Graphene Nanocomposite Membranes: Fabrication and Water Treatment Applications.

Graphene, a two-dimensional hexagonal honeycomb carbon structure, is widely used in membrane technologies thanks to its unique optical, electrical, mechanical, thermal, chemical and photoelectric properties. The light weight, mechanical strength, anti-bacterial effect, and pollution-adsorption properties of graphene membranes are valuable in water treatment studies. Incorporation of nanoparticles like carbon nanotubes (CNTs) and metal oxide into the graphene filtering nanocomposite membrane structure can provide an improved photocatalysis process in a water treatment system. With the rapid development of graphene nanocomposites and graphene nanocomposite membrane-based acoustically supported filtering systems, including CNTs and visible-light active metal oxide photocatalyst, it is necessary to develop the researches of sustainable and environmentally friendly applications that can lead to new and groundbreaking water treatment systems. In this review, characteristic properties of graphene and graphene nanocomposites are examined, various methods for the synthesis and dispersion processes of graphene, CNTs, metal oxide and polymer nanocomposites and membrane fabrication and characterization techniques are discussed in details with using literature reports and our laboratory experimental results. Recent membrane developments in water treatment applications and graphene-based membranes are reviewed, and the current challenges and future prospects of membrane technology are discussed.

Mixing of Excitons in Nanostructures Based on a Perylene Dye with CdTe Quantum Dots.

Semiconductor quantum dots of the A2B6 group and organic semiconductors have been widely studied and applied in optoelectronics. This study aims to combine CdTe quantum dots and perylene-based dye molecules into advanced nanostructure system targeting to improve their functional properties. In such systems, new electronic states, a mixture of Wannier-Mott excitons with charge-transfer excitons, have appeared at the interface of CdTe quantum dots and the perylene dye. The nature of such new states has been analyzed by absorption and photoluminescence spectroscopy with picosecond time resolution. Furthermore, aggregation of perylene dye on the CdTe has been elucidated, and contribution of Förster resonant energy transfer has been observed between aggregated forms of the dye and CdTe quantum dots in the hybrid CdTe-perylene nanostructures. The studied nanostructures have strongly quenched emission of quantum dots enabling potential application of such systems in dissociative sensing.

Bound state vector solitons with locked and precessing states of polarization.

We report experimental observation of new tightly and loosely bound state vector solitons with locked and precessing states of polarization in a carbon nanotube mode locked fiber laser in the anomalous dispersion regime.

Salting out in organic solvents: a new route to carbon nanotube bundle engineering.

In this study we investigate salt effects on bundle formation of carbon nanotubes (CNTs) dispersed in an organic solvent, N-methyl-2-pyrrolidone (NMP). Addition of NaI salt leads to self-assembly of CNTs into well-recognizable bundles. It is possible to control the size of the CNT bundles by varying the salt concentration.