Recent trends and advancement in metal oxide nanoparticles for the degradation of dyes: synthesis, mechanism, types and its application.

Synthetic dyes play a crucial role in our daily lives, especially in clothing, leather accessories, and furniture manufacturing. Unfortunately, these potentially carcinogenic substances are significantly impacting our water systems due to their widespread use. Dyes from various sources pose a serious environmental threat owing to their persistence and toxicity. Regulations underscore the urgency in addressing this problem. In response to this challenge, metal oxide nanoparticles such as titanium dioxide (TiO2), zinc oxide (ZnO), and iron oxide (Fe3O4) have emerged as intriguing options for dye degradation due to their unique characteristics and production methods. This paper aims to explore the types of nanoparticles suitable for dye degradation, various synthesis methods, and the properties of nanoparticles. The study elaborates on the photocatalytic and adsorption-desorption activities of metal oxide nanoparticles, elucidating their role in dye degradation and their application potential. Factors influencing degradation, including nanoparticle properties and environmental conditions, are discussed. Furthermore, the paper provides relevant case studies, practical applications in water treatment, and effluent treatment specifically in the textile sector. Challenges such as agglomeration, toxicity concerns, and cost-effectiveness are acknowledged. Future advancements in nanomaterial synthesis, their integration with other materials, and their impact on environmental regulations are potential areas for development. In conclusion, metal oxide nanoparticles possess immense potential in reducing dye pollution, and further research and development are essential to define their role in long-term environmental management.

A Short Review on Current Status and Obstacles in the Sustainable Production of Biohydrogen from Microalgal Species.

Biohydrogen is an economical fuel which has enormous promise as an alternative energy source. The synthesis of biohydrogen can be done more affordably and sustainably using microalgae. For the generation of biohydrogen and the treatment of wastewater, microalgae derived from effluent have been showing very impressive outcomes. In comparison to traditional fuel sources, microalgae have benefits. Microalgae are capable of fixing ambient Carbon dioxide and converting it to carbohydrates, which are subsequently processed biochemically to provide fuel. When compared to terrestrial crops, they require less water and minerals for production. But besides these benefits, there are certain technological restrictions on the scale-up implementations of microalgae bioenergy. In this work, we explored the production of biohydrogen from several types of microalgae. The process of producing biohydrogen is affected by a number of variables, including pH, substrate concentration, the kinds of microalgal species, and others. The most recent studies and difficulties related to each stage of the biohydrogen manufacturing process are outlined. The synthesis of microalgal biohydrogen is improved using promising approaches that are discussed. Also, the specific future direction are covered. The possibility for microalgae-based production of biohydrogen to serve as an environmentally friendly and carbon-free biofuel solution that might handle the impending fuel scarcity was demonstrated. However, additional study is required on both the upstream and downstream processes of the synthesis of biohydrogen.

Electrodeionization: Principle, techniques and factors influencing its performance.

Ecosystems are becoming more and more polluted, hence sustainable techniques of pollution removal are needed. In the recent times, exceedingly pure water has become ideal for several industries. Modern industry needs ultra-pure water, which is highly processed water that is devoid of colloidal particles and has a conductivity of less than 0.06 µS. A very effective method for removing ionic chemicals from polluted waters emerged recently called electrodeionization. Continuous electrodeionization (CEDI) is a technique for producing high-purity water. Besides rendering purified water, the technique has got promising wastewater treatment technologies - by facilitating the eradication of ionizable compounds, hazardous chemicals, radioactive pollutants, heavy metals and other potential contaminants. Innovative materials have been developed in order to advance and improve this technique, which would result in enormous ecological and financial benefit on a worldwide scale. In this review article, several factors that affect the performance of CEDI has been comprehended, with the impact of Ion-exchange resins and membranes as the focal point.

Continuous electrodeionization on the removal of toxic pollutant from aqueous solution.

