RESUMO
The characteristics of an LED lighting system consisting of a commercial violet LED and a green phosphor based on CsPbBr3 nanocrystals are studied in the context of development of LED illumination sources with antibacterial effects but without harmful effects on human health. The internal efficiency of the nanocrystalline phosphor in a silicone compound was found to exceed 40%, dropping noticeably because of heating for an electric current of ~0.1 A (phosphor excitation intensity ~0.1 W/mm2). This undesirable feature can be diminished by using a remote phosphor design for the illuminators and by using chemical techniques to improve the thermal stability of the nanocrystals.
RESUMO
The effect of gold and silver plasmonic films on the photoluminescence and photostability of InP/ZnSe/ZnSeS/ZnS nanocrystals (quantum dots) is reported. Colloidal gold films promote the photostability enhancement of InP/ZnSe/ZnSeS/ZnS quantum dots (more durable emission properties in the presence of metal nanostructures) through reducing exciton lifetime. In contrast, silver decreases the photostability of InP/ZnSe/ZnSeS/ZnS quantum dots without changing the photoluminescence intensity and kinetics. By adjusting the excitation wavelength closer to the extinction band of gold nanoparticles a 1.8-fold enhancement of luminescence intensity has been obtained using a polyelectrolyte spacer between the metal and InP/ZnSe/ZnSeS/ZnS nanoparticles. Thus, plasmonics offers essential practical improvement of light emitters in terms of their durable luminescent properties upon prolonged optical excitation without losses in luminescence efficiency or even along with increased efficiency.