A chip-scale atomic beam clock.

Atomic beams are a longstanding technology for atom-based sensors and clocks with widespread use in commercial frequency standards. Here, we report the demonstration of a chip-scale microwave atomic beam clock using coherent population trapping (CPT) interrogation in a passively pumped atomic beam device. The beam device consists of a hermetically sealed vacuum cell fabricated from an anodically bonded stack of glass and Si wafers in which lithographically defined capillaries produce Rb atomic beams and passive pumps maintain the vacuum environment. A prototype chip-scale clock is realized using Ramsey CPT spectroscopy of the atomic beam over a 10 mm distance and demonstrates a fractional frequency stability of ≈1.2 × 10-9/[Formula: see text] for integration times, τ, from 1 s to 250 s, limited by detection noise. Optimized atomic beam clocks based on this approach may exceed the long-term stability of existing chip-scale clocks, and leading long-term systematics are predicted to limit the ultimate fractional frequency stability below 10-12.

Facile one step green synthesis of iron nanoparticles using grape leaves extract: textile dye decolorization and wastewater treatment.

The existing knowledge on the reactivity of green iron particles on textile dye and wastewater decolorization is very limited. In this study, the potential of green iron particles synthesized using grape leaves extract on reactive dye (reactive red 195, reactive yellow 145, reactive blue 4 and reactive black 5) decolorization were investigated. 95-98% of decolorization was achieved for all reactive dyes at 1.4-2.0 g/L of green iron. Maximum decolorization was attained at lower dye concentration and showed very little impact on decolorization when pH was increased from 3 to 11. The pseudo-first-order fit confirms the reaction between iron particles and dye molecules with rate constant 0.317-0.422 and it is followed by adsorption, data fit with pseudo-second-order model. Hence, not only adsorption but also the reduction process is involved in the reactive dye decolorization. Benzene, phenyl sodium, 2-chloro-1,3,5-triazine, naphthalene, sodium benzene sulfonate, benzene 1,2 di amine, anthracene-9,10 dione, aniline, phenol, benzene sulfonic acid were the major intermediates detected in dye decolorization and the respective reaction pathway is proposed. Green iron from grape leaves extract demonstrated better performance and it is recognized as the promising cost-effective material for textile wastewater treatment.

High-quality-factor microring resonator for strong atom-light interactions using miniature atomic beams.

An integrated photonic platform is proposed for strong interactions between atomic beams and annealing-free high-quality-factor (Q) microresonators. We fabricated a thin-film, air-clad SiN microresonator with a loaded Q of 1.55×106 around the optical transition of 87Rb at 780 nm. This Q is achieved without annealing the devices at high temperatures, enabling future fully integrated platforms containing optoelectronic circuitry. The estimated single-photon Rabi frequency (2g) is 2π×64MHz 100 nm above the resonator. Our simulation result indicates that miniature atomic beams with a longitudinal speed of 0.2 m/s to 30 m/s will interact strongly with our resonator, allowing for the detection of single-atom transits and realization of scalable single-atom photonic devices. Interactions between racetrack resonators and thermal atomic beams are also simulated.

Nematic-Orbit Coupling and Nematic Density Waves in Spin-1 Condensates.

We propose the creation of artificial nematic-orbit coupling in spin-1 Bose-Einstein condensates, in analogy with spin-orbit coupling. Using a suitably designed microwave chip, the quadratic Zeeman shift, normally uniform in space, can be made to be spatiotemporally varying, leading to a coupling between spatial and nematic degrees of freedom. A phase diagram is explored where three quantum phases with the nematic order emerge: easy axis, easy plane with single-well structure, and easy plane with double-well structure in momentum space. By including spin-dependent and spin-independent interactions, we also obtain the low energy excitation spectra in these three phases. Last, we show that the nematic-orbit coupling leads to a periodic nematic density modulation in relation to the period λ_{T} of the cosinusoidal quadratic Zeeman term. Our results point to the rich possibilities for manipulation of tensorial degrees of freedom in ultracold gases without requiring Raman lasers, and therefore, obviating light-scattering induced heating.

Textile dye degradation using nano zero valent iron: A review.

Water soluble unfixed dyes and inorganic salts are the major pollutants in textile dyeing industry wastewater. Existing treatment methods fail to degrade textile dyes and have limitations too. The inadequate treatment of textile dyeing wastewater is a major concern when effluent is directly discharged into the nearby environment. Long term disposal threatens the environment, which needs reclamation. This article reviews the current knowledge of nano zero valent iron (nZVI) technique in the degradation of textile dyes. The application of nZVI on textile dye degradation is receiving great attention in the recent years because nZVI particles are highly reactive towards the pollutant, less toxic, and economical. The nZVI particles aggregate quickly with respect to time and the addition of supports such as resin, nickel, zinc, bentonite, biopolymer, kaolin, rectorite, nickel-montmorillonite, bamboo, cellulose, biochar, graphene, and clinoptilolite enhanced the stability of iron nanoparticles. Inclusion of supports may in turn introduce additional toxic pollutants, hence green supports are recommended. The majority of investigations concluded dye color removal as textile dye compound removal, which is not factual. Very few studies monitored the removal of total organic carbon and observed the products formed. The results revealed that partial mineralization of the textile dye compound was achieved. Instead of stand alone technique, nZVI can be integrated with other suitable technique to achieve complete degradation of textile dye and also to treat multiple pollutants in the real textile dyeing wastewater. It is highly recommended to perform more bench-scale and pilot-scale studies to apply this technique to the textile effluent contaminated sites.