Biosynthesis of TiO2 nano particles by using Rosemary (Rosmarinus officinalis) leaf extracts and its application for crystal dye degradation under sunlight.

Titanium dioxide (TiO2) nanoparticles were prepared through Rosmarinus-officinalis leaf extracts at 90 and 200°C. In this research, the degradations of methylene blues by using TiO2 nanoparticles Sun light radiations were studied. The synthesized materials were characterized using XRDs, UV-Vis, PL, SEM, TEM, EDS and XPS. The results displayed that bio-synthesis temperatures intrude the shapes and sizes of TiO2 nanoparticles. For TiO2-90, micrographs show separable crystalline with irregular morphologies and agglomerate cubic particles. For the other TiO2-200 sample, SEM and TEM micro-imaging shows crumbly agglomerated cubic structures. The XRD shows that the intense peaks observed at angles of 25.37°, 37.19°, 47.81° and 53.89° confirming a highly crystalline oriented as (004), (200), and (105) planes respectively. The optical properties of TiO2 nanoparticles synthesized were conveyed by PL and UV-Vis. The energy band gap calculated was 3.0 eV for both samples; that indicates heating temperature didn't influence the band gap of the samples. The elemental composition Ti and O2 is shown by EDS and XPS. Photo-catalytic experiments discovered that TiO2-90 nanoparticles were well-organized in photo-degradations of MB, likened to TiO2-200. The great activities of TiO2-90 were because of better physicochemical characteristics associated with TiO2-200 effectively degrading MB under photo-light. Photo-degradations of dye under sunlight as plentifully obtainable energy sources by TiO2, synthesized by simpler techniques, can be hopeful to grow an eco-friendly and economical process.

Growth, yield, and yield variables of onion (Allium Cepa L.) varieties as influenced by plantspacing at DambiDollo, Western Ethiopia.

Onion (Allium cepa L.) is an important bulb plant grown worldwide. Proper use of the agronomic practice has undoubtedly contributed to growing crop yields. The right level of any farming practice, like the distance between plants, plant density, date of planting, and time of harvest, can produce the wanted outcomes. Therefore, this research was piloted to evaluate the influence of plant spacing on the development of bulb harvest-related traits of onion varieties in Dambi Dollo University, Western Ethiopia, in 2021. Three onion varieties (Adama red, Monarch, Nafis) and four intra-row spaces (6 cm, 8 cm, 10 cm, and 12 cm) in factorial combinations were settled by a complete randomized block design which was simulated three times. The findings of the study indicate that all the factors related to crop growth and bulb yield of onion varieties were mainly influenced by different kinds and plant spacing. Conversely, the collaboration of these two factors did not affect all other factors, but the interaction of the two factors had a great effect on the days to maturity measured in this study. The highest plant height was registered on the onion planted at a distance of 10 cm (59.83 cm) and 12 cm (59.08 cm) distance between plants. The high commercial yields (34.44 t ha-1) and entire bulb yield (35.40 t ha-1) were found in the Nafis variety. The highest marketable yields (31.12 ha-1) and entire marketable yield (31.78 ha-1) were recorded on an onion plant planted 10 cm between plants. Therefore, in the research area, farmers can use a variety of Nafis and a 10 cm distance between plants to increase their onion production.

Biosynthesis of TiO2 nanoparticles by Caricaceae (Papaya) shell extracts for antifungal application.

Titanium dioxide nanoparticles (TiO2 NPs) were prepared by Caricaceae (Papaya) Shell extracts. The Nanoparticles were analyzed by UV-Vis spectrums, X-ray diffractions, and energy-dispersive X-rays spectroscopy analyses with a scanning electron microscope. An antifungal study was carried out for TiO2 NP in contradiction of S. sclerotiorums, R. necatrixs and Fusarium classes that verified a sophisticated inhibitions ratio for S. sclerotiorums (60.5%). Germs of pea were individually preserved with numerous concentrations of TiO2 NPs. An experience of TiO2 NPs (20%, 40%, 80% and 100%), as well as mechanisms that instigated momentous alterations in seed germinations, roots interval, shoot lengths, and antioxidant enzymes, were investigated. Associated with controls, the supreme seeds germinations, roots and plant growth were perceived with the treatments of TiO2 NPs. Super-oxide dis-mutase and catalase activities increased because of TiO2 NPs treatments. This advocates that TiO2 Nanoparticles may considerably change antioxidant metabolisms in seed germinations.

Influence of capillary tube length on the performance of domestic refrigerator with eco-friendly refrigerant R152a.

The household heating and cooling system often use the capillary device. The use of the helical capillary eliminates the need for lightweight refrigeration devices in the system. Capillary pressure is noticeably affected by the capillary geometric parameters, such as length, mean diameter, and pitch. This paper is concerned with the effects of the capillary length on the performance of the system. Three separate length capillary tubes were used in the experiment. The data on R152a were studied under various conditions to assess the impact of varying the length. Maximum COP is obtained at an evaporator temperature of - 12 °C and capillary length of 3.65 m. The result is drawn that the system performance enhances when the capillary length is improved to 3.65 m when compared to 3.35 m and 3.96 m. As a result, as the capillary length increases up to a specific amount, the system's performance improves. The findings from the experiment were compared with those from the computational fluid dynamics (CFD) analysis.

