Preparation of a cellulose acetate membrane using cigarette butt recycling and investigation of its efficiency in removing heavy metals from aqueous solution.

This study investigated the recycling of freshly-smoked cigarette butts (FCBs) and unsmoked cigarette filters (UCFs) into a cellulose acetate (CA) membrane. The both samples were prepared by means of a combination of seven cigarette brands, and the phase inversion method was used to recycle each sample into a membrane using N-methyl-2-pyrrolidone. The efficiency of the prepared membranes for the removal of chromium, cadmium, and lead from an aqueous solution in a forward osmosis reactor was investigated. The results showed that the both membranes had a smooth surface and macrovoids. The flux of the prepared membranes from the UCFs and FCBs recycling were 14.8 and 13.2 LMH, respectively. The porosity and reverse salt of the UCFs membrane were 61% and 3.5 gMH, while those for FCBs membrane were 58% and 3.9 gMH. The observed metal removal efficiency of the both membranes was in the range of 85 to 90%. However, increasing the concentration of metals up to five times caused a slight decrease in the removal efficiency (less than 5%).

Preparation of a thin-film nanocomposite forward osmosis membrane for the removal of organic micro-pollutants from aqueous solutions.

In this study, a thin-film nanocomposite forward osmosis (TFN FO) membrane was synthesized. The properties and structures of membranes were evaluated for the removal of three organic micro-pollutants from synthetic and real industrial wastewater samples. Laboratory scale fabrication thin-film nanocomposite forward osmosis (FO) membranes composed of a support layer and an active layer. The former was constructed by adding different weight ratios of polyethylene glycol 400 (PEG-400) (0-8 wt.%), polysulfone (PSf), and 1-methyl, 2-pyrrolidone via the phase inversion process, while the latter was synthesized by the incorporation of different weight ratios of graphene oxide (GO) (0-0.012 wt.%), M-phenylenediamine, and 1, 3, 5-benzene trichloride into polyamide layer through the interfacial polymerization reaction. In comparison with thin-film composite (TFC) membranes, the TFN membranes revealed higher hydrophilicity, porosity, water permeability, water flux and salt rejection and lower internal concentration polarization (ICP), reverse salt flux and specific reverse salt flux. The TFN membrane containing 0.008% GO in the active layer and 4% PEG 400 in the support layer exhibited maximum water flux (34.3 LMH) and rejection rate of benzene, phenol and toluene (97%, 84%, and 91%, respectively). The results revealed that the TFN-FO membranes possess a promising potential to improve the water flux and wastewater treatment.