1.
Acta Crystallogr Sect E Struct Rep Online
; 69(Pt 3): o358, 2013 Mar 01.
Artigo
em Inglês
| MEDLINE
| ID: mdl-23476548
RESUMO
The title mol-ecule, C19H12S2O2, lies on a twofold rotation axis. The thio-chromonone unit is essentially planar, with a maximum deviation of 0.0491â (14)â Å. The dihedral angle between the thio-chromenone ring systems is 64.48â (4)°. In the crystal, there are weak π-π stacking inter-actions, with a centroid-centroid distance of 3.7147â (9)â Å.
2.
J Org Chem
; 72(15): 5867-9, 2007 Jul 20.
Artigo
em Inglês
| MEDLINE
| ID: mdl-17590047
RESUMO
Highly deactivated aromatic compounds were smoothly monobrominated by treatment with N-bromosuccinimide (NBS) in concentrated H2SO4 medium affording the corresponding bromo derivatives in good yields. Mild reaction conditions and simple workup provides a practical and commercially viable route for the synthesis of bromo compounds of deactivated aromatics.