Arsenic is among the most harmful pollutants and can create severe public health effects from such a small volume of water. Electrodeionization was used to eradicate arsenic ions from groundwater in this research. Electrodeionization system incorporates hybrid electro dialysis/ion exchange to remove and concentrate Arsenic ions from water, then reuses the processed water. The findings indicate that Electrodeionization will remove arsenic from liquids at intensities varies from 5 to 25 ppm in batch recirculation mode and 5-15 ppm in continuous column analysis. Although the device demonstrated the maximum ion percentage removal, of about 100 percent, when operated at a low voltage range from 5 to 20 V. A number of column studies were conducted to establish the breakthrough curves with concentrations ranging from 5 to 15 ppm, applied voltages ranging from 5 to 20 V, and flow rates ranging from 5 to 20 mL/min. For the present work, Arsenic was eliminated up to 98.8 percent in the trials reported here, with energy usage in the Electrodeionization unit varying around 3.88 and 60.7 kW h per kilogram of removed arsenic. This demonstrates the application's ability and productivity in removing Arsenic from aqueous solutions.

A review on recent trends in the removal of emerging contaminants from aquatic environment using low-cost adsorbents.

Emerging contaminants (ECs), a class of contaminants with low concentrations but significant harm, have received a lot of attention in recent times. ECs comprises of various chemicals that enter the environment every day. In today's modern lifestyle, we use many chemical-based products. These persist in wastewater and ultimately enter the water bodies, causing serious problems to the human and aquatic ecosystem. This is because the conventional wastewater treatment methods are inefficient in identifying and removing such contaminants. Aiming for a long-term, effective solution to this issue, Adsorption was proposed. Although several adsorbents are already present in the market, which have proved beneficial in removing such ECs, not all are affordable. This article reviews replacing costly adsorbents with agriculture-based biomass that are abundant, inexpensive, and biodegradable and possess excellent adsorption capacity. The objectives of this article is to look at adsorption as a viable treatment option for emerging pollutants, as well as sophisticated and cost-effective emerging contaminants treatment options.

Feasibility of magnetic nano adsorbent impregnated with activated carbon from animal bone waste: Application for the chromium (VI) removal.

Chromium is the heavy metal which existing in the effluents cause extensive discomfort to the environmental components. Bone waste is widely generated in food processing industries and restaurants. It is now used by switching into activated carbon. By co-precipitation procedure, the activated carbon is coated with a nano adsorbent. The Fe3O4-BAC adsorbent potential was established in this study via several batch tests. The adsorbing adverts had super magnetic behavior, and the magnetization value was 22 emu/g. The SEM imaging of the Fe3O4-BAC shows an improved morphology of 100-446 nm, and the nanoparticles were monodispersed. The present investigation also delves into the study of system parameters on the removal of metal ions. Optimal adsorption has been found at the acidic pH at the contact time of 60min for the adsorbent amount of 5 g/L. Maximum capacity of adsorption by nano adsorbent was 27.86 mg/g. Thermodynamic and isotherm tests have established the process viability. In addition, the kinetic studies establish the inclination of the studied Fe3O4-BAC towards pseudo-first order models. Hence, Fe3O4-BAC could be potential adsorbent to remove chromium from an aqueous solution.

A review on recent advances in electrodeionization for various environmental applications.

The growing contamination of ecosystems necessitates the development of long-term pollution-removal technologies. Electrodeionization, in notably, has newly proven as an efficient method for removing ionic chemicals from polluted waterways. The fact that continuous electrodeionization is a greener technique is most probably the biggest cause for its success. It replaces the toxic chemicals typically required to replenish resins with electric power, therefore eliminating the wastewater involved with resin renewal. In water treatment, electrodeionization solves some of the drawbacks of ion exchange resin beds, particularly ion dumping as beds expire. This comprehensive review explores the theory, principles, and mechanisms of ion movement and separation in an electrodeionization unit. Also, it investigated the construction and usage, notably in removing heavy metal and its current developments in electrodeionization unit. Recent advances in Electrodeionization like polarity reversal, Resin wafer Electrodeionization, membrane free Electrodeionization, and electrostatic shielding with novel materials and hybrid process along with Electrodeionization were addressed. Further advancements are expected in electrodeionization systems that exhibit better efficacy while running at lower costs due to decreased energy usage, rendering them appealing for industrial scale up across a wide range of applications across the world.

Critical review on hazardous pollutants in water environment: Occurrence, monitoring, fate, removal technologies and risk assessment.

