RESUMO
The 2,3-didecyloxy derivative of an n-type anthracene (n-BG) and a p-type tetracene (p-R) have been synthesized and their self-assembly into nano-ribbons studied. Hyperspectral fluorescence imaging revealed their narcissistic self-sorting, leading to separated nanoribbons emitting with very different colors (blue or green for n-BG, depending on the growth solvent, and red for p-R). It is unique that the usual origins of self-sorting, such as specific H-bonding, different growth kinetics, or incompatible steric hindrance can be ruled out. Hence, the narcissistic behaviour is herein proposed to originate from a so-far unconsidered cause: the discrepancy between the quadrupolar character of n-BG and dipolar character of p-R. At the p-n junctions of these nanoribbons, inter-ribbon FRET and electro-luminescence switch-on were observed by fluorescence/luminescence microscopy.
RESUMO
Semi-conducting polymers are promising materials for current and next generations of electronic devices, sensors and actuators, especially regarding their ability to conform to flexibles architectures. In particular, aqueous-based dispersions of semi-conducting complexes such as PEDOT:PSS can be printed using a variety of coating techniques and the conductivity of the final deposit may reach high values upon a proper treatment. The micro-structuration of these polymeric deposits remains challenging and of prime importance for further integration. We show here that a microfluidic post-treatment of PEDOT:PSS films of permits us to boost locally only their conductivity by several orders of magnitude, with a micron scale resolution. This is a fast process (~second), straightforward to upscale, that yields conductive patterns within the pristine film. Taking advantage of the localized Joule's effect, we evidence using quantitative thermography a very efficient heating behaviour of the conductive tracks, which makes these polymeric structures promising candidates for low cost, clean-room free electrodes for lab-on-chip applications.
RESUMO
A new functionalised graphene sheet (FGS) filled poly(dimethyl)siloxane insulator nanocomposite has been developed with high dielectric constant, making it well suited for applications in flexible electronics. The dielectric permittivity increased tenfold at 10 Hz and 2 wt.% FGS, while preserving low dielectric losses and good mechanical properties. The presence of functional groups on the graphene sheet surface improved the compatibility nanofiller/polymer at the interface, reducing the polarisation process. This study demonstrates that functionalised graphene sheets are ideal nanofillers for the development of new polymer composites with high dielectric constant values.PACS: 78.20.Ci, 72.80.Tm, 62.23.Kn.
