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1.
Sci Total Environ ; 897: 165290, 2023 Nov 01.
Artigo em Inglês | MEDLINE | ID: mdl-37406703

RESUMO

In the present study, the ability of a coating of zinc oxide (ZnO) powder to improve the fire-safety of wood exposed to radiative heat flux was examined, focusing on the ignition time of the wood. To test ZnO's efficiency on the wood substrate, two different amounts of ZnO (0.5 and 1 g ZnO per dm2) were applied to the wood surface and exposed to radiative heat from a cone calorimeter wherein a pristine piece of wood with no ZnO treatment was taken as control. The experiments were conducted at three different irradiation levels i.e., 20, 35, and 50 kWm-2. The results showed that applying ZnO on the surface of the wood significantly increased the ignition time (TTI). For the three different heat fluxes, using 0.5 g ZnO per dm2 coating on the wood surface increased the TTI by 26-33 %. Furthermore, the application of 1 g of ZnO per dm2 generated a TTI increment of 37-40 %. All three irradiation levels showed similar trends in TTI. The micrographs taken before and after combustion showed no significant disparity in the morphology of ZnO. The agglomerated ZnO particles on the wood surface remained intact after combustion. This study demonstrates a facile method of using ZnO to delay the ignition of wood. This could potentially impart fire-safety to wooden structures/façades in wildland-urban interfaces and elsewhere by reducing flame spread.

2.
J Appl Polym Sci ; 138(27): 50658, 2021 Jul 15.
Artigo em Inglês | MEDLINE | ID: mdl-34149062

RESUMO

The global coronavirus disease 2019 (COVID-19) pandemic has rapidly increased the demand for facemasks as a measure to reduce the rapid spread of the pathogen. Throughout the pandemic, some countries such as Italy had a monthly demand of ca. 90 million facemasks. Domestic mask manufacturers are capable of manufacturing 8 million masks each week, although the demand was 40 million per week during March 2020. This dramatic increase has contributed to a spike in the generation of facemask waste. Facemasks are often manufactured with synthetic materials that are non-biodegradable, and their increased usage and improper disposal are raising environmental concerns. Consequently, there is a strong interest for developing biodegradable facemasks made with for example, renewable nanofibres. A range of natural polymer-based nanofibres has been studied for their potential to be used in air filter applications. This review article examines potential natural polymer-based nanofibres along with their filtration and antimicrobial capabilities for developing biodegradable facemask that will promote a cleaner production.

3.
Polymers (Basel) ; 12(7)2020 Jul 08.
Artigo em Inglês | MEDLINE | ID: mdl-32650531

RESUMO

Carbon based fillers have attracted a great deal of interest in polymer composites because of their ability to beneficially alter properties at low filler concentration, good interfacial bonding with polymer, availability in different forms, etc. The property alteration of polymer composites makes them versatile for applications in various fields, such as constructions, microelectronics, biomedical, and so on. Devastations due to building fire stress the importance of flame-retardant polymer composites, since they are directly related to human life conservation and safety. Thus, in this review, the significance of carbon-based flame-retardants for polymers is introduced. The effects of a wide variety of carbon-based material addition (such as fullerene, CNTs, graphene, graphite, and so on) on reaction-to-fire of the polymer composites are reviewed and the focus is dedicated to biochar-based reinforcements for use in flame retardant polymer composites. Additionally, the most widely used flammability measuring techniques for polymeric composites are presented. Finally, the key factors and different methods that are used for property enhancement are concluded and the scope for future work is discussed.

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