Green synthesis of sustainable magnetic nanoparticles Fe3O4 and Fe3O4-chitosan derived from Prosopis farcta biomass extract and their performance in the sorption of lead(II).

The sustainable processes are now in tremendous demand for nanomaterial synthesis as a result of their unique properties and characteristics. The magnetic nanoparticles comprised of Fe3O4 and its conjugate with abundant and renewable biopolymer, chitosan, were synthesized using Prosopis farcta biomass extract, and the resulting materials were used to adsorb Pb (II) from aqueous solution. Thermodynamic parameters revealed that the sorption of lead (II) on Fe3O4 as well as Fe3O4-Chitosan (Fe3O4-CS) has been an endothermic and self-regulating procedure wherein the sorption kinetics was defined by a pseudo-second-order pattern and the sorption isotherms corresponded to the Freundlich pattern. A multivariable quadratic technique for adsorption process optimization was implemented to optimize the lead (II) adsorption on Fe3O4 and Fe3O4-chitosan nanoparticles, the optimal conditions being pH 7.9, contact time of 31.2 min, initial lead concentration of 39.2 mg/L, adsorbent amount of 444.3 mg, at a 49.7 °C temperature. The maximum adsorption efficiencies under optimal conditions were found to be 69.02 and 89.54 % for Fe3O4 and Fe3O4-CS adsorbents, respectively. Notably, Fe3O4 and Fe3O4-CS can be easily recovered using an external magnet, indicating that they are a viable and cost-effective lead removal option.

Utilization of ferrous slags as coagulants, filters, adsorbents, neutralizers/stabilizers, catalysts, additives, and bed materials for water and wastewater treatment: A review.

Solid waste is currently produced in substantial amounts by industrial activities. While some are recycled, the majority of them are dumped in landfills. Iron and steel production leaves behind ferrous slag, which must be created organically, managed wisely and scientifically if the sector is to remain more sustainably maintained. Ferrous slag is the term for the solid waste that is produced when raw iron is smelted in ironworks and during the production of steel. Both its specific surface area and porosity are relatively high. Since these industrial waste materials are so easily accessible and offer such serious disposal challenges, the idea of their reuse in water and wastewater treatment systems is an appealing alternative. There are many components such as Fe, Na, Ca, Mg, and silicon found in ferrous slags, which make it an ideal substance for wastewater treatment. This research investigates the potential of ferrous slag as coagulants, filters, adsorbents, neutralizers/stabilizers, supplementary filler material in soil aquifers, and engineered wetland bed media to remove contaminants from water and wastewater. Ferrous slag may provide a substantial environmental risk before or after reuse, so leaching and eco-toxicological investigations are necessary. Some study revealed that the amount of heavy metal ions leached from ferrous slag conforms to industrial norms and is exceedingly safe, hence it may be employed as a new type of inexpensive material to remove contaminants from wastewater. The practical relevance and significance of these aspects are attempted to be analyzed, taking into account all recent advancements in the fields, in order to help in the development of informed decisions about future directions for research and development related to the utilization of ferrous slags for wastewater treatment.

Bioactive potential of beetroot (Beta vulgaris).

Beetroot (Beta vulgaris) is the most well-known and commonly cultivated fruit from the Chenopodiaceae family. Beetroot is a rich source of nutrients including vitamins (B complex and C), minerals, fibre, proteins, and a variety of bioactive phenolic substances, which are chiefly composed of betalains, and other components possessing antioxidant activity, such as coumarins, carotenoids, sesquiterpenoids, triterpenes, and flavonoids (astragalin, tiliroside, rhamnocitrin, kaempferol, rhamnetin). Beetroot and its value-added products provide a variety of health advantages and may help prevent and manage various ailments and diseases due to bioactive components. Beetroot's phytochemical diversity makes them potential sources of nutraceutical chemicals that can be used to build functional foods. Pharmacologically, beetroot has the potential to be an antioxidant, antimicrobial, anticancerous, hypocholesterolemic, and anti-inflammatory agent. In a comprehensive analysis, this review first provides an overview of the bioactive compounds present in beetroot and its parts, followed by a specific description of the current evidence on this bioactive potential of beetroot and its parts, highlighting the biochemical mechanisms involved. Additionally, the factors affecting the concentration and activity of the beetroot bioactives and the best possible method to conserve its bioactivity has also been discussed in this review.

