Characterization of water-soluble ions in PM10 over an industrial area in northern Colombia: Temporal variations and correlation with satellite data.

This study was designed to assess the concentrations of nine water-soluble ions in PM10 mass at two sites of an open-pit coal mine and to analyze the correlation and variation of the spatial distribution of sulfate ions with the PM10 sulfate aerosol optical depth at 550 nm (suaod550) in two (North and South) stations of the study area. The daily average of PM10 concentrations ranged from 20.48 to 53.10 µg/m3 and thus did not exceed the daily average maximum permissible level of PM10 (100 µg/m3) established in the Colombia standard at any station. The concentrations of nine water-soluble ions in PM10 (Cl-, NO3-, PO43-, SO42- Na+, NH4+, K+, Mg2+, and Ca2+) were determined. The ions under analysis, SO42-, Na+, and NH4+ had the highest concentrations. Combined, they accounted for 75% of the mass of water-soluble ions in a total of 210 samples. The SO42- concentrations in PM10 significantly correlated with suaod550 (r ranging from 0.57 to 0.66), emphasizing the strong effect of suaod550 from Venezuela (Lake Maracaibo) on central and northern Colombia. These results demonstrate that the effects of local sulfate emissions near monitoring sites can be predicted and assessed using satellite data.

Human health risk assessment of PM10-bound heavy metals and PAHs around the Latin America's Largest opencast coal mine.

Air pollution in opencast coal mine areas is a critical issue, resulting in harmful severe effects on human health. Therefore, it is essential to understand the air pollution factors and to assess the risks to humans. This study evaluated the potential risks (carcinogen and non-carcinogen) of inhalation exposure to PM10-bound heavy metals and Polycyclic Aromatic Hydrocarbons (PAHs) in an open pit mine in northern Colombia. During February-May 2022, PM10 samples were collected at eight sites. Heavy metals (i.e., Al, Cr(VI), Mn, Cu, Zn, As, Pb) and PAHs (thirteen priority PAHs, and one non-priority PAH) levels linked to PM10 were analyzed by X-ray fluorescence and gas chromatography-mass spectrometry, respectively. PM10 concentrations were found to range between 4.70 and 59.90 µg m-3. Out of the three different zones of the study area (i.e., North Zone, South Zone, and Populated Zone), the North Zone recorded the highest daily average concentrations of Cr(VI) (104.16 ng m-3), Mn (28.39 ng m-3), Cu (33.75 ng m-3), Zn (57.99 ng m-3), As (44.92 ng m-3), and Pb (27.13 ng m-3). The fraction of the analyzed heavy metals at all monitoring sites was 82%-89% for Al, followed by Cr(VI) with 3%-6%. Cr(VI) was the major contributor to the carcinogenic risk values, while Cu, Cr(VI), and As were the main drivers for the non-carcinogenic risk. The average cancer risk range for heavy metals was 3.30 × 10-04 -5.47 × 10-04. On the other hand, the cancer risk for PAHs exposure was acceptable. The average incremental lifetime cancer risk (ILCR) values varied between 2.87 × 10-07 and 4.21 × 10-07. Benzo[a]pyrene contributed to 54%-56% of the total risk from inhalation of PM10-bound PAHs, while Indeno[1,2,3-cd]pyrene contributed to 16%-19%. Based on the Monte Carlo sensitivity analysis, exposure to Cr(VI) was the main factor affecting cancer risk in the North, South, and Populated Zones. A suitable risk assessment and management plan requires understanding PM10-bound heavy metals and PAHs concentration levels as well as their potential health risks, mainly in open-cast coal mine zones. Our study found that people living near open-pit mines face potential health risks, so it is crucial to establish policies and regulations to control emission sources.

Health risk assessment for particulate matter: application of AirQ+ model in the northern Caribbean region of Colombia.

Air pollution is considered the world's most important environmental and public health risk. The annual exposure for particulate matter (PM) in the northern Caribbean region of Colombia between 2011 and 2019 was determined using PM records from 25 monitoring stations located within the area. The impact of exposure to particulate matter was assessed through the updated Global Burden of Disease health risk functions using the AirQ+ model for mortality attributable to acute lower respiratory disease (in children ≤ 4 years); mortality in adults aged > 18 years old attributable to chronic obstructive pulmonary disease, ischaemic heart disease, lung cancer, and stroke; and all-cause post-neonatal infant mortality. The proportions of the prevalence of bronchitis in children and the incidence of chronic bronchitis in adults attributable to PM exposure were also estimated for the population at risk. Weather Research and Forecasting-California PUFF (WRF-CALPUFF) modeling systems were used to estimate the spatiotemporal trends and calculate mortality relative risk due to prolonged PM2.5 exposure. Proportions of mortality attributable to long-term exposure to PM2.5 were estimated to be around 11.6% of ALRI deaths in children ≤ 4 years of age, 16.1% for COPD, and 26.6% for IHD in adults. For LC and stroke, annual proportions attributable to PM exposure were estimated to be 9.1% and 18.9%, respectively. An estimated 738 deaths per year are directly attributed to particulate matter pollution. The highest number of deaths per year is recorded in the adult population over 18 years old with a mean of 401 events. The mean risk in terms of the prevalence of bronchitis attributable to air pollution in children was determined to be 109 per 100,000 inhabitants per year. The maximum RR values for mortality (up 1.95%) from long-term PM2.5 exposure were predicted to correspond to regions downwind to the industrial zone. Supplementary information: The online version contains supplementary material available at 10.1007/s11869-023-01304-5.

