Matching the critical portion of the flow duration curve to minimise changes in modelled excess shear.

Hydrologic and hydraulic modeling in the USEPA Stormwater Management Model (SWMM) were used to examine the effectiveness of typical stormwater management practices in reducing the potential for stream erosion. Fifty-year continuous simulations were used to produce flow duration curves and stream erosion rates for a variety of critical shear stress values representative of both cohesive and non-cohesive sediments. An excess shear stress erosion potential index was used to evaluate changes in erosion between undeveloped conditions of a 10 hectare watershed and four variations of post-development stormwater control. Evaluation of flow duration curves showed that when development takes place, the duration of mid- to low-range discharges increase significantly, especially when detention practices are applied. In channels with low entrainment thresholds for bed and bank materials, e.g. sands and highly erodible clays, the significant increase of the duration of mid- to low-range discharges results in erosion potential index values greater than two regardless of the detention practices used. Overcontrol detention resulted in erosion potential index values of less than one, indicating a loss of erosion potential for bed materials such as most gravels (d(s) > 6 mm) and resistant clays that have critical shear stress values greater than four Pa.

Factors influencing total dietary exposures of young children.

A deterministic model was developed to identify the critical input parameters needed to assess dietary intakes of young children. The model was used as a framework for understanding the important factors in data collection and data analysis. Factors incorporated into the model included transfer efficiencies of pesticide from surfaces to food, transfer efficiencies of pesticide from surfaces to hands to food, and more accurate microactivity data related to contact frequency for the three variables of interest--hands, surfaces, and food. Results from range-finding measurements of transfer efficiencies using an aqueous pesticide solution of a mixture of malathion, diazinon, and chlorpyrifos sprayed on the surfaces indicate that a higher pesticide transfer occurred from hard surfaces to food (hardwood, plastic), with low transfer from soft surfaces (carpet, cloth). Six children, all less than 4 years old, were videotaped to obtain realistic contact frequency and times for the interaction of hands, surfaces, and foods during eating meals and snacks while in their homes or day care centers. The time range of eating events varied from about 2 to 55 min, with an average of about 20 min. The average number of contact frequencies between food and hands was 19 times for each eating event, with a range of 10-40. Contacts between the surface and hand were about the same as the food and hands. Contacts between foods and surfaces ranged from 0 to 32, but only five or less of the contacts per eating event were associated with surfaces other than eating utensil. The children's microactivity data collected during the eating events, together with the laboratory results from the transfer studies, were provided as input into a Monte Carlo simulation of the dietary ingestion model. Simulation results indicate that children's handling of the food could contribute 20-80% of the total dietary intake of pesticides. Dietary exposure due to residues in the food before handling accounted for 16% and 47%, respectively, of the total mean intake from simulations for a child's consumption of an apple or banana. These results indicated that transfer efficiencies for foods on various surfaces typically found in homes as well as children's hand contacts with the food and surfaces are important as determinants of dietary exposure.