Rapid synthesis of ultrasmall platinum nanoparticles supported on macroporous cellulose fibers for catalysis.

Herein, we report a facile method for the synthesis of platinum nanoparticles (PtNPs) about 2.25 nm in size by heating a solution of chloroplatinic acid and sodium rhodizonate. The PtNPs were synthesized in about 5 min. The PtNPs were supported on macroporous cellulose fibers that were obtained from Kimwipe paper (KWP). The cellulose fiber-supported PtNPs (PtNPs@KWP) exhibited excellent catalytic activity towards the reduction of organic pollutants [e.g. methyl orange (MO)] in the presence of hydrogen (H2) gas and formic acid (FA). FA and H2 gas were utilized as clean and alternative reducing agents. The reduction of MO was performed in two different types of water matrices viz. deionized water (DIW) and simulated fresh drinking water (FDW). In both water matrices, the FA mediated reduction of MO was found to be faster than the H2 gas-bubbled one. The PtNPs@KWP demonstrated excellent cycling stability without leaching the PtNPs or platinum ions into the solution for at least five cycles.

Adsorption of methylene blue and tetracycline onto biomass-based material prepared by sulfuric acid reflux.

The adsorptive removal of environmental pollutants is an effective method for the treatment of contaminated water. Thus, the preparation of adsorbents from low-cost, readily available, and renewable resources has garnered immense attention in recent years. In this study, a facile one-step method for the preparation of a high-capacity adsorbent is demonstrated by refluxing pine cones in concentrated sulfuric acid. With sulfuric acid reflux, the pine cones undergone carbonization as well as functionalization with sulfonic acid groups. The adsorbent demonstrated high adsorption capacity for two emerging organic pollutants, methylene blue (MB) and tetracycline (TC). Different variables such as pH, temperature, contact time, and initial concentration of the pollutants were analyzed and showed that the adsorption capacity for MB increased in a basic pH and vice versa for TC. Also, the elevated temperature favored the adsorption for both MB and TC. The maximum adsorption capacity was found to be 1666.66, and 357.14 mg g-1 for MB and TC, respectively. In comparison to the pristine pine cone, the sulfuric acid treated pine cone demonstrated an extraordinary improvement in the adsorption capacity. The adsorption of MB and TC was performed from the tap water matrix and similar adsorption capacities were found. A packed glass column was also prepared to demonstrate the adsorption of MB from tap water under flow conditions.