Synthesis of nano-sized lead sulfide thin films from Avocado (Glycosmis cochinchinensis) Leaf extracts to empower pollution remediation.

The translucent and nano-crystalline PbS films were equipped with the CBD techniques on metal substrates by the temperature of 90 °C through aqueous solutions of Lead Nitrate and Thiourea. The XRD phases verify the crystalline property of synthesized thin films that the shape falls in the cubic structures with favourite orientations. It revealed that the prepared material is cubic crystal oriented as (111), (110), (100) and (101) crystal planes. The crystalline size varied between 0.4 and 0.7 nm. The band gap was assessed using UV-vis captivation spectra and Tau relations. The average energy band gap was found to be 2.43 eV which is greater than bulk materials of PbS; because of quantum confinements of Lead Sulfide Nano Crystalline thin films, and PL also confirms this result. The variation in band gap with Leaf extracts and particle sizes displayed blue shifts characteristic of electrons quantum confinements. SEM micrograph shows extremely uniform and adherent PbS films are found at higher PH values. It was evidently observed that the viscosity of the synthesized thin films reduced from 563 to 111 nm with a rise in pH value. The sample prepared at pH 4 shows good performance, and thin films deposited from Avocado (Glycosmis cochinchinensis) leaf extracts are a promising method to empower pollution remediation and future energy.

Factors Associated with the Prevalence of Hepatitis B among Volunteer Blood Donors at Jimma Blood Bank, South Ethiopia.

Background: Hepatitis B is a severe, widespread infectious disease of the liver that affects millions of people around the world. It is one of the life-threatening liver infections caused by the hepatitis B virus (HBV). HBV is the cause of up to 80% of cases of primary liver cancer. Due to the potential risk associated with HBV infection, it is important to study the factors which are associated with the seropositive volunteers. Objective: The purpose of this study was to identify factors associated with seropositivity for the hepatitis B virus among volunteers who donated blood at the Jimma Blood Bank in southern Ethiopia. Methods: Cross-sectional research was conducted on blood donors who came to the Jimma Blood Bank to donate their blood. Three hundred and fifty-nine volunteer blood donors who arrived at the Jimma Blood Bank were investigated face-to-face in order to collect sociodemographic characteristics and risk factors for HBV infection. The data were analyzed using statistical software SPSS version 20.0. The association between the risk factor for HBV infection and HBV infection was determined using chi-square tests. Result: In total, there were 359 participants; their mean age was 22.5, among which 161 (44.8%) were males. Out of 359 volunteers, 13 (3.6%) were seropositive for HBsAg. The test positivity rate among males was 7/198 (3.54%), while the rate among females was 6/161 (3.7%). More than 3/4 of those who tested positive were under the age of 40. Chi-square analysis showed that volunteers whose income was between 12 and 26.84 USD were less likely to have the infectious disease than those whose income was less than 11.84 USD per month (p=0.042). Conclusion: The prevalence of HBV was found to be 3.6% among selected volunteers. It was found that, out of 20 volunteers, 13 had infection. Chi-square analysis showed that HBV infection was associated with low monthly income and the use of unsafe therapeutic injections.

Biological approach synthesis and characterization of iron sulfide (FeS) thin films from banana peel extract for contamination of environmental remediation.

Biological approach synthesis and characterization of Iron Sulfide (FeS) thin films from banana peel extract for contamination remediation of environment studied. Iron chloride, Sodium thiosulfate and Ethylene-di-amine-tetra acetate (EDTA) were used as precursor solutions without further purification. The nanoparticle of banana peel was extracted and prepared with synthesized FeS thin films and analyzed by X ray-diffraction for structural examination, Scanning electron microscope (SEM) for surface morphological analysis, Ultra-violet-visible-spectrometer (UV-Vis) and photo-luminescence spectro-photo-meter (P-L) for optical characterizations. XRD peaks are shown with recognized to (110), (200), (310), and (301) crystalline planes. The occurrence of this deflection peak are recognised the FeS crystal segment of the tetragonal crystalline systems. SEM micrographs of the films prepared biological method show the distribution of grains, which cover the surface of the substrate completely and are uniform and films deposited purely have defects. The photo-luminescence, absorbance, and transmittance strength of banana peel extract FeS thin film is greater than pure FeS thin films in which wide-ranging and symmetries groups were perceived. In the present study, the comparison of pure FeS thin films and Nano synthesized banana peel extract with FeS thin films was studied. It is observed that Nano synthesized banana fibre absorbs higher than pure FeS thin films in solar cell application. Finally, green synthesis is an ecofriendly, easy and cheap promising method for the fabrication of thin films for solar cell applications.