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Org Biomol Chem
; 21(32): 6438-6455, 2023 Aug 16.
Artigo
em Inglês
| MEDLINE
| ID: mdl-37522832
RESUMO
The Negishi coupling is a significant C-C bond-forming reaction to access synthetically valuable organic compounds. In recent years, researchers have developed sustainable first-row transition metal (Fe, Co, Ni and Cu) based complexes in place of the conventional Pd catalyst for this reaction. Several such low-cost metal-based catalysts showed high efficiency and potential application in natural product synthesis. This review focuses on the recent achievements in low-cost transition metal-based Negishi coupling reactions, covering reports from 2016.