Water is required for the existence of all living things. Water pollution has grown significantly, over the decades and now it has developed as a serious worldwide problem. The presence and persistence of Hazardous pollutants such as dyes, pharmaceuticals and personal care products, heavy metals, fertilizer and pesticides and their transformed products are the matter of serious environmental and health concerns. A variety of approaches have been tried to clean up water and maintain water quality. The type of pollutants present in the water determines the bulk of technological solutions. The main objective of this article was to review the occurrences and fate of hazardous contaminants (dyes, pharmaceuticals and personal care products, heavy metals, and pesticides) found in wastewater effluents. These effluents mingle with other streams of water and that are utilized for a variety of reasons such as irrigation and other domestic activities that is further complicating the issue. It also discussed traditional treatment approaches as well as current advances in hazardous pollutants removal employing graphite oxides, carbon nanotubes, metal organic structures, magnetic nano composites, and other innovative forms of useable materials. It also discussed the identification and quantification of harmful pollutants using various approaches, as well as current advancements. Finally, a risk assessment of hazardous pollutants in water is provided in terms of the human health and the environment. This data is anticipated to serve as a foundation for future improvements in hazardous pollutant risk assessment. Furthermore, future studies on hazardous pollutants must not only emphasize on the parent chemicals, as well as on their possible breakdown products in various media.

A review on adsorptive separation of toxic metals from aquatic system using biochar produced from agro-waste.

Water is a basic and significant asset for living beings. Water assets are progressively diminishing due to huge populace development, industrial activities, urbanization and rural exercises. Few heavy metals include zinc, copper, lead, nickel, cadmium and so forth can easily transfer into the water system either direct or indirect activities of electroplating, mining, tannery, painting, fertilizer industries and so forth. The different treatment techniques have been utilized to eliminate the heavy metals from aquatic system, which includes coagulation/flocculation, precipitation, membrane filtration, oxidation, flotation, ion exchange, photo catalysis and adsorption. The adsorption technique is a better option than other techniques because it can eliminate heavy metals even at lower metal ions concentration, simplicity and better regeneration behavior. Agricultural wastes are low-cost biosorbent and typically containing cellulose have the ability to absorb a variety of contaminants. It is important to note that almost all agro wastes are no longer used in their original form but are instead processed in a variety of techniques to improve the adsorption capacity of the substance. The wide range of adsorption capacities for agro waste materials were observed and almost more than 99% removal of toxic pollutants from aquatic systems were achieved using modified agro-waste materials. The present review aims at the water pollution due to heavy metals, as well as various heavy metal removal treatment procedures. The primary objectives of this research is to include an overview of adsorption and various agriculture based adsorbents and its comparison in heavy metal removal.

A review on sources, identification and treatment strategies for the removal of toxic Arsenic from water system.

Arsenic liberation and accumulation in the groundwater environment are both affected by the presence of primary ions and soluble organic matter. The most important influencing role in the co-occurrence is caused by human activity, which includes logging, agricultural runoff stream, food, tobacco, and fertilizers. Furthermore, it covers a wide range of developed and emerging technologies for removing arsenic impurities from the ecosystem, including adsorption, ion exchangers, bio sorption, coagulation and flocculation, membrane technology and electrochemical methods. This review thoroughly explores various arsenic toxicity to the atmosphere and the removal methods involved with them. To begin, the analysis focuses on the general context of arsenic outbreaks in the area, health risks associated with arsenic, and measuring techniques. The utilization of innovative functional substances such as graphite oxides, metal organic structures, carbon nanotubes, and other emerging types of composite materials, as well as the ease, reduced price, and simple operating method of the adsorbent material, are better potential alternatives for arsenic removal. The aim of this article is to examine the origins of arsenic, as well as identification and treatment methods. It also addressed recent advancements in Arsenic removal using graphite oxides, carbon nanotubes, metal organic structures, magnetic nano composites, and other novel types of usable materials. Under ideal conditions for the above methods, the arsenic removal will achieve nearly 99% in lab scale.

Application of adsorption process for effective removal of emerging contaminants from water and wastewater.

Emerging pollutants in the marine ecosystem, as well as their possible impact on live species, have become a rising cause of worry. A traditional wastewater treatment plants alone are not successful in eliminating such massive contaminant groups and therefore additional water treatment is required which is to be cost effective. Since standard primary and secondary treatment plants are unsuccessful at eliminating or degrading these harmful chemicals, a cost-effective tertiary treatment approach is proposed. Adsorption is a successful approach for Contaminants removal globally, because it is low installation expense, high performance and has easy operational design. Emerging pollutants have been removed from wastewaters using various adsorbents like activated carbons, improved bio chars, Nano adsorbents, hybrid adsorbents, and others. The purpose of this paper is to review the source of contaminants and the concept of adsorption when separating emerging contaminants. The present study aims to examine the adsorption mechanism as an effective approach for treating emerging contaminants. Then, the analysis of natural and man-made adsorbents for the separation of contaminants is examined along with its comparison. Also, future view on emerging contaminants and adsorbents in modern generation has been discussed.

