The effect of antisite disorder on magnetic and exchange bias properties of Gd-substituted Y2CoMnO6double perovskite.

Combining experimental investigations and first-principles density functional theory (DFT) calculations, we report physical and magnetic properties of Gd-substituted Y2CoMnO6double perovskite, which are strongly influenced by antisite-disorder-driven spin configurations. On Gd doping, Co and Mn ions are present in mixed-valence (Co3+, Co2+, Mn3+and Mn4+) states. Multiple magnetic transitions have been observed: (i) paramagnetic to ferromagnetic transition is found to occur atTC= 95.5 K, (ii) antiferromagnetic transition atTN= 47 K is driven by3d-4fpolarization and antisite disorder present in the sample, (iii) change in magnetization belowT⩽20 K, primarily originating from Gd ordering, as revealed from our DFT calculations. AC susceptibility measurement confirms the absence of any spin-glass or cluster-glass phases in this material. A significantly large exchange bias effect (HEB= 1.07 kOe) is found to occur below 47 K due to interfaces of FM and AFM clusters created by antisite-disorder.

Emergence of weak pyrochlore phase and signature of field induced spin ice ground state in Dy2- x La x Zr2O7; x = 0, 0.15, 0.3.

The pyrochlore oxides Dy2Ti2O7 and Ho2Ti2O7 are well studied spin ice systems and have shown the evidences of magnetic monopole excitations. Unlike these, Dy2Zr2O7 is reported to crystallize in a distorted fluorite structure. We present here the magnetic and heat capacity studies of La substituted Dy2Zr2O7. Our findings suggest the absence of spin ice state in Dy2Zr2O7 but the emergence of the magnetic field induced spin freezing near T ≈ 10 K in ac susceptibility measurements which is similar to Dy2Ti2O7. The magnetic heat capacity of Dy2Zr2O7 shows a shift in the peak position from 1.2 K in zero field to higher temperatures in the magnetic field, with the corresponding decrease in the magnetic entropy. The low temperature magnetic entropy at 5 kOe field is R ln2 - (1/2)R ln(3/2) which is the same as for the spin ice state. Substitution of non-magnetic, isovalent La3+ for Dy3+ gradually induces the structural change from highly disordered fluorite to weakly ordered pyrochlore phase. The La3+ substituted compounds with less distorted pyrochlore phase show the spin freezing at lower field which strengthens further on the application of magnetic field. Our results suggest that the spin ice state can be stabilized in Dy2Zr2O7 either by slowing down of the spin dynamics or by strengthening the pyrochlore phase by suitable substitution in the system.

An experimental and theoretical study of magnetocaloric effect in Nd0.5Dy0.5FeO3.

A significant magnetocaloric effect (MCE) has been revealed in our investigation on polycrystalline Nd0.5Dy0.5FeO3 below 30 K. Observed magnetization of the system at low temperature is 32% higher than the expected average magnetization of NdFeO3 and DyFeO3. Such an enhancement in the magnetization led to a large change in magnetic entropy (10.4 Jkg-1 K-1) at 4 K. The observed entropy change is remarkable considering the higher natural abundance of Nd compared to that of Dy and negligible MCE seen in case of NdFeO3. Theoretical calculations performed using mean-field approximation and Monte Carlo simulations on an Ising type spin model indicate that the high magnetocaloric effect is caused primarily by the ordering of rare-earth ions in C-type antiferromagnetic state in presence of molecular exchange field created by Fe ions.