RESUMO
The title compound, C(25)H(35)N(5)S, has an approximately C-shaped conformation. The dihedral angle between the triazole and phenyl planes is 79.5â (2)°. The crystal structure consists of infinite chains parallel to the b axis, constructed by C-Hâ¯S hydrogen bonds between translation-related mol-ecules. Adjacent chains are linked via weak C-Hâ¯C inter-actions between the adamantyl and phenyl groups.
RESUMO
The mol-ecule of the title compound, C(24)H(32)N(4)OS, is a functionalized 1,3,4-oxadiazole-2-thione with substituted piperazine and adamantanyl substituents attached at the 3- and 5-positions, respectively, of the oxadiazole spacer with an approximately C-shaped conformation. In the crystal, mol-ecules form dimers via C-Hâ¯S inter-action. The piperazine ring has a chair conformation; the substituents S, methyl-ene C and adamantane C of the essentially planar oxadiazole ring are approximately in the same plane, with distances of -0.046â (2), -0.085â (5) and 0.003â (4)â Å, respectively. The dihedral angle between the planes of the phenyl and oxadiazole rings is 31.3â (3)°.
RESUMO
The title mol-ecule, C(17)H(20)N(2)O, is a functionalized hydrazine with benzoyl and adamantyl substituents attached to the two hydrazine N atoms. In the crystal, mol-ecules are linked via N-Hâ¯N hydrogen bonds, forming chains propagating along the a-axis direction. There are also C-Hâ¯O, C-Hâ¯N and C-Hâ¯π inter-actions present within the chains.