1.3 µm dissipative soliton resonance generation in Bismuth doped fiber laser.

In this work, a Figure-9 (F9) bismuth-doped fiber laser (BiDFL) operating in the dissipative soliton resonance (DSR) regime is presented. The 1338 nm laser used a BiDF as the active gain medium, while a nonlinear amplifying loop mirror (NALM) in an F9 configuration was employed to obtain high energy mode-locked pulses. The wave breaking-free rectangular pulse widened significantly in the time domain with the increase of the pump power while maintaining an almost constant peak power of 0.6 W. At the maximum pump power, the mode-locked laser delivered a rectangular-shaped pulse with a duration of 48 ns, repetition rate of 362 kHz and a radio-frequency signal-to-noise ratio of more than 60 dB. The maximum output power was recorded at around 11 mW with a corresponding pulse energy of 30 nJ. This is, to the best of the author's knowledge, the highest mode-locked pulse energy obtained at 1.3 µm as well as the demonstration of an NALM BiDFL in a F9 configuration.

Study on the dopant concentration ratio in thulium-holmium doped silica fibers for lasing at 2.1µm.

We present the fabrication and laser performance of thulium-holmium co-doped silica fibers when cladding pumped at ∼790 nm. By using the hybrid gas phase-solution doping process in conjunction with the MCVD preform fabrication technique, the doping concentration and the Tm:Ho ratio were varied to study the energy transfer efficiency from Tm3+ to Ho3+. Our study indicates that for a thulium concentration that has resulted in an efficient two-for-one cross- relaxation process with 790 nm pumping, and while maintaining a Tm:Ho concentration ratio in the range ∼ 10 to 20, the energy transfer efficiency has reached above 75%. In a free-running laser cavity, the pump power limited laser output of 38W with a slope efficiency of 56% at 2.1 microns is demonstrated.

Study on the temperature dependent characteristics of O-band bismuth-doped fiber amplifier.

We report the temperature dependent performance of an O-band bismuth (Bi)-doped fiber amplifier (BDFA) in the temperature range from -60 to +80°C. At room temperature, maximum gains of 27 and 40 dB with noise figures (NFs) of 4.3 and 4.8 dB are measured for -23 dBm signal power in the single and double pass BDFA, respectively. An increment in gain and reduction in NF is observed as the ambient temperature of the BDFA is reduced. In the double pass BDFA, the temperature dependent gain coefficient from -60 to +80°C is found to be around -0.02 and -0.03 dB/°C across the wavelength band of 1300-1360 nm for -10 and -23 dBm signal powers, respectively. We also study the gain and NF characteristics with pump power and signal power at different temperatures, and a maximum gain of 45 dB is obtained at -60°C for -30 dBm signal power.

40 dB gain all fiber bismuth-doped amplifier operating in the O-band.

In this Letter, we investigate and compare the gain and noise figure characteristics of bismuth (Bi)-doped fiber amplifiers configured in both single and double signal pass implementations. A maximum gain of 25 dB and a noise figure of 4 dB is measured at 1360 nm in the single pass configuration for -23 dBm input signal power, whereas in the double pass configuration the gain of the amplifier is improved significantly by 14 dB allowing us to achieve a gain of 39 dB with a noise figure of 5 dB. To the best of our knowledge, this is the highest gain reported to date using Bi-doped fiber as a gain medium. Furthermore, we also study the gain and noise figure dependency on pump power, signal power, and pump wavelength for the double pass amplifier configuration. We observed similar gain and noise figure performance in the double pass configuration to that of the single pass configuration but with the benefit of less pump power and a shorter length of the Bi-doped fiber.

Highly efficient thulium-doped high-power laser fibers fabricated by MCVD.

