Distribution, speciation, and assessment of heavy metals in sediments from Wadi Asal, Red Sea, Egypt.

Globally, the environmental contamination of stream sediments due to geogenic and anthropogenic sources is of growing concern. In this study, the heavy metals (Cd, Co, Cr, Cu, Ni, Pb, and Zn) in 22 superficial sediments in Wadi Asal, Red Sea, Egypt, were explored to assess sediment sources, the mobility of chemical species, and the degree of contamination in sediments. Therefore, the total heavy metal values in the fine fraction (< 63 µm), a five-step sequential extraction on selective samples, risk assessment, and principal component analysis (PCA) were applied. The mobility of heavy metals in Wadi Asal sediments, according to non-residual fraction percent, declines in the following order: Cd (90.9%) > Pb (85.2%) > Co (84.4%) > Cu (80.8%) > Zn (75.9%) > Ni (48.4%) > Cr (39.6%); indicating the high mobility of Cd, Zn, Pb, Cu, and Co. The mean metal contamination factor (CF) order is Cd (10.96) > Ni (3.91) > Cr (2.77) > Zn (2.18) > Pb (2.10) > Co (1.12) > Cu (0.70). The Geo-accumulation Index (Igeo) is decreased in the following order: Cd (2.19) > Ni (0.78) > Cr (0.55) > Zn (0.44) > Pb (0.42) > Co (0.22) > Cu (0.14). The risk assessment code (RAC) revealed very high to high risk for Cd, Co, and Pb. The results pointed out that the metals Cr, Co, Cu, and Ni are from geogenic sources, while Zn, Cd, and Pb are from anthropogenic sources due to Pb-Zn mining activities. Based on the threshold effect level (TEL), Cd, Cr, Ni, and Pb have adverse effects on living organisms. According to these findings, the area along Wadi Asal and the downstream regions on the beach are highly polluted and heavy metal monitoring in sediments and aquatic organisms is recommended.

Hydrogeological characteristics and water chemistry in a coastal aquifer of Korea: implications for land subsidence.

Land subsidence is the gradual or sudden dropping of the ground surface developed by increasing the total stress. Most studies have discussed the relationship between land subsidence with groundwater level. However, there is a lack of discussion on groundwater environmental changes after occurring land subsidence. This study aimed to evaluate the hydrogeological and water chemistry characteristics of construction sites with land subsidence. Land subsidence in the Yangyang coastal area occurred suddenly on August 3, 2022, when the retaining wall of the construction collapsed. The groundwater level was measured three times, and water samples were collected twice between August 5, 2022, and September 5, 2022, for laboratory analysis. After land subsidence occurred, the average groundwater level was - 19.91 m ground level (GL) on August 9, 2022, and finally decreased to - 19.21 m GL on September 05, 2022. The groundwater levels surrounding the construction site gradually increased for a month. The electrical conductivity value measured at the monitoring wells ranged from 89 to 7800 µS/cm, and four wells exceeded the measurement limit near the groundwater leaked points. The highest mixing ratio of leaked water samples, collected on August 9, 2022, was 27.6%. Furthermore, the fresh groundwater-saltwater interface depth was estimated to be above the construction bottom. Although groundwater levels recovered, the groundwater quality continuously is affected by saltwater. This finding could contribute to understanding the hydrogeological characteristics surrounding construction sites with land subsidence and provide insight into the hydrochemical evolution process during declined groundwater levels in coastal aquifers.

Heavy metal pollution in Manzala Lake sediments, Egypt: sources, variability, and assessment.

The environmental pollution of lake systems due to anthropogenic factors is of growing concern worldwide. Manzala Lake is the largest northern coastal-deltaic lakes of Egypt and has socioeconomic impacts. In this study, the concentrations and origins of seven heavy metals (HMs) and the organic content in the Manzala Lake sediments were explored during the winter and summer. The concentration of the HMs and the organic content were quantified using inductively coupled plasma and loss-on-ignition techniques. Pearson's correlation coefficient (PCC) and principal component analysis (PCA) were applied to evaluate the sources of the metals in the sediments. The HMs and organic matter were enriched during the winter season. The average concentrations of the HMs in the sediments conformed to the following sequence: Fe (14.13) > Mn (0.8) > Cu (0.11) > Zn (0.11) > Ni (0.06) > Pb (0.5) > Cd (0.002) (mg/kg). Sediment quality protocols showed that Mn, Cd, Cu, and Ni pose a significant threat to the aquatic environment in Manzala Lake. The geoaccumulation index (Igeo) values indicated pollution of the sediments with most metals, excluding Fe and Ni. The periodic mean Igeo pollution level followed the sequence Cd > Cu > Zn > Mn > Pb > Ni > Fe. The greatest pollution load index noted during the winter season was principally induced by Cd and Cu. The overall ecological risk index was moderate, with Cd being the most prominent HM. PCA combined with PCC showed that the HM enrichments in the southern (Bahr Al-Baqar Drain [S1], Bashteer [S3], Legan [S5], and Al-Ginka [S8]) and the extreme northeastern (El-Qapouti [S6]) parts of Manzala Lake sediments were mainly due to the discharge from different drains (industrial, agricultural, and municipal wastes) and the industrial region in Port Said, respectively. The lower HM concentrations from the extreme northern parts (Al-Boghaz [S2], Al-Temsah [S4], Al-Hamra [S7], and Al-Kowar [S9]) were due to their isolation from urban areas compared with the other localities. Extensive waste disposal was responsible for the HM pollution in the Manzala Lake sediments. Advanced treatment technologies and monitoring of the pollution in the water and sediments of Manzala Lake are required to decrease the accumulation of the heavy metals.