An effective separation of toxic arsenic from aquatic environment using electrochemical ion exchange process.

The existence of arsenic in drinking water available for human consumption in multiple nations is among the major health issues globally. Intensified research efforts has made to eradicate arsenic contaminants from water in order to supply people who are living in multiple regions with safe drinking water. A novel process for the deletion of arsenic from aqueous solutions by the electrochemical ion exchange hybrid method were explored in this work. The paper aims to extract arsenic from aqueous solution and recycle it using an electrochemical ion exchange system for industrial purposes. A 3-compartment system was used to demonstrate this process: the center cell is separated from the anodized and cathodic chambers by means of double anionic exchange membrane, a middle cell packed with a strong anion exchange resin, and two rinse compartments, one at each electrode. Efforts are being made to illustrate the optimization of the operating parameters, including concentration, resin dose, pH, contact time, temperature for optimal arsenic removal in batch mode operation. The maximum removal of arsenic obtained is almost 100% and a minimum of 91% extraction at an initial intensity of 5-15 mg /L of arsenic with supply voltage in the 5-20 V range.

A review on effective removal of emerging contaminants from aquatic systems: Current trends and scope for further research.

Wastewater is water that has already been contaminated by domestic, industrial and commercial activity that needs to be treated before it could be discharged into some other water bodies to avoid even more groundwater contamination supplies. It consists of various contaminants like heavy metals, organic pollutants, inorganic pollutants and Emerging contaminants. Research has been doing on all types of contaminates more than a decade, but this emerging contaminants is the contaminants which arises mostly from pharmaceuticals, personal care products, hormones and fertilizer industries. The majority of emerging contaminants did not have standardized guidelines, but may have adverse effects on human and marine organisms, even at smaller concentrations. Typically, extremely low doses of emerging contaminants are found in the marine environment and cause a potential risk to the aquatic animals living there. When contaminants emerge in the marine world, they are potentially toxic and pose many risks to the health of both man and livestock. The aim of this article is to review the Emerging contaminate sources, detection methods and treatment methods. The purpose of this study is to consider the adsorption as a beneficial treatment of emerging contaminants also advanced and cost effective emerging contaminates treatment methods.

Role of in Situ Natural Organic Matter in Mobilizing As during Microbial Reduction of FeIII-Mineral-Bearing Aquifer Sediments from Hanoi (Vietnam).

Natural organic matter (NOM) can contribute to arsenic (As) mobilization as an electron donor for microbially-mediated reductive dissolution of As-bearing Fe(III) (oxyhydr)oxides. However, to investigate this process, instead of using NOM, most laboratory studies used simple fatty acids or sugars, often at relatively high concentrations. To investigate the role of relevant C sources, we therefore extracted in situ NOM from the upper aquitard (clayey silt) and lower sandy aquifer sediments in Van Phuc (Hanoi area, Vietnam), characterized its composition, and used 100-day microcosm experiments to determine the effect of in situ OM on Fe(III) mineral reduction, As mobilization, and microbial community composition. We found that OM extracted from the clayey silt (OMC) aquitard resembles young, not fully degraded plant-related material, while OM from the sandy sediments (OMS) is more bioavailable and related to microbial biomass. Although all microcosms were amended with the same amount of C (12 mg C/L), the extent of Fe(III) reduction after 100 days was the highest with acetate/lactate (43 ± 3.5% of total Fe present in the sediments) followed by OMS (28 ± 0.3%) and OMC (19 ± 0.8%). Initial Fe(III) reduction rates were also higher with acetate/lactate (0.53 mg Fe(II) in 6 days) than with OMS and OMC (0.18 and 0.08 mg Fe(II) in 6 days, respectively). Although initially more dissolved As was detected in the acetate/lactate setups, after 100 days, higher concentrations of As (8.3 ± 0.3 and 8.8 ± 0.8 µg As/L) were reached in OMC and OMS, respectively, compared to acetate/lactate-amended setups (6.3 ± 0.7 µg As/L). 16S rRNA amplicon sequence analyses revealed that acetate/lactate mainly enriched Geobacter, while in situ OM supported growth and activity of a more diverse microbial community. Our results suggest that although the in situ NOM is less efficient in stimulating microbial Fe(III) reduction than highly bioavailable acetate/lactate, it ultimately has the potential to mobilize the same amount or even more As.

