Low Cost and Compact FMCW 24 GHz Radar Applications for Snowpack and Ice Thickness Measurements.

Monitoring the evolution of snow on the ground and lake ice-two of the most important components of the changing northern environment-is essential. In this paper, we describe a lightweight, compact and autonomous 24 GHz frequency-modulated continuous-wave (FMCW) radar system for freshwater ice thickness and snow mass (snow water equivalent, SWE) measurements. Although FMCW radars have a long-established history, the novelty of this research lies in that we take advantage the availability of a new generation of low cost and low power requirement units that facilitates the monitoring of snow and ice at remote locations. Test performance (accuracy and limitations) is presented for five different applications, all using an automatic operating mode with improved signal processing: (1) In situ lake ice thickness measurements giving 2 cm accuracy up to ≈1 m ice thickness and a radar resolution of 4 cm; (2) remotely piloted aircraft-based lake ice thickness from low-altitude flight at 5 m; (3) in situ dry SWE measurements based on known snow depth, giving 13% accuracy (RMSE 20%) over boreal forest, subarctic taiga and Arctic tundra, with a measurement capability of up to 3 m in snowpack thickness; (4) continuous monitoring of surface snow density under particular Antarctic conditions; (5) continuous SWE monitoring through the winter with a synchronized and collocated snow depth sensor (ultrasonic or LiDAR sensor), giving 13.5% bias and 25 mm root mean square difference (RMSD) (10%) for dry snow. The need for detection processing for wet snow, which strongly absorbs radar signals, is discussed. An appendix provides 24 GHz simulated effective refractive index and penetration depth as a function of a wide range of density, temperature and wetness for ice and snow.

Validation of GlobSnow-2 snow water equivalent over Eastern Canada.

In Québec, Eastern Canada, snowmelt runoff contributes more than 30% of the annual energy reserve for hydroelectricity production, and uncertainties in annual maximum snow water equivalent (SWE) over the region are one of the main constraints for improved hydrological forecasting. Current satellite-based methods for mapping SWE over Québec's main hydropower basins do not meet Hydro-Québec operational requirements for SWE accuracies with less than 15% error. This paper assesses the accuracy of the GlobSnow-2 (GS-2) SWE product, which combines microwave satellite data and in situ measurements, for hydrological applications in Québec. GS-2 SWE values for a 30-year period (1980 to 2009) were compared with space- and time-matched values from a comprehensive dataset of in situ SWE measurements (a total of 38 990 observations in Eastern Canada). The root mean square error (RMSE) of the GS-2 SWE product is 94.1 ± 20.3 mm, corresponding to an overall relative percentage error (RPE) of 35.9%. The main sources of uncertainty are wet and deep snow conditions (when SWE is higher than 150 mm), and forest cover type. However, compared to a typical stand-alone brightness temperature channel difference algorithm, the assimilation of surface information in the GS-2 algorithm clearly improves SWE accuracy by reducing the RPE by about 30%. Comparison of trends in annual mean and maximum SWE between surface observations and GS-2 over 1980-2009 showed agreement for increasing trends over southern Québec, but less agreement on the sign and magnitude of trends over northern Québec. Extended at a continental scale, the GS-2 SWE trends highlight a strong regional variability.

Comparison of commonly-used microwave radiative transfer models for snow remote sensing.

This paper reviews four commonly-used microwave radiative transfer models that take different electromagnetic approaches to simulate snow brightness temperature (TB): the Dense Media Radiative Transfer - Multi-Layer model (DMRT-ML), the Dense Media Radiative Transfer - Quasi-Crystalline Approximation Mie scattering of Sticky spheres (DMRT-QMS), the Helsinki University of Technology n-Layers model (HUT-nlayers) and the Microwave Emission Model of Layered Snowpacks (MEMLS). Using the same extensively measured physical snowpack properties, we compared the simulated TB at 11, 19 and 37 GHz from these four models. The analysis focuses on the impact of using different types of measured snow microstructure metrics in the simulations. In addition to density, snow microstructure is defined for each snow layer by grain optical diameter (Do) and stickiness for DMRT-ML and DMRT-QMS, mean grain geometrical maximum extent (Dmax) for HUT n-layers and the exponential correlation length for MEMLS. These metrics were derived from either in-situ measurements of snow specific surface area (SSA) or macrophotos of grain sizes (Dmax), assuming non-sticky spheres for the DMRT models. Simulated TB sensitivity analysis using the same inputs shows relatively consistent TB behavior as a function of Do and density variations for the vertical polarization (maximum deviation of 18 K and 27 K, respectively), while some divergences appear in simulated variations for the polarization ratio (PR). Comparisons with ground-based radiometric measurements show that the simulations based on snow SSA measurements have to be scaled with a model-specific factor of Do in order to minimize the root mean square error (RMSE) between measured and simulated TB. Results using in-situ grain size measurements (SSA or Dmax, depending on the model) give a mean TB RMSE (19 and 37 GHz) of the order of 16-26 K, which is similar for all models when the snow microstructure metrics are scaled. However, the MEMLS model converges to better results when driven by the correlation length estimated from in-situ SSA measurements rather than Dmax measurements. On a practical level, this paper shows that the SSA parameter, a snow property that is easy to retrieve in-situ, appears to be the most relevant parameter for characterizing snow microstructure, despite the need for a scaling factor.

Near-infrared digital photography to estimate snow correlation length for microwave emission modeling.

The study is based on experimental work conducted in alpine snow. We made microwave radiometric and near-infrared reflectance measurements of snow slabs under different experimental conditions. We used an empirical relation to link near-infrared reflectance of snow to the specific surface area (SSA), and converted the SSA into the correlation length. From the measurements of snow radiances at 21 and 35 GHz, we derived the microwave scattering coefficient by inverting two coupled radiative transfer models (the sandwich and six-flux model). The correlation lengths found are in the same range as those determined in the literature using cold laboratory work. The technique shows great potential in the determination of the snow correlation length under field conditions.

Influence of complexation phenomena with multivalent cations on the analysis of glyphosate and aminomethyl phosphonic acid in water.

Experimental and theoretical influence of multivalent cations on the analysis of glyphosate and aminomethyl phosphonic acid (AMPA) was studied in pure water and in one surface water. The procedure chosen, based on derivatization with FMOC-Cl, HPLC separation, and fluorescence detection, appears highly affected at cations concentrations current in natural waters. A detailed speciation study performed with the VMINTEQ software strongly suggests that the complexes formed between analytes and cations do not dissociate during the reaction and do not react with the derivatization agent, so that only the free forms are derivatized. These results point out the necessity of a pre-treatment to prevent these interferences, even in low salinity waters. The different ways conceivable are discussed in terms of kinetic and thermodynamic considerations.