Zr-Based MOF-545 Metal-Organic Framework Loaded with Highly Dispersed Small Size Ni Nanoparticles for CO2 Methanation.

We report the use of Zr-based metal-organic frameworks (MOFs) MOF-545 and MOF-545(Cu) as supports to prepare catalysts with uniformly and highly dispersed Ni nanoparticles (NPs) for CO2 hydrogenation into CH4. In the first step, we studied the MOF support under catalytic conditions using operando diffuse reflectance infrared Fourier transform (DRIFT) spectroscopy, ex situ characterizations (PXRD, XPS, TEM, and EDX-element mapping), and DFT calculations. We showed that the high-temperature conditions undoubtedly confer a potential for catalytic functionality to the solids toward CH4 production, while no role of the Cu could be evidenced. The MOF was shown to be transformed into a catalytically active material, amorphized but still structured with dehydroxylated Zr-oxoclusters, in line with DFT calculations. In the second step, Ni@MOF-545 catalysts were prepared using either impregnation (IM) or double solvent (DS) methods, followed by a dry reduction (R) route under H2 to immobilize Ni NPs. The highest catalytic activity was obtained with the Ni@MOF-545 DS R catalyst (595 mmolCH4 gNi-1 h-1) with 100% CH4 selectivity and 60% CO2 conversion after ∼3 h. The higher catalytic activity of Ni@MOF-545 DS R is a result of much smaller (∼5 nm) and better dispersed Ni NPs than in the IM sample (20-40 nm), the latter exhibiting sintering. The advantages of the encapsulation of Ni NPs by the DS method and of the use of a MOF-545-based support are discussed, highlighting the interest of designing yet-unexplored Zr-based MOFs loaded with Ni NPs for CO2 hydrogenation.

General Offending and Intimate Partner Violence Perpetration in Young Adulthood: A Dutch Longitudinal Study.

This study examines the relationship between general offending and intimate partner violence (IPV) perpetration in young adulthood, using a Dutch longitudinal study. Young adults were followed over four waves, and self-reported data on general offending, IPV perpetration, and a number of individual characteristics were collected. Results of random effects models demonstrated that young adults involved in more diverse offending behavior reported higher levels of different types of IPV perpetration, even when individual factors were taken into account. Moreover, logistic regression analyses showed that general offending was also related to an increased likelihood of continuity in IPV perpetration. Taken together, the findings indicate that it is useful to view IPV perpetration as part of a broader criminal career.

The Relationship Between the Development of General Offending and Intimate Partner Violence Perpetration in Young Adulthood.

This study examined how patterns in general offending relate to the occurrence of and likelihood of persistence in intimate partner violence (IPV) perpetration in young adulthood. The study used longitudinal data from the cohort of 18 year olds from the Project on Human Development in Chicago Neighborhoods study. Self-reported offending was measured in all three waves, and data on IPV were collected in Waves 1 and 3. Group-based trajectory modeling identified three distinct general offending trajectory groups: non-offenders, low-rate offenders, and high-rate offenders. The majority of respondents engaged in psychological IPV perpetration, and half of all young adults reported physical IPV, but prevalence rates decreased over the waves. Binary logistic regression analyses showed that those involved in offending, especially those who showed a diverse offending pattern, were at increased risk of perpetrating psychological and (severe) physical IPV, as well as to show persistence in the different forms of IPV perpetration. The findings highlight an important overlap between general crime and IPV perpetration. In recognition that IPV is often part of a broader pattern of antisocial behavior, interventions should focus on interrupting the criminal careers of all young offenders to reduce the prevalence and harms of IPV.

Enumeration of sublethally injured Escherichia coli O157:H7 ATCC 43895 and Escherichia coli strain B-41560 using selective agar overlays versus commercial methods.

