RESUMO
We study electron correlation in sequential double ionization of noble gas atoms and HCl in intense, femtosecond laser pulses. We measure the photoelectron angular distributions of Ne+ relative to the first electron in a pump-probe experiment with 8 fs, 800 nm, circularly polarized laser pulses at a peak intensity of a few 10(15) W/cm2. Using a linear-linear pump-probe setup, we further study He, Ar, and HCl. We find a clear angular correlation between the two ionization steps in the sequential double ionization intensity regime.
RESUMO
The title compounds are diastereoisomers with antipodean axial chirality. The M isomer crystallizes as a (1/3) acetone solvate, C(32)H(30)NO(+).Br(-).3C(3)H(6)O, while the P isomer crystallizes as a (1/1) dichloromethane solvate, C(32)H(30)NO(+).Br(-).CH(2)Cl(2). In each structure, O-H.Br hydrogen bonds link the cations and anions to give ion pairs. The seven-membered azepinium ring adopts the usual twisted-boat conformation and its ring strain causes a slight curvature of the plane of each naphthyl ring.