RESUMO
In the title compound, (C(6)H(10)N(2))[Co(C(7)H(3)NO(4))(2)]·5H(2)O, the Co(II) ion is six-coordinated in an N(2)O(4) environment by two pyridine-2,6-dicarboxyl-ate (pydc) ligands, having a distorted octa-hedral geometry. The crystal packing is stabilized by inter-molecular N-Hâ¯O, O-Hâ¯O and weak C-Hâ¯O hydrogen bonds. There are also π-π inter-actions between the pyridine rings of the pydc ligands and between the pydc ligands and the benzene-1,3-diammonium cations, with centroid-centroid distances of 3.4575â (15) and 3.7521â (15)â Å.
RESUMO
In the title compound, (C(6)H(10)N(2))[Ni(C(7)H(3)NO(4))(2)]·5H(2)O, the Ni(II) ion is six-coordinated by two N and four O atoms from two pyridine-2,6-dicarboxyl-ate ligands in a distorted octa-hedral fashion. The crystal packing is stabilized by inter-molecular O-Hâ¯O and N-Hâ¯O and weak C-Hâ¯O hydrogen bonds and π-π inter-actions [centroid-centroid distances = 3.4669â (19) and 3.764â (2)â Å].