Kinanthropometric and performance characteristics of elite and non-elite female softball players.

AIM: The purpose of the present study was to compare the kinanthropometric and performance characteristics of elite and non-elite female softball players. METHODS: A total forty elite and non-elite level female softball players were selected from the different colleges affiliated to the Guru Nanak Dev University, Amritsar, for the present study. The height of subjects was measured by using the standard anthropometric rod. Weight was measured with portable weighing machine. Widths and diameters of body parts were measured by using digital caliper. Girths and lengths were taken with steel tape. Skinfold thickness measurements were taken using the Slimguide skinfold caliper. All subjects were also assessed for performance tests i.e. vertical jump, 50m sprint, medicine ball throw, 10×4m shuttle run and reaction time. RESULTS: Independent samples t-test reveals that elite female softball players were significantly taller (P<0.05) than the non- elite players. The elite female softball players also had significantly greater biacromial (P<0.05), bi- illiocristal (P<0.05) and bicondylar femur (P<0.05) diameters and forearm circumference (P<0.05) as compared to non-elite female softball players. The non-elite female softball players were found to have significantly greater thigh circumference (P<0.05), triceps (P<0.05) and subscapular (P<0.05) skinfold thicknesses than the elite female softball players. The non-elite players were also found to have significantly higher percentage body fat (P<0.05) than the elite players. In performance tests, the elite players were found to have significantly better reaction time (P<0.05), speed (P<0.05) and agility (P<0.05) as compared to non-elite female softball players. CONCLUSION: The elite female softball players had significantly greater kinanthropometric characteristics, body composition and performance characteristics than the non-elite female softball players.

Evaluation of aqueous leaves extract of Moringa oleifera Linn for wound healing in albino rats.

Aqueous extract of leaves of M. oleifera was investigated and rationalised for its wound healing activity. The aqueous extract was studied at dose level of 300 mg/kg body weight using resutured incision; excision and dead space wound models in rats. Significant increase in wound closure rate, skin-breaking strength, granuloma breaking strength, hydroxyproline content, granuloma dry weight and decrease in scar area was observed. The prohealing actions seem to be due to increased collagen deposition as well as better alignment and maturation. From the results obtained, it may be concluded that the aqueous extract of M. oleifera has significant wound healing property.

MR imaging and in vivo proton spectroscopy of the brain in neonates with hypoxic ischemic encephalopathy.

INTRODUCTION: A number of studies have suggested the potential utility of in vivo proton MR spectroscopy for the evaluation of brain injury in the asphyxiated neonates. We present our initial experience with in vivo proton MR spectroscopy in neonates who were diagnosed as having hypoxic injury on clinical examination and the severity of the insult was graded using Sarnat staging. METHODS AND MATERIAL: MR imaging and in vivo proton MR spectroscopy was performed in 16 neonates with hypoxic ischemic encephalopathy (HIE) to correlate the imaging and metabolite abnormality with clinical severity of the condition at the time of insult and with outcome at 2 months of age. The ratios of different metabolites were calculated as observed on MR spectroscopy from an 8 ml voxel that included thalami, basal ganglia and part of the ventricular system using spin echo technique with an echo time of 135 ms. RESULTS AND DISCUSSION: The results of the spectroscopy were compared with imaging abnormalities and Sarnat's clinical staging of HIE. MR Imaging abnormalities included basal ganglia, thalamic and periventricular hemorrhage and periventricular hyperintensities and were noticed in 8/16 neonates with different stages of HIE. Maximum imaging abnormalities were noted in stage II (6/9) followed by stage III (1/2) and stage I (1/5), respectively. The alpha-Glx resonance at 3.76 ppm was seen in 14/16, Glycine at 3.56 ppm (Gly) was seen in 10/16 and Lactate (L) at 1.33 ppm was observed in 4/16 neonates with HIE. CONCLUSION: MR spectroscopy was more sensitive than imaging in detecting the insult due to HIE and increased concentration of alpha-Glx/Cr and Gly/Cr correlated better with severity of the HIE. The demonstration of L was associated with poor outcome.