1.
Chem Commun (Camb)
; 47(45): 12295-7, 2011 Dec 07.
Artigo
em Inglês
| MEDLINE
| ID: mdl-22012242
RESUMO
Reaction of 2,6-dimesityl pyridine (L(py)) with BBr(3) leads to the spontaneous formation of the trigonal dibromoborenium cation [L(py)·BBr(2)](+)via bromide ejection. Systematic structural and computational studies, and the reactivity displayed by a closely related N-heterocyclic carbene (NHC) donor, reveal the role played by arene-borane interactions in this chemistry. [L(py)·BBr(2)](+) features a structurally characterized (albeit weak) electrostatic interaction between the borane Lewis acid and flanking arene π systems.