Meteorological factors contributing to organic and elemental carbon concentrations in PM10 near an open-pit coal mine.

Variations in the carbonaceous aerosol contents, organic carbon (OC) and elemental carbon (EC), in particulate matter less than 10 µm in size (PM10), were analyzed at sites influenced by coal mining in an open-pit mine located in northern Colombia. Samples were collected during different seasonal periods throughout 2015. Meteorological variables for each site were examined during the different seasons. Aerosols were detected using a thermal-optical reflectance protocol method. The highest PM10 concentrations, between the ranges of 28.2 ± 8.2 µg m-3 and 75.0 ± 36.5 µg m-3, were recorded during the dry season. However, the highest concentrations of OC (4.8-14.2 µg m-3) and EC (2.9-13.9 µg m-3) in PM10 were observed during the transition period between the dry and wet seasons. The strong correlation between OC and EC in PM10 (r = 0.6-1.0) during the transition season indicates a common primary combustion source. High OC (> 8.3 µg m-3) and EC (> 6.9 µg m-3) concentrations were associated with low wind speeds (< 2.1 m s-1) moving in different directions. Analyses of the sources of atmospheric aerosol pollutants in the mining area in northern Colombia showed that the daily maximum total carbon concentrations were mainly associated with regional atmospheric transport of particulate matter from industrial areas and biomass burning sites located in the territory of Venezuela.

Changes in ambient particulate matter during the COVID-19 and associations with biomass burning and Sahara dust in northern Colombia.

The restriction of mobility due to preventive social isolation has improved air quality in many regions of the world. At the same time, global and regional atmospheric phenomena such as biomass burning or dust transport from Sahara can exacerbate particulate matter (PM) mass. In this study, PM10 and PM2.5 concentrations were evaluated in industrial and urban areas during the lockdown period due to COVID-19 in northern Colombia. Aerosol Optical Depth (AOD) observations obtained from the spaceborne MODIS (MOD04-3k) and the active fire data was obtained from VIIRS Active Fire. We measured surface contamination at several stations to quantify the PM10 and PM2.5 changes associated with the general closure of anthropogenic and industrial activities driven by COVID-19 and by the macroscale and/or mesoscale contributions. In the industrial zone, a slight decrease in daily concentrations was detected at the stations located near the mining operations. In the urban area, the decrease is more salient in COVID-19 lockdown. A reduction rate in the daily averages of PM10 of 23.3%, 6.0%, and 19.0% was observed in the SCa, SBi, and SUn stations, respectively. The biomass burning episode has contributed 52% to the daily average of PM10 and 45% to the daily average of PM2.5. The episode due to the passage of Saharan dust through the Caribbean Sea has contributed 79% to the daily average of PM10 (150.75 µg/m3) and on 57% to the daily average of PM2.5.

Impact of lockdown on particulate matter concentrations in Colombia during the COVID-19 pandemic.

The first confirmed case of COVID-19 in Colombia was reported on March 6, 2020. For this reason, on March 25, preventive isolation was declared mandatory. These measures involved the suspension of economic activities and drastically reduced the number of vehicles on the road. The objective of this study is to evaluate the impact of the lockdown due to the COVID-19 pandemic on PM2.5 concentrations at 5 monitoring stations and aerosol optical depth values of the Terra/MODIS satellite. We analyzed and compared the weekly and monthly concentrations of PM2.5 before and during the lockdown between the week of January 6 to June 22, 2020, and compared the daily values obtained from the Terra/MODIS satellite for the months of January-June during the years 2018-2020 to elucidate the effects of the lockdown. Similar to other monitored sites in the world, we observed substantial reductions in weekly PM2.5 concentrations, from 41 to 84% (Bogotá), from 13 to 66% (Funza), from 17 to 57% (Boyacá), from 35 to 86% (Valledupar) and 31 at 60% (Risaralda). Unlike other studies, the aerosol optical depth values increased up to 59% during the months of lockdown compared to previous years and up to 70% of the weekly mean when compared to before the lockdown. These spatiotemporal behaviors of PM2.5 and the aerosol optical depth in Colombia are influenced by reductions in vehicular flow during quarantine, regional rainfall, and height of the planetary boundary layer. Emissions from economic activities affect pollutant levels in the area. The analysis of the levels of pollutants during the lockdown provides a baseline for regulatory agencies to establish mitigation plans.

Intake Fraction of PM10 from Coal Mine Emissions in the North of Colombia.

Intake fraction was determined in this study to provide insight into population exposures to PM10 that is effectively inhaled due to emissions of an opencast coal mine. We applied the CALPUFF model to a coal mine in Northern Colombia, which has 6 active pits with an annual production of 33.7 million tons. We estimated the intake fractions for 7 towns through the integration of dispersion model results over the population data. The resulting average intake fractions were between 6.13 × 10-9 and 3.66 × 10-8 for PM10. 62.4% of the intake fractions in the domain were calculated within a 23 km radius from the coal mine and coved 44.3% of the total population in this area. We calculated an estimate point for morbidity impacts using standard epidemiological assumptions. It is estimated that there were annually 105835 restricted activity days and 336832 respiratory symptom cases due to the direct impact of the opencast coal mining. These data also provide a framework for improved understanding of the effect of coal mining in Colombia.