Quality control procedures during food processing may involve direct inoculation of food samples onto appropriate selective media for subsequent enumeration. However, sublethally injured bacteria often fail to grow, enabling them to evade detection and intervention measures and ultimately threaten the health of consumers. This study compares traditional selective and nonselective agar-based overlays versus two commercial systems (Petrifilm and Easygel) for recovery of injured E. coli B-41560 and O157:H7 strains. Bacteria were propagated in tryptic soy broth (TSB), ground beef slurry, and infant milk formula to a density of 10(6) to 10(8) CFU/ml and then were stressed for 6 min either in lactic acid (pH 4.5) or heat shocked for 3 min at 60°C. Samples were pour plated in basal layers of either tryptic soy agar (TSA), sorbitol MacConkey agar (SMAC), or violet red bile agar (VRB) and were resuscitated for 4 h prior to addition of agar overlays. Other stressed bacteria were plated directly onto Petrifilm and Easygel. Results indicate that selective and nonselective agar overlays recovered significantly higher numbers (greater than 1 log) of acid- and heat-injured E. coli O157:H7 from TSB, ground beef, and infant milk formula compared with direct plating onto selective media, Petrifilm, or Easygel, while no significant differences among these media combinations were observed for stressed E. coli B-41560. Nonstressed bacteria from TSB and ground beef were also recovered at densities significantly higher in nonselective TSA-TSA and in VRB-VRB and SMAC-SMAC compared with Petrifilm and Easygel. These data underscore the need to implement food safety measures that address sublethally injured pathogens such as E. coli O157:H7 in order to avoid underestimation of true densities for target pathogens.

Judging risk: key determinants in British domestic violence cases.

Data from the largest study to date of the working practices of British victim support workers (known as Independent Domestic Violence Advisors or IDVAs) are used to provide insight into how "risk judgments" are made in cases of domestic violence. Using data from more than 2,000 victims, this study found a convergence between actuarial data and IDVAs' risk judgments when the risk score was high, but in cases with a lower risk score, IDVAs often used their professional judgment to upgrade risk. Next, we identified the specific factors underpinning IDVAs' risk judgments. Consistent with existing research, we found that IDVAs relied on a subset of available information when forming risk judgments, and characteristics of the abusive situation, such as the escalation of violence, use of weapons, stalking, and significant injuries, were particularly salient to them. Furthermore, IDVAs paid attention to victims' perceptions and when they felt very frightened or afraid of further injury then IDVAs were more likely to label them as high risk. Although we identified some encouraging overlap between the subset of factors informing risk judgments and those associated with victims' reabuse at a later date, some notable differences indicate a need for messages from research about the significance of particular risk factors to be reinforced to frontline practitioners on a regular basis.

The perceptions of high-risk victims of domestic violence to a coordinated community response in Cardiff, Wales.

Research was conducted with very high-risk victims of domestic violence to determine their levels of revictimization one year after being referred to a Multi-Agency Risk Assessment Conference (MARAC) and their perceptions of this type of intervention. The MARACs provide increased and ongoing communication between agencies and victims, risk assessments, advocacy to victims, help translating policy into action, and help in holding perpetrators to account. More than 4 in 10 victims reported no further violence one year after the MARAC. Nearly all victims first attributed responsibility for ending the violence to themselves and then acknowledged the importance of having multiagency support once they were ready to change their situations. This research reveals that taking a holistic multiagency approach to domestic violence can reduce recidivism, even among the population most at risk.

Reducing repeat victimization among high-risk victims of domestic violence: the benefits of a coordinated community response in Cardiff, Wales.

The goal of Multi-Agency Risk Assessment Conferences (MARACs) is to provide a forum for sharing information and taking actions to reduce harm to high-risk domestic violence victims. Interviews with participants and victims, observations, and police data reveal how the MARACs work in practice and also what they can accomplish. Results showed MARACs to be invaluable: Agencies assisted victims more efficiently, primarily through enhanced information sharing. MARACs improve victims' safety because both police and victim data revealed that 6 in 10 victims had not been revictimized. These positive results demonstrate the benefits of a coordinated community response.