We report a hybrid process by combining both vapor-phase and solution-doping techniques of rare-earth doped preform fabrication in conjunction with the MCVD technique, in order to fabricate highly efficient Tm-doped laser fibers. The proposed fabrication route takes advantage of co-doping silica with high alumina content through the vapor-phase doping process, which is otherwise difficult to achieve using conventional solution doping technique. In addition, by employing the solution doping method, high-purity thulium halide precursors that have low vapor pressures up to several hundred degree Celsius. These high-purity thulium halide precursors can be used to dope the fiber core region with a high thulium concentration that is optimized for an efficient two-for-one cross-relaxation process for 79xnm diode pumped thulium-doped fiber laser. Fibers fabricated using the hybrid approach show more homogeneous and flat-top dopant profiles, compared with the conventional approach, where both aluminum and thulium are incorporated in the core through solution doping. This will ensure that more doped region will take part in the cross-relaxation process. Superior laser performance with a slope efficiency of >70% in the two-micron band has been demonstrated when diode pumped at ~790nm.

Temperature dependent steady and dynamic oscillatory shear rheological characteristics of Indian cow milk (Desi) ghee.

Rheological characteristics of Desi ghee were investigated at 18, 24, 30 and 36 °C. The steady shear properties were evaluated by varying the shear rate from 0.01 to 100 s-1 and the dynamic shear properties were studied by varying strain and frequency sweep from 0.01 to 100% and 0.1 to 100 rad s-1, respectively. At the four selected temperatures, the ghee samples displayed non-Newtonian shear thinning behavior with flow behavior index (n) ranging from 0.224 to 0.911. As the shear rate increased from 0 to 100 s-1, the values of dynamic viscosity decreased from 54 to 8.14, 20.01 to 1.05, 1.33 to 0.295, and 3.02 to 0.0025 Pa s at 18, 24, 30 and 36 °C, respectively. Out of four rheological models (Power-law or Ostwald-de Waele, Herschel-Bulkley, Casson, and Bingham model) fitted to the shear rate and stress data, the Ostwald model was found to be superior in predicting the shear rate-stress data at 18 °C, whereas Ostwald-de Waele and Herschel-Bulkley models predicted all the data points over the temperature range of 24-30 °C, as observed by the values of coefficient of determination (R2 ), standard deviation (SD), and relative deviation percentage (Rd ). The value of activation energy (EA ), as calculated from Arrhenius type equation, was found to be 1.98 × 106 kJ mol-1 over the entire temperature range. The study also revealed that the magnitudes of dynamic shear viscosity (η*) were higher than those of the steady shear viscosity (η) at the four temperatures, indicating that the Cox-Merz rule was not applicable to the ghee samples.

Optimization and modeling of methyl orange adsorption onto polyaniline nano-adsorbent through response surface methodology and differential evolution embedded neural network.

Presence of pigments and dyes in water bodies are growing tremendously and pose as toxic materials and have severe health effects on human and aquatic creatures. Treatments methods for removal of these toxic dyes along with other pollutants are growing in different dimensions, among which adsorption was found a cheaper and efficient method. In this study, the performance of polyaniline-based nano-adsorbent for removal of methyl orange (MO) dye from wastewater in a batch adsorption process is studied. Along with this to minimize the number of experiments and obtain optimal conditions, a multivariate predictive model based on response surface methodology (RSM) is developed. This is compared with data-driven modeling using the artificial neural network (ANN) which is integrated with differential evolution optimization (DEO) for prediction of the adsorption of MO. The interactive effects on MO removal efficiency with respect to independent process variables were investigated. The fit of the predictive model was found to good enough with R2 = 0.8635. The optimal ANN architecture with 5-12-1 topology resulted in higher R2 and lower RMSE of 0.9475 and 0.1294 respectively. Pearson's Chi-square measure which provides a good measurement scale for weighing the goodness of fit is found to be 0.005 and 0.038 for RSM and ANN-DEO respectively, and other statistical metrics evaluated in this study further confirms that the ANN-DEO is very superior over RSM for model predictions.

Modeling and optimization by particle swarm embedded neural network for adsorption of zinc (II) by palm kernel shell based activated carbon from aqueous environment.

