The effects of different activating agents on the physical and electrochemical properties of activated carbon electrodes fabricated from wood-dust of Shorea robusta.

This study focuses on the effects of activating agents on the physical and electrochemical properties of activated carbon (AC) electrodes, fabricated from wood dust of Shorea robusta. Three different activating agents namely H3PO4, KOH and Na2CO3 have been used to prepare ACs, which were named as: Sr-H3PO4, Sr-KOH and Sr-Na2CO3. The ACs were characterized by TGA/DSC, XRD, Raman, SEM, FTIR and BET. All the as prepared ACs were found to be amorphous in nature. The oxygen surface functionality was developed at the surface. The surface area of Sr-H3PO4, Sr-KOH and Sr-Na2CO3 were found to be 1269.5 m2/g, 280.6 m2/g and 58.9 m2/g respectively. The activated carbon-electrodes were then fabricated and supercapacitive performances were evaluated by "three electrode system" in aqueous 6M KOH using cyclic voltammetry (CV), galvanostatic charge discharge (GCD) and electrochemical impedance spectroscopy (EIS).The GCD performed at 1A/g revealed the specific capacitance values were 136.3 F/g, 42.2 F/g and 59.1 F/g for Sr-H3PO4, Sr-KOH and Sr-Na2CO3-electrodes, respectively. Energy density for Sr-H3PO4 electrode was found to be 3.0 Wh/kg at 99.6 W/kg power densities. Moreover, it also displayed imposing cyclic stability of about 96.9 %, 89.5 % and 78.5 % after 1000 cycles of charge/discharge respectively. The overall electrochemical performance of Sr-H3PO4 showed outstanding supercapacitive performances demonstrating the high possibility of this material to be used for the EDLC application in supercapacitive energy storage. The Nyquist plot also showed the lowest internal resistance of about 0.4 Ω for Sr-H3PO4 electrode.

Anticipated pain and pain experience among orthodontic patients: is there any difference?

BACKGROUND: Orthodontic treatment is taken as a painful procedure by most of the patients. The pain can be experienced during different procedures like separator placement, banding, bonding, extraction as well as arch wire activation and debonding. There are very few studies done on the anticipated pain and pain experienced among mentioned orthodontic procedures. OBJECTIVES: To compare the anticipated pain and pain experience among the patients going for comprehensive orthodontic treatment. METHODS: Total 45 patients going for comprehensive orthodontic therapy are enrolled into the study. They are given a 100mm Visual Analogue Scale (VAS) for pain. The anticipated pain as well as perceived pain after different orthodontic procedures are recorded on the VAS by patients and returned back to orthodontic office. The data are analyzed by SPSS 16.00 software by paired and independent t-test for the statistical significance. RESULTS: The result showed that there is significant difference between the anticipated pain before orthodontic treatment and the pain experienced following orthodontic treatment. It also showed that perception of pain between two sexes is significantly different. The comparison of anticipated pain among male and female does not show any significant difference, however the pain felt after separator placement as well as after orthodontic bonding is significantly different in two sexes. CONCLUSION: The level of anticipated pain before orthodontic treatment is higher than the real pain experienced after orthodontic procedures. So it is better to counsel and explain the patients about the orthodontic treatment and procedures.

Outcome of supracondylar fractures of the humerus in children treated by closed reduction and percutaneous pinning.

Supracondylar fractures of humerus in children are common injuries. Displaced fractures are inherently unstable. Conservative treatment results in malunion. Open reduction and internal fixation (ORIF) is more invasive and recovery is prolonged. From September 2004 to September 2005, 102 displaced supracondylar fractures of humerus, aged between one and half year to 13 years, were treated using close reduction and percutaneous Kirschner (K) wire fixation under c-arm fluoroscopy. Seventy nine patients were treated by cross K-wires and in twenty three cases lateral two K-wires were put. Above elbow plaster of paris back slab was applied in all cases for at least four weeks. Back slab, K-wires were removed after four weeks and elbow range of motion exercise was started. Results were analyzed using Flynn's criteria. All patients were followed up to 14th week postoperatively. In cross K-wire group(N=79) 70.8% had excellent, 22.7% good, 3.8% fair and 2.5% had poor results at eight weeks follow up which was improved to 91.1% excellent, 6.3 good, 1.2% fair and 1.26% poor results at 14 weeks follow up. In lateral K-wire group (N=23) 70% had excellent, 21.7% good, 4.3% fair and 4.3% had poor result at eighth week which was improved to 91.3% excellent, 4.3% good, 4.3% fair and no poor result at 14th week follow up. Eight patients got superficial pin tract infection and seven patients sustained ulnar nerve injury post operatively. We recommend this procedure for displaced supracondylar fractures in children as it is safe and cost effective procedure with acceptable complication rates.