the predominant radicals involved in MNZ degradation. Finally, the regeneration of the catalyst was investigated and showed that after five cycles of use and regeneration by chemical and thermal methods, this catalyst has acceptable chemical stability.


Assuntos
Metronidazol , Poluentes Químicos da Água , Adsorção , Catálise , Ultrassom , Poluentes Químicos da Água/análise
17.
Int J High Risk Behav Addict ; 2(1): 28-33, 2013 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-24971268

RESUMO

BACKGROUND: Due to its progressive nature in all aspects of life, addiction endangers the health of individuals, families and the society. OBJECTIVES: The purpose of this study was to determine the role of self-regulation and affective control in predicting interpersonal reactivity of drug addicts. MATERIALS AND METHODS: This research is a correlation study. The statistical population of this study includes all drug addicts who were referred to addiction treatment centers of Ardabil in 2011 of whom 160 addicts were selected through convenience sampling. A self-regulation questionnaire, interpersonal reactivity questionnaire and affective control scale were used for data collection. RESULTS: Research results showed that self-regulation (r = -0.40) and affective control (r = -0.29) have a significant relationship with interpersonal reactivity of addicts (P < 0.001). The results of the multiple regression analysis indicated that 19 percent of interpersonal reactivity can be predicted by self-regulation and affective control. CONCLUSION: These results suggest that self-regulation and affective control play an important role in exacerbating as well as reducing interpersonal reactivity of addicts.

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