Sources and behavior of trace elements in groundwater in the South Eastern Desert, Egypt.

Due to water scarcity, the groundwater will represent an essential source of water in many communities worldwide. This study was carried out to investigate the main hydrogeochemical characteristic of trace elements composition, their sources, and its vulnerability in groundwater to the human population. Fifteen groundwater samples were collected from boreholes and hand dug wells from the South Eastern Desert, Egypt, and analyzed for Al, As, B, Fe, Mn, Cd, Co, Cr, Cu, Hg, Ni, Pb, Rb, Sb, Sr, Th, U, V, and Zn using inductively coupled plasma mass spectrometry. Multivariate analyses were applied to identify the distribution and potential source of trace elements. The groundwater is tapped from the Miocene and the fractured basement rock aquifers. The mean concentrations of trace elements exceed the guideline values of all organizations, except in some wells for Zn, Cu, and Co. Cationic trace elements declined in the order of Mn > Fe > Zn > Al > V > Ni > Rb > Sr > U > Cu > Cr > Co > Cd > Pb > Th > Sb > Hg. Oxyanions As (mean 15.48 mg/L) and B (mean 1.24 mg/L) showed very high concentrations and higher than the average WHO concentrations in water suggesting potential adverse toxicity to all aquatic organisms. Five factor analyses indicated that different geochemical contributions are involved in the chemical characteristics of groundwater in the study area. Water-rock interaction and dissolution processes in bed rocks from different coastal Miocene deposits, meta-volcanics, basic-ultrabasic rocks, granitic and meta-sediments, seawater intrusion, residential wastes, and mining activities, in addition to the pH/Eh conditions, adsorption, and surface complexation during the chemical weathering are the main factors influence the trace elements distribution in groundwater. Results from this study for the six different groundwater aquifers are a unique insight into the sources and mobility of the observed trace elements in the groundwater and can be used in the assessment of contamination for drinking water wells. The association of trace elements from different aquifers might be useful in tracers studies of water-rock interaction. Due to the enrichment of trace elements in nearshore and crystalline groundwater aquifers in the study area and in similar areas worldwide, treatment technologies, and sustainable water management processes should be applied to prevent severe risks to the communities.

Seasonal variation and enrichment of metals in sediments of Rosetta branch, Nile River, Egypt.

This study investigated heavy metal pollution in sediments of the Rosetta branch of the River Nile of Egypt to quantify the toxic distribution potential of metals into the surrounding environment. Sediment samples were collected at 9 sites during in four seasons. Organic matter and total metal concentrations were determined using loss on ignition and inductively coupled plasma spectrometry, respectively. Principal component analysis has been applied to evaluate the metal sources and the relationships between metals in sediments. Metal concentrations showed the following order: winter > autumn > spring > summer. Mean concentrations of Cu, Zn, Cd, and Pb in sediments were above the average background value of metals in shale. Pb and Cd showed higher enrichment during all seasons at stations N3/N4, Zn at stations N1 to N4, and Cu at stations N6/N8. The variations in heavy metal total concentration and organic matter are due to different input sources, physico-chemical conditions, and adsorption/precipitation/redox conditions in sediments. Mean values of Geo-accumulation index (Igeo) for Fe, Mn, and Cu were below 0 which were classified as unpolluted during spring, summer, and autumn, except Cu increased from unpolluted to moderately polluted during winter. Igeo values for Cd, Pb, and Zn increased from unpolluted-moderately polluted to highly-very highly polluted during autumn and winter. Pollution Load Index was recorded in highest values during winter, especially at Fuwwah/Basioun and in lowest values during summer at after the Edfina Barrage/before Kafer El-Zayat due to industrial/human activities. Both natural and anthropogenic sources contributed to the metal accumulations in sediments, and industrial, agricultural, and municipal sewage effluents discharged from non-point sources may be the main anthropogenic sources for metals in the Rosetta branch.

Application of mineral liberation analysis in studying micro-sedimentological structures within sulfide mine tailings and their effect on hardpan formation.

In this paper, mineral liberation analysis (MLA) was applied as a new approach to elucidate and quantify textural, mineralogical, and chemical variations on a µm/mm scale to understand the alteration processes relevant for hardpan formation at the Davidschacht mine tailings in Freiberg, Germany. Additionally, the bulk mineralogical, geochemical, and physical properties were investigated in detail. Within the upper 1.5m of this impoundment, a repetition was observed of oxidized sediments with pH values between 2 and 3, and of unoxidized sulfide/carbonate bearing sediments with pH values around 7.0. The alteration process was not homogeneous, as even within the same lamina different stages of oxidation were observed. According to the MLA measurements, the 2D pore area decreased from about 43 area-% in the unoxidized layers to 10.5-24.0 area-% in the hardpan layers, which is due to the accumulation of secondary precipitates. This clogging of pores was localized at the contact zone between two graded layers. The upper part of the lower layer consisted of very fine grained mica and chlorite fragments, which have a relatively high water retention capacity. This lamina was overlain by the bottom part of the next graded layer, which was characterized as relatively coarse grained with coarse open pores and an elevated content of primary reactive sulfides. This lamina provides access to oxygen and rain water to stimulate reactions, eventually supported by microbiological activity. Since graded layers might be amputated at top or bottom, the above described assemblage was not ubiquitous, but nevertheless multiple repetitions were encountered even at thin section level. The occurrence of these repetitions of slightly inclined tile like hardpans may reduce rain water and oxygen input at the rim of the impoundment. The application of MLA has opened up new opportunities for a better understanding of the sedimentological and mineralogical setup in relation to oxidation, transport, and precipitation processes on a µm scale within tailings impoundments.