Zn (II) is one the common pollutant among heavy metals found in industrial effluents. Removal of pollutant from industrial effluents can be accomplished by various techniques, out of which adsorption was found to be an efficient method. Applications of adsorption limits itself due to high cost of adsorbent. In this regard, a low cost adsorbent produced from palm oil kernel shell based agricultural waste is examined for its efficiency to remove Zn (II) from waste water and aqueous solution. The influence of independent process variables like initial concentration, pH, residence time, activated carbon (AC) dosage and process temperature on the removal of Zn (II) by palm kernel shell based AC from batch adsorption process are studied systematically. Based on the design of experimental matrix, 50 experimental runs are performed with each process variable in the experimental range. The optimal values of process variables to achieve maximum removal efficiency is studied using response surface methodology (RSM) and artificial neural network (ANN) approaches. A quadratic model, which consists of first order and second order degree regressive model is developed using the analysis of variance and RSM - CCD framework. The particle swarm optimization which is a meta-heuristic optimization is embedded on the ANN architecture to optimize the search space of neural network. The optimized trained neural network well depicts the testing data and validation data with R2 equal to 0.9106 and 0.9279 respectively. The outcomes indicates that the superiority of ANN-PSO based model predictions over the quadratic model predictions provided by RSM.

Bismuth-doped all-fiber mode-locked laser operating at 1340 nm.

We demonstrate a 1340 nm mode-locked Bismuth (Bi)-doped fiber laser without any saturable absorber. The effect of pump power on pulse width is studied, and a variation from 1.5 to 3 ns is reported. The output of the mode-locked Bi-doped fiber laser is further amplified using a master oscillator power amplifier configuration, and a peak power of 1.15 W is achieved. Soliton bunching is observed, and a true pulse width of 1.2 ps is reported from the measured autocorrelation trace. Stable operation of the mode-locked laser is verified from the radio-frequency spectrum with a fundamental repetition rate of 6.3 MHz, and SNR of 65 dB.

Bi-doped fiber amplifier with a flat gain of 25 dB operating in the wavelength band 1320-1360 nm.

Bismuth (Bi)-doped phosphosilicate fibers have been fabricated by the modified chemical vapor deposition (MCVD)-solution doping technique under different process conditions. The influence of fabrication conditions on unsaturable loss in fibers has been investigated. Pump wavelength dependent Bi gain has been studied to obtain a flat gain over a wide bandwidth. A diode pumped all-fiber Bi-doped amplifier with a flat gain of 25±1 dB from 1320-1360 nm (40 nm) has been demonstrated for -10 dBm of input signal power with a noise figure (NF) ranging from 4-6 dB. Moreover, a small signal gain of 29 dB and a NF of 4.5 dB at 1340 nm has been achieved for an input signal power of -30 dBm.

Exploiting the short wavelength gain of silica-based thulium-doped fiber amplifiers.

Short wavelength operation (1650-1800 nm) of silica-based thulium-doped fiber amplifiers (TDFAs) is investigated. We report the first demonstration of in-band diode-pumped silica-based TDFAs working in the 1700-1800 nm waveband. Up to 29 dB of small-signal gain is achieved in this spectral region, with an operation wavelength accessible by diode pumping as short as 1710 nm. Further gain extension toward shorter wavelengths is realized in a fiber laser pumped configuration. A silica-based TDFA working in the 1650-1700 nm range with up to 29 dB small-signal gain and noise figure as low as 6.5 dB is presented.

Toxicological and hematological effect of Terminalia arjuna bark extract on a freshwater catfish, Heteropneustes fossilis.

Increasing demand for eco-friendly botanical piscicides and pesticides as replacements for harmful synthetic chemicals has led to investigation of new sources of plant materials. Stem bark of Terminalia arjuna, which has been used as a popular folk medicine since ancient time, was examined for its piscicidal activity. This study aims to determine toxicity of ethanol extract of T. arjuna bark on fresh water stinging catfish (Heteropneustes fossilis), along with evaluation of changes in hematological parameters of the fishes exposed to a lethal concentration. The percent mortality of fishes varied significantly in response to concentrations of the extract and exposure times (between exposure time F = 36.57, p < 0.001; between concentrations F = 39.93, p < 0.001). The lethal concentrations (LC50) of ethanol extract were found to be 12.7, 8.94, 5.63 and 4.71 mg/l for 24, 48, 72 and 96 h, respectively. During acute toxicity test, blood samples of treatment fishes showed significant decreases in the red blood cells count, hematocrit content, hemoglobin concentration, mean corpuscular hemoglobin concentration and plasma protein level when compared to those of the control group, while there were significant increases in the mean corpuscular volume, mean corpuscular hemoglobin, white blood cells count and plasma glucose concentration. These results suggest that T. arjuna bark extract could be considered as a potent piscicide due to its toxic effect on fish, particularly fish hematology.

