1.
Org Biomol Chem
; 12(13): 2045-8, 2014 Apr 07.
Artigo
em Inglês
| MEDLINE
| ID: mdl-24554233
RESUMO
A furan-based hexaazamacrocycle encapsulates a sulfate anion in its cavity showing strong affinity and selectivity for sulfate in water over a wide range of inorganic anions. The DFT calculations demonstrate that the receptor provides binding sites as hydrogen bonding donors and electrostatic positive charges for the strong binding of sulfate.