Affective response to tunes synthesized with musical pitch curves.

Tunes perceived as happy may help a user reach an affective state of positive valence. However, a user with negative valence may not be ready to listen to such a tune immediately. In this paper, we consider nudging a user from their current affective state to a target affective state in small steps. We propose a technique to generate a gradation of tunes between an initial-reference tune and a target-reference tune, to achieve the affect transition. The two-dimensional gradation is realized in time and in pitch, respectively, by varying the tempo and by the use of musical pitch curves, i.e. pitch transients or simply 'transients'. We exploit the duration and scaling of transients observed in South Indian music (Carnatic) to introduce transients into existing tunes. In our experiment, we have introduced the transients into Western music tunes. The results of perceptual evaluation show that the affective response to transients is likely to be higher at slow tempos than at fast tempos. Further, when felt, transient-tunes are twice as likely to be associated with positive valence than with negative valence, irrespective of tempo.

A Sensor-enabled Digital Trier Social Stress Test in an Enterprise Context.

The Trier Social Stress Test (TSST) protocol is a widely accepted method of inducing social and/or cognitive stress in participants and studying its effects. Traditionally, this protocol is administered in laboratory or university settings, which are less formal than in offices. In this paper, we report the results of the analysis of multi-modal sensor data collected from employees of an enterprise who underwent the test. We briefly discuss the adaptations that enabled administering it digitally in a semi-automatic mode with minimal researcher/test-administrator intervention. In our setup, noninvasive sensor-signals, including the Galvanic Skin Response and Photoplethysmogram, were collected during and outside the stress-inducing tasks. We analyze the data collected from twenty participants and show that the State Trait Anxiety Inventory (STAI) score is needed in assessing the effect of the digital version of the TSST. A support vector machine classifier yielded an F1 score of 0.723 with the STAI score taken as ground truth. We also introduce the idea of ground truth based on the change in the STAI scores to reduce variation due to subjective interpretation, for which an F1 score of 0.847 was obtained.

Unraveling substituent effects on the glass transition temperatures of biorenewable polyesters.

Converting biomass-based feedstocks into polymers not only reduces our reliance on fossil fuels, but also furnishes multiple opportunities to design biorenewable polymers with targeted properties and functionalities. Here we report a series of high glass transition temperature (Tg up to 184 °C) polyesters derived from sugar-based furan derivatives as well as a joint experimental and theoretical study of substituent effects on their thermal properties. Surprisingly, we find that polymers with moderate steric hindrance exhibit the highest Tg values. Through a detailed Ramachandran-type analysis of the rotational flexibility of the polymer backbone, we find that additional steric hindrance does not necessarily increase chain stiffness in these polyesters. We attribute this interesting structure-property relationship to a complex interplay between methyl-induced steric strain and the concerted rotations along the polymer backbone. We believe that our findings provide key insight into the relationship between structure and thermal properties across a range of synthetic polymers.

Fast Self-Healing of Polyelectrolyte Multilayer Nanocoating and Restoration of Super Oxygen Barrier.

A self-healable gas barrier nanocoating, which is fabricated by alternate deposition of polyethyleneimine (PEI) and polyacrylic acid (PAA) polyelectrolytes, is demonstrated in this study. This multilayer film, with high elastic modulus, high glass transition temperature, and small free volume, has been shown to be a super oxygen gas barrier. An 8-bilayer PEI/PAA multilayer assembly (≈700 nm thick) exhibits an oxygen transmission rate (OTR) undetectable to commercial instrumentation (<0.005 cc (m-2 d-1 atm-1 )). The barrier property of PEI/PAA nanocoating is lost after a moderate amount of stretching due to its rigidity, which is then completely restored after high humidity exposure, therefore achieving a healing efficiency of 100%. The OTR of the multilayer nanocoating remains below the detection limit after ten stretching-healing cycles, which proves this healing process to be highly robust. The high oxygen barrier and self-healing behavior of this polymer multilayer nanocoating makes it ideal for packaging (food, electronics, and pharmaceutical) and gas separation applications.