Understanding the dynamics of enhanced light non-aqueous phase liquids (LNAPL) remediation at a polluted site: Insights from hydrogeophysical findings and chemical evidence.

This study intricately unfolds a pioneering methodology for remediating contaminants in a persistent light non-aqueous phase liquids (LNAPL)-contaminated site. The remediation strategy seamlessly integrates enhanced desorption and in-situ chemical oxidation (ISCO), orchestrating the injection of PetroCleanze® (a desorbent) and RegenOx® (an oxidizer) through meticulously designed wells. These injections, based on detailed geological and hydrogeological assessments, aim at mobilizing residual contaminants for subsequent extraction. Real-time subsurface dynamics are investigated through geophysical monitoring, employing electrical resistivity tomography (ERT) to trace reagent migration pathways via their effect on bulk electrical conductivity. The integration of groundwater sampling data aims at providing additional insights into the transformations of contaminants in the spatiotemporal context. Vivid two-dimensional time-lapse ERT sections showcase the evolution of resistivity anomalies, providing high-resolution evidence of the heterogeneity, dispersion pathways of desorbent and oxidant, and residual LNAPL mobilization. Hydrochemical analyses complement this, revealing effective mobilization processes with increasing aqueous concentrations of total petroleum hydrocarbons (TPH) over time. Speciation analysis unveils the intricate interplay of desorption and oxidation, portraying the dynamic fractionation of hydrocarbon components. The hydrogeophysical and data-driven framework not only delivers qualitative and quantitative insights into reagent and contaminant distribution but also enhances understanding of spatial and temporal physio-chemical changes during the remediation process. Time-lapse ERT visually narrates the reagent's journey through time, while chemical analyses depict the unfolding processes of desorption and oxidation across space and time. The coupling of hydrogeophysical and chemical findings pictures the transformations of pollutants following the sequence of product injection and the push and pull activities, capturing the removal of mobilized contaminants through hydraulic barrier wells. This enhanced understanding proves instrumental towards optimizing and tailoring remediation efforts, especially in heterogeneous environmental settings. This study establishes a new standard for a sophisticated and innovative contaminant remediation approach, advancing environmental practices through the harmonized analysis of geophysical and chemical data.

Environmental monitoring of the Capo Frasca military training site (West Sardinia): Operability and environmental protection balanced plan.

Military activities in training areas can contaminate soil and groundwater through different persistent pollutants. This article reports the design of the operating procedure to assess and monitor the environmental impact of training activities carried out at the Capo Frasca military firing range (PCF) on the west coast of Sardinia. The procedure includes two steps: (i) a baseline investigation of soil to detect the impact of previous training activities at PCF, and (ii) the development of a post-training monitoring plan. Results of the baseline investigations revealed that the activities conducted at PCF over many decades have not significantly affected the soil quality. Energetic compounds (ECs) were found below the limit of detection (LOD), and some low exceedances of the screening values (SVs) for Cd, Cu, and Ni were recorded in small areas that coincided with parts of two operational areas. A human health risk assessment (HHRA) identified no relevant issues. Results of baseline investigation allowed the planning of a light, noninvasive post-training monitoring plan based on two levels, L1 and L2, where L1 involves only manual sampling of topsoil (0-0.2 m). If L1 reveals contamination, a more in-depth and extensive L2 follow-up monitoring will be implemented. Results of post-training monitoring are not yet available. This environmental investigation protocol is intended to be a practical tool for regulatory provisions and is expected to be useful and effective for firing range management. This investigation also emphasized that, compared with the international state-of-the-art, environmental surveys in Italian military ranges require the improvement of ECs set to be analyzed, lowering EC LOD, and establishing ECs SVs. In Sardinia, many military areas, including PCF, are considered areas of significant natural interest. Therefore, it is deemed beneficial to move beyond HHRA and undertake the ecological risk assessment. Integr Environ Assess Manag 2024;00:1-16. © 2024 SETAC.

Contamination presence and dynamics at a polluted site: Spatial analysis of integrated data and joint conceptual modeling approach.

Contaminated sites are complex systems posing challenges for their characterization as both contaminant distribution and hydrogeological properties vary markedly at the metric scale, yet may extend over broad areas, with serious issues of spatial under-sampling in the space. Characterization with sufficient spatial resolution is thus, one of the main concerns and still open areas of research. To this end, the joint use of direct and indirect (i.e., geophysical) investigation methods is a very promising approach. This paper presents a case study aspiring to demonstrate the benefit of a multidisciplinary approach in the characterization of a hydrocarbon-contaminated site. Detailed multi-source data, collected via stratigraphic boreholes, laser-induced fluorescence (LIF) surveys, electrical resistivity tomography (ERT) prospecting, groundwater hydrochemical monitoring, and gas chromatography-mass spectrometry (GC-MS) analyses were compiled into an interactive big-data package for modeling activities. The final product is a comprehensive conceptual hydro-geophysical model overlapping multi-modality data and capturing hydrogeological and geophysical structures, as well as contamination distribution in space and dynamics in time. The convergence of knowledge in the joint model verifies the possibility of discriminating geophysical findings based on lithological features and contamination effects, unmasking the real characteristics of the pollutant, the contamination mechanisms, and the residual phase hydrocarbon sequestration linked to the hydrogeological dynamics and adopted remediation actions. The emerging conceptual site model (CSM), emphasizing the necessity of a large amount of multi-source data for its reliable, high-resolution reconstruction, appears as the necessary tool for the design of remedial actions, as well as for the monitoring of remediation performance.

A field-scale remediation of residual light non-aqueous phase liquid (LNAPL): chemical enhancers for pump and treat.

The remediation of petroleum-contaminated soil and groundwater is a challenging task. The petroleum hydrocarbons have a long persistence in both the vadose zone and in the aquifer and potentially represent secondary and residual sources of contamination. This is particularly evident in the presence of residual free-phase. Pump-and-treat is the most common hydrocarbon decontamination strategy. Besides, it acts primarily on the water dissolved phase and reduces concentrations of contaminants to an asymptotic trend. This study presents a case of enhanced light non-aqueous phase liquid (LNAPL) remediation monitored using noninvasive techniques. A pilot-scale field experiment was conducted through the injection of reagents into the subsoil to stimulate the desorption and the oxidation of residual hydrocarbons. Geophysical and groundwater monitoring during pilot testing controlled the effectiveness of the intervention, both in terms of product diffusion capacity and in terms of effective reduction of pollutant concentrations. In particular, non-invasive monitoring of the reagent migration and its capability to reach the target areas is a major add-on to the remediation technique. Most of the organic contaminants were decomposed, mobilized, and subsequently removed using physical recovery techniques. A considerable mass of contaminant was recovered resulting in the reduction of concentrations in the intervention areas.