Mass Production of Carbon Nanofibers Using Microwave Technology.

Carbon nanotubes (CNFs) were produced by gas phase single stage microwave assisted chemical vapour deposition (MA-CVD) using ferrocene as a catalyst and acetylene (C2H2) and hydrogen (H2) as precursor gases. The effect of the process parameters such as microwave power, radiation time, and gas ratio of C2H2/H2 was investigated. The CNFs were characterized using scanning and transmission electron microscopy (TEM), and by thermogravimetric analysis (TGA). Results reveal that the optimized conditions for CNF production were 1000 W reaction power, 35 min radiation time, and 0.8 gas ratio of C2H2/H2. TEM analyses revealed that the uniformly dispersed CNFs diameters ranging from 115-131 nm. The TGA analysis showed that the purity of CNF produced was 93%.

Highly efficient Yb-free Er-La-Al doped ultra-low NA large mode area single-trench fiber laser.

We demonstrate a 60µm core diameter Yb free Er-La-Al doped single-trench fiber having a 0.038 ultra-low-NA, fabricated using conventional MCVD process in conjunction with solution doping technique. Numerical simulations predict an effective single mode operation with effective area varying from 1,820µm(2) to 1,960µm(2) (taking bend-induced modal distortion into account) for different thicknesses of trenches and resonant rings at a constant bend radius of 25cm. Moreover, all solid structure favors easy cleaving and splicing. Experimental measurements demonstrate a robust effective single mode operation. Furthermore, with a 4%-4% laser cavity, this fiber shows a record efficiency of 46% with respect to the absorbed pump power.

Large mode area multi-trench fiber for UV and visible transmission.

We experimentally demonstrate all-solid 10 and 20 µm core diameter multi-trench fibers for UV and visible wavelengths. Measurements ensure an effective single-mode operation over a wide range of bend radii, which is suitable for applications such as beam delivery. Both fibers were fabricated by the conventional modified chemical vapor deposition process, which is suitable for mass production. Moreover, all-solid fiber design ensures easy cleaving and splicing.

1120 nm diode-pumped Bi-doped fiber amplifier.

Bismuth-doped aluminosilicate fiber has been fabricated by the MCVD-solution doping method and characterized for its unsaturable loss and gain. The amplifier performance has been compared for a novel pumping wavelength of 1120 nm with the conventional pumping wavelength region of 1047 nm. Unsaturable loss was 65% and 35% at 1047 and 1120 nm, pump wavelengths, respectively. A maximum gain of about 8 dB at 1180 nm for a fiber length of 100 m was observed with 1120 nm pumping. Gain enhancement of 70% was achieved with the 1120 nm pump as compared to the 1047 nm pump. A further 3.5 dB gain was obtained on simultaneous pumping at 1047 and 1120 nm.

High power, compact, picosecond MOPA based on single trench fiber with single polarized diffraction-limited output.

We experimentally demonstrate an all-solid Yb-doped 30 µm core diameter single trench fiber. Measurements ensure a robust effective single-mode operation without the need of tight coiling as required for conventional fibers thanks to the ultralow NA (∼0.038) and resonant ring surrounding the core. All-solid and cylindrical design ensures the suitability for mass scale production with the added benefit of all-fiberized device structure. A compact master oscillator power amplifier (MOPA) has been built using this fiber delivering ∼23.5 ps pulses at 13.5 MHz repetition rate delivering up to ∼52 W of average output power corresponding to a pulse energy of ∼3.8 µJ and peak power of >160 kW, while maintaining ∼76% slope efficiency. The output beam exhibits a polarization extinction ratio of more than 15 dB and a M2 less than 1.15.