Extensive use of waste glass in one-part alkali-activated materials: Towards sustainable construction practices.

The feasibility of the extensive recycling of waste glass in alkali-activated materials (AAMs) was evaluated. The waste glass was utilised in AAMs for two purposes: a partial activator and a mineral precursor. The waste glass was blended with commercial sodium hydroxide and then heated to produce the solid activator powder. The technical performance of waste glass-based activator was investigated to replace commercial sodium silicate, a common alkali-activator used in AAMs. The effect of waste glass using only as the activator (WGA) and using as both activator and precursor (WGAP) in fly ash/slag-based one-part AAMs was studied using strength and microstructure characterisations. A mass-cost and emission analysis of waste glass-based AAMs (WGA and WGAP) was conducted, comparing the results with ordinary Portland cement (OPC). Characterisation tests of waste glass-based activator showed the effective formation of sodium silicate minerals with the adequate dissolution of activator in water by releasing reactive alkali and silica. Both WGA and WGAP showed comparable strengths at 56 days with a denser microstructure under ambient curing. According to mass analysis, waste glass could be utilised up to 17% by mass of total binder. Based on the analysis of cost and CO2 emissions, WGA and WGAP are around 23% and 15% cheaper and 84% and 82% greener than OPC. The dual role of waste glass in AAMs as an activator and as a precursor broadens the recycling of glass waste in the cement industry by favouring technical and environmental outcomes.

Self-assembly and viscosity changes of binary surfactant solutions: A molecular dynamics study.

HYPOTHESIS: Structure and self-assembly of surfactants in the solution shows a fundamental influence on its viscosity. Through molecular simulations using Martini force field, synergistic effects in aggregation as well as the viscosity changes of a binary ionic surfactant system can be modelled. Simulations: Coarse-grained molecular dynamics simulations are performed to model the SDS/CAPB binary surfactant solution, and both equilibrium and non-equilibrium methods are used to calculate the viscosity of the equilibrated micellar systems. FINDINGS: Our simulation results indicate that the new version of the Martini force field can provide more reasonable self-assembly of surfactant, both single and binary system. Synergistic effects in micelle formation for SDS/CAPB have been successfully reproduced, that is, the formation of cylindrical micelles or even wormlike micelles at a lower concentration when compared with the pure system. Meanwhile, both equilibrium and non-equilibrium methods provide quantitatively comparable viscosity for each system. For pure micellar system, the viscosity linearly increases with the total concentration. Nevertheless, our simulation fails to capture the viscosity enhancement of the solution in corresponding with the formation of rodlike or wormlike micelles, and a full parameter optimization of force field is still necessary.

Different strategies of foam stabilization in the use of foam as a fracturing fluid.

An attractive alternative to mitigate the adverse effects of conventional water-based fluids on the efficiency of hydraulic fracturing is to inject foam-based fracking fluids into reservoirs. The efficiency of foaming fluids in subsurface applications largely depends on the stability and transportation of foam bubbles in harsh environments with high temperature, pressure and salinity, all of which inevitably lead to poor foam properties and thus limit fracturing efficiency. The aim of this paper is to elaborate popular strategies of foam stabilization under reservoir conditions. Specifically, this review first discusses three major mechanisms governing foam decay and summarizes recent progress in research on these phenomena. Since surfactants, polymers, nanoparticles and their composites are popular options for foam stabilization, their stabilizing effects, especially the synergies in composites, are also reviewed. In addition to reporting experimental results, the paper also reports recent advances in interfacial properties via molecular dynamical simulation, which provide new insights into gas/liquid interfacial properties under the influence of surfactants at molecular scale. The results of both experiments and simulations indicate that foam additives play an essential role in foam stability and the synergic effects of surfactants and nanoparticles exhibit more favorable performance.

Pore scale investigation on scaling-up micro-macro capillary number and wettability on trapping and mobilization of residual fluid.

The mobilization mechanism of the trapped phases controlled by the viscous force and capillary force in porous media is crucial to various engineering applications. In this paper, pore scale water flooding process in rock models with nonuniform wettability is simulated by computational fluid dynamics (CFD) using the volume of fluid (VOF) model. Four types of rock are imaged by micro-CT (µ-CT) and adopted as inputs to generate the structured mesh models. The simulations of two-phase flow are carried out to study the immiscible displacement process in the development of oil fields. The scaling-up critical capillary number at micro-macro scale are acquired and validated, the effects of which on relative permeability, residual oil recovery and immiscible displacement efficiency are analyzed. The simulation results indicate that the critical capillary number at microscopic scale ranges from 10-6 to 10-5 for water-wetted and oil-wetted rock respectively, and approaches to 1 at the macro scale. The effect of wettability on oil recovery is positive for intermediate-wetted or weak water-wetted rock, while negative for strong wettability.

Assessment of dynamic material properties of intact rocks using seismic wave attenuation: an experimental study.

The mechanical properties of any substance are essential facts to understand its behaviour and make the maximum use of the particular substance. Rocks are indeed an important substance, as they are of significant use in the energy industry, specifically for fossil fuels and geothermal energy. Attenuation of seismic waves is a non-destructive technique to investigate mechanical properties of reservoir rocks under different conditions. The attenuation characteristics of five different rock types, siltstone, shale, Australian sandstone, Indian sandstone and granite, were investigated in the laboratory using ultrasonic and acoustic emission instruments in a frequency range of 0.1-1 MHz. The pulse transmission technique and spectral ratios were used to calculate the attenuation coefficient (α) and quality factor (Q) values for the five selected rock types for both primary (P) and secondary (S) waves, relative to the reference steel sample. For all the rock types, the attenuation coefficient was linearly proportional to the frequency of both the P and S waves. Interestingly, the attenuation coefficient of granite is more than 22% higher than that of siltstone, sandstone and shale for both P and S waves. The P and S wave velocities were calculated based on their recorded travel time, and these velocities were then used to calculate the dynamic mechanical properties including elastic modulus (E), bulk modulus (K), shear modulus (µ) and Poisson's ratio (ν). The P and S wave velocities for the selected rock types varied in the ranges of 2.43-4.61 km s-1 and 1.43-2.41 km h-1, respectively. Furthermore, it was observed that the P wave velocity was always greater than the S wave velocity, and this confirmed the first arrival of P waves to the sensor. According to the experimental results, the dynamic E value is generally higher than the static E value obtained by unconfined compressive strength tests.

Experimental investigation of geochemical and mineralogical effects of CO2 sequestration on flow characteristics of reservoir rock in deep saline aquifers.

Interactions between injected CO2, brine, and rock during CO2 sequestration in deep saline aquifers alter their natural hydro-mechanical properties, affecting the safety, and efficiency of the sequestration process. This study aims to identify such interaction-induced mineralogical changes in aquifers, and in particular their impact on the reservoir rock's flow characteristics. Sandstone samples were first exposed for 1.5 years to a mixture of brine and super-critical CO2 (scCO2), then tested to determine their altered geochemical and mineralogical properties. Changes caused uniquely by CO2 were identified by comparison with samples exposed over a similar period to either plain brine or brine saturated with N2. The results show that long-term reaction with CO2 causes a significant pH drop in the saline pore fluid, clearly due to carbonic acid (as dissolved CO2) in the brine. Free H(+) ions released into the pore fluid alter the mineralogical structure of the rock formation, through the dissolution of minerals such as calcite, siderite, barite, and quartz. Long-term CO2 injection also creates a significant CO2 drying-out effect and crystals of salt (NaCl) precipitate in the system, further changing the pore structure. Such mineralogical alterations significantly affect the saline aquifer's permeability, with important practical consequences for the sequestration process.

Energy monitoring and analysis during deformation of bedded-sandstone: use of acoustic emission.

This paper investigates the mechanical behaviour and energy releasing characteristics of bedded-sandstone with bedding layers in different orientations, under uniaxial compression. Cylindrical sandstone specimens (54 mm diameter and 108 mm height) with bedding layers inclined at angles of 10°, 20°, 35°, 55°, and 83° to the minor principal stress direction, were produced to perform a series of Uniaxial Compressive Strength (UCS) tests. One of the two identical sample sets was fully-saturated with water before testing and the other set was tested under dry conditions. An acoustic emission system was employed in all the testing to monitor the acoustic energy release during the whole deformation process of specimens. From the test results, the critical joint orientation was observed as 55° for both dry and saturated samples and the peak-strength losses due to water were 15.56%, 20.06%, 13.5%, 13.2%, and 13.52% for the bedding orientations 10°, 20°, 35°, 55°, and 83°, respectively. The failure mechanisms for the specimens with bedding layers in 10°, 20° orientations showed splitting type failure, while the specimens with bedding layers in 55°, 83° orientations were failed by sliding along a weaker bedding layer. The failure mechanism for the specimens with bedding layers in 35° orientation showed a mixed failure mode of both splitting and sliding types. Analysis of the acoustic energy, captured from the acoustic emission detection system, revealed that the acoustic energy release is considerably higher in dry specimens than that of the saturated specimens at any bedding orientation. In addition, higher energy release was observed for specimens with bedding layers oriented in shallow angles (which were undergoing splitting type failures), whereas specimens with steeply oriented bedding layers (which were undergoing sliding type failures) showed a comparatively less energy release under both dry and saturated conditions. Moreover, a considerable amount of energy dissipation before the ultimate failure was observed for specimens with bedding layers oriented in shallow angles under both dry and saturated conditions. These results confirm that when rock having bedding layers inclined in shallow angles the failures could be more violent and devastative than the failures of rock with steeply oriented bedding layers.

Performance evaluation of cement stabilized fly ash-GBFS mixes as a highway construction material.

Fly ash and granulated blast furnace slag (GBFS) are major by-products of thermal and steel plants, respectively. These materials often cause disposal problems and environmental pollution. Detailed laboratory investigations were carried out on cement stabilized fly ash-(GBFS) mixes in order to find out its suitability for road embankments, and for base and sub-base courses of highway pavements. Proctor compaction test, unconfined compressive strength (UCS) test and California Bearing Ratio (CBR) test were conducted on cement stabilized fly ash-GBFS mixes as per the Indian Standard Code of Practice. Cement content in the mix was varied from 0% to 8% at 2% intervals, whereas the slag content was varied as 0%, 10%, 20%, 30% and 40%. Test results show that an increase of either cement or GBFS content in the mixture, results in increase of maximum dry density (MDD) and decrease of optimum moisture content (OMC) of the compacted mixture. The MDD of the cement stabilized fly ash-GBFS mixture is comparably lower than that of similarly graded natural inorganic soil of sand to silt size. This is advantageous in constructing lightweight embankments over soft, compressible soils. An increase in percentage of cement in the fly ash-GBFS mix increases enormously the CBR value. Also an increase of the amount of GBFS in the fly ash sample with fixed cement content improves the CBR value of the stabilized mix. In the present study, the maximum CBR value of compacted fly ash-GBFS-cement (52:40:8) mixture obtained was 105%, indicating its suitability for use in base and sub-base courses in highway pavements with